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公开(公告)号：US20120121498A1
公开(公告)日：2012-05-17
申请号：US13353722
申请日：2012-01-19
申请人： Sheng Dai , Xiqing Wang
发明人： Sheng Dai , Xiqing Wang
IPC分类号： C01B31/02
CPC分类号： C04B38/0022 , C01B32/00 , C04B35/524 , C04B35/62218 , C04B2111/00793 , C04B2111/0081 , C04B2111/00853 , C04B2235/48 , Y10S977/755 , Y10T428/24165 , Y10T428/249967 , Y10T428/249978 , Y10T428/249979 , C04B38/0054 , C04B38/062
摘要： The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than −2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.
摘要翻译： 本发明涉及一种制备中孔碳材料的方法，所述方法包括使前体组合物经历固化步骤，随后进行碳化步骤，所述前体组合物包含：（i）由嵌段共聚物组成的模板组分，（ii ）酚类化合物或材料，（iii）可交联的醛组分，和（iv）至少0.5M浓度的pKa或小于-2的强酸，其中所述碳化步骤包括在碳化作用下加热前体组合物 温度足以将前体组合物转化成介孔碳材料。 本发明还涉及具有改进的热稳定性的中孔碳材料，优选根据上述方法制备。
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公开(公告)号：US08828533B2
公开(公告)日：2014-09-09
申请号：US13349162
申请日：2012-01-12
申请人： Sheng Dai , Pasquale Fernando Fulvio , Richard T. Mayes , Xiqing Wang , Xiao-Guang Sun , Bingkun Guo
发明人： Sheng Dai , Pasquale Fernando Fulvio , Richard T. Mayes , Xiqing Wang , Xiao-Guang Sun , Bingkun Guo
CPC分类号： H01B1/04 , B01J20/20 , B01J20/205 , B01J20/28026 , B01J20/28083 , B01J20/282 , B01J20/3078 , B82Y30/00 , B82Y40/00 , C01B32/00 , C04B35/521 , C04B35/524 , C04B35/83 , C04B38/0032 , C04B2111/00853 , C04B2111/94 , C04B2235/422 , C04B2235/424 , C04B2235/48 , C04B2235/52 , C04B2235/5288 , C04B2235/5454 , Y10T428/249978 , Y10T428/249979 , Y10T428/249986 , C04B38/0064
摘要： A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.
摘要翻译： 一种导电介孔碳复合材料，其包含介于中孔碳基体内的导电碳纳米颗粒，其中所述导电介孔碳复合材料具有孔径至少为10nm至高达50nm的介孔的至少一部分，并且其中所述介孔为 或者当所述导电性碳纳米颗粒彼此熔合时或两者都是由所述导电性碳纳米颗粒的表面划定的间隔。 还描述了用于生产上述复合材料的方法，包括它们的装置（例如锂电池）及其使用方法。
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公开(公告)号：US20100297389A1
公开(公告)日：2010-11-25
申请号：US12468946
申请日：2009-05-20
申请人： Sheng Dai , Xiqing Wang
发明人： Sheng Dai , Xiqing Wang
CPC分类号： C04B38/0022 , C01B32/00 , C04B35/524 , C04B35/62218 , C04B2111/00793 , C04B2111/0081 , C04B2111/00853 , C04B2235/48 , Y10S977/755 , Y10T428/24165 , Y10T428/249967 , Y10T428/249978 , Y10T428/249979 , C04B38/0054 , C04B38/062
摘要： The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than −2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.
摘要翻译： 本发明涉及一种制备中孔碳材料的方法，所述方法包括使前体组合物经历固化步骤，随后进行碳化步骤，所述前体组合物包含：（i）由嵌段共聚物组成的模板组分，（ii ）酚类化合物或材料，（iii）可交联的醛组分，和（iv）至少0.5M浓度的pKa或小于-2的强酸，其中所述碳化步骤包括在碳化作用下加热前体组合物 温度足以将前体组合物转化成介孔碳材料。 本发明还涉及具有改进的热稳定性的中孔碳材料，优选根据上述方法制备。
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公开(公告)号：US08513319B2
公开(公告)日：2013-08-20
申请号：US13353722
申请日：2012-01-19
申请人： Sheng Dai , Xiqing Wang
发明人： Sheng Dai , Xiqing Wang
CPC分类号： C04B38/0022 , C01B32/00 , C04B35/524 , C04B35/62218 , C04B2111/00793 , C04B2111/0081 , C04B2111/00853 , C04B2235/48 , Y10S977/755 , Y10T428/24165 , Y10T428/249967 , Y10T428/249978 , Y10T428/249979 , C04B38/0054 , C04B38/062
摘要： The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than −2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.
