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公开(公告)号:US08231975B2
公开(公告)日:2012-07-31
申请号:US13235817
申请日:2011-09-19
IPC分类号: B32B27/00
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/302 , C08G18/792 , C09D175/04 , D06M2200/11 , D06M2200/12 , Y10T428/3154 , Y10T428/31544 , Y10T428/31551
摘要: A polymer having at least one urea linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2CF2)p(CH2CH2)q(R1)r—XH Formula (I) wherein p and q are each independently an integer of 1 to 3; r is 0 or 1; X is —O—, —NH— or —S—; R1 is a divalent radical selected from the group consisting of —S(CH2