摘要翻译： 本发明涉及一种制备中孔碳材料的方法，所述方法包括使前体组合物经历固化步骤，随后进行碳化步骤，所述前体组合物包含：（i）由嵌段共聚物组成的模板组分，（ii ）酚类化合物或材料，（iii）可交联的醛组分，和（iv）至少0.5M浓度的pKa或小于-2的强酸，其中所述碳化步骤包括在碳化作用下加热前体组合物 温度足以将前体组合物转化成介孔碳材料。 本发明还涉及具有改进的热稳定性的中孔碳材料，优选根据上述方法制备。
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公开(公告)号：US20130183511A1
公开(公告)日：2013-07-18
申请号：US13349162
申请日：2012-01-12
申请人： Sheng Dai , Pasquale Fernando Fulvio , Richard T. Mayes , Xiqing Wang , Xiao-Guang Sun , Bingkun Guo
发明人： Sheng Dai , Pasquale Fernando Fulvio , Richard T. Mayes , Xiqing Wang , Xiao-Guang Sun , Bingkun Guo
CPC分类号： H01B1/04 , B01J20/20 , B01J20/205 , B01J20/28026 , B01J20/28083 , B01J20/282 , B01J20/3078 , B82Y30/00 , B82Y40/00 , C01B32/00 , C04B35/521 , C04B35/524 , C04B35/83 , C04B38/0032 , C04B2111/00853 , C04B2111/94 , C04B2235/422 , C04B2235/424 , C04B2235/48 , C04B2235/52 , C04B2235/5288 , C04B2235/5454 , Y10T428/249978 , Y10T428/249979 , Y10T428/249986 , C04B38/0064
摘要： A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.
摘要翻译： 一种导电介孔碳复合材料，其包含介于中孔碳基体内的导电碳纳米颗粒，其中所述导电介孔碳复合材料具有孔径至少为10nm至高达50nm的介孔的至少一部分，并且其中所述介孔为 或者当所述导电性碳纳米颗粒彼此熔合时或两者都是由所述导电性碳纳米颗粒的表面划定的间隔。 还描述了用于生产上述复合材料的方法，包括它们的装置（例如锂电池）及其使用方法。
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公开(公告)号：US08114510B2
公开(公告)日：2012-02-14
申请号：US12468946
申请日：2009-05-20
申请人： Sheng Dai , Xiqing Wang
发明人： Sheng Dai , Xiqing Wang
IPC分类号： B32B3/26
CPC分类号： C04B38/0022 , C01B32/00 , C04B35/524 , C04B35/62218 , C04B2111/00793 , C04B2111/0081 , C04B2111/00853 , C04B2235/48 , Y10S977/755 , Y10T428/24165 , Y10T428/249967 , Y10T428/249978 , Y10T428/249979 , C04B38/0054 , C04B38/062
摘要： The invention is directed to a method for fabricating a mesoporous carbon material, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic compound or material, (iii) a crosslinkable aldehyde component, and (iv) at least 0.5 M concentration of a strong acid having a pKa of or less than −2, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a mesoporous carbon material. The invention is also directed to a mesoporous carbon material having an improved thermal stability, preferably produced according to the above method.
摘要翻译： 本发明涉及一种制备中孔碳材料的方法，所述方法包括使前体组合物经历固化步骤，随后进行碳化步骤，所述前体组合物包含：（i）由嵌段共聚物组成的模板组分，（ii ）酚类化合物或材料，（iii）可交联的醛组分，和（iv）至少0.5M浓度的pKa或小于-2的强酸，其中所述碳化步骤包括在碳化作用下加热前体组合物 温度足以将前体组合物转化成介孔碳材料。 本发明还涉及具有改进的热稳定性的中孔碳材料，优选根据上述方法制备。
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公开(公告)号：US20110177428A1
公开(公告)日：2011-07-21
申请号：US12690224
申请日：2010-01-20
申请人： Sheng Dai , Huimin Luo , Gary A. Baker
发明人： Sheng Dai , Huimin Luo , Gary A. Baker
IPC分类号： H01M8/08
CPC分类号： C08J5/2256 , C08J2379/08 , H01B1/122 , H01M8/0289 , H01M8/0295 , H01M2300/0045
摘要： Protic ionic liquids having a composition of formula (A−)(BH+) wherein A− is a conjugate base of an acid HA, and BH+ is a conjugate acid of a superbase B. In particular embodiments, BH+ is selected from phosphazenium species and guanidinium species encompassed, respectively, by the general formulas: The invention is also directed to films and membranes containing these protic ionic liquids, with particular application as proton exchange membranes for fuel cells.
摘要翻译： 具有式（A - ）（BH +）组成的促进离子液体，其中A-是酸性HA的共轭碱，BH +是超级碱基B的共轭酸。在具体实施方案中，BH +选自磷腈化合物和胍 物质分别由以下通式表示：本发明还涉及含有这些质子离子液体的膜和膜，特别用作燃料电池的质子交换膜。
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公开(公告)号：US20110140296A1
公开(公告)日：2011-06-16
申请号：US13011554
申请日：2011-01-21
申请人： Sheng Dai , Georges A. Guiochon , Chengdu Liang
发明人： Sheng Dai , Georges A. Guiochon , Chengdu Liang
IPC分类号： C01B31/16
CPC分类号： C01B31/02 , B01J20/20 , B01J20/28004 , B01J20/28042 , B01J20/28078 , B01J20/28083 , B01J20/28085 , B01J20/282 , B01J2220/82 , C01B32/00 , C01B32/05 , C04B38/045 , C04B38/0615 , C04B35/52 , C04B38/0022 , C04B38/0064
摘要： A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores
摘要翻译： 碳整料包括具有至少100nm的骨架尺寸的坚固的碳整料，以及具有大孔和中孔的分级孔结构
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公开(公告)号：US07857993B2
公开(公告)日：2010-12-28
申请号：US10940054
申请日：2004-09-14
CPC分类号： C09K11/02 , B82Y10/00 , B82Y30/00 , C09K11/06 , C09K11/565 , C09K11/883 , G21K4/00
摘要： Applicant's present invention is a composite scintillator having enhanced transparency for detecting ionizing radiation comprising a material having optical transparency wherein said material comprises nano-sized objects having a size in at least one dimension that is less than the wavelength of light emitted by the composite scintillator wherein the composite scintillator is designed to have selected properties suitable for a particular application.
摘要翻译： 申请人的本发明是具有增强的用于检测电离辐射的透射度的复合闪烁体，其包括具有光学透明度的材料，其中所述材料包括具有小于复合闪烁体发射的光的至少一个尺寸的尺寸的纳米尺寸物体，其中 复合闪烁体被设计成具有适合于特定应用的选定特性。
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公开(公告)号：US07772150B2
公开(公告)日：2010-08-10
申请号：US11742652
申请日：2007-05-01
申请人： Gabriel M. Vieth , Nancy J. Dudney , Sheng Dai
发明人： Gabriel M. Vieth , Nancy J. Dudney , Sheng Dai
IPC分类号： B01J20/00 , B01J23/02 , B01J23/40 , B01J23/42 , B01J23/70 , B01J37/00 , C08F4/60 , C08K9/02 , C08J3/00 , C08K3/08 , H01B1/22
CPC分类号： B01J23/42 , B01J35/0013 , B01J35/04 , B82Y30/00 , Y10T428/249953
摘要： A method to prepare porous medium decorated with nanoparticles involves contacting a suspension of nanoparticles in an ionic liquid with a porous medium such that the particles diffuse into the pores of the medium followed by heating the resulting composition to a temperature equal to or greater than the thermal decomposition temperature of the ionic liquid resulting in the removal of the liquid portion of the suspension. The nanoparticles can be a metal, an alloy, or a metal compound. The resulting compositions can be used as catalysts, sensors, or separators.
摘要翻译： 制备用纳米颗粒装饰的多孔介质的方法包括将离子液体中的纳米颗粒的悬浮液与多孔介质接触，使得颗粒扩散到介质的孔中，然后将所得组合物加热到等于或大于热 离子液体的分解温度导致悬浮液的液体部分的除去。 纳米颗粒可以是金属，合金或金属化合物。 所得组合物可用作催化剂，传感器或分离器。
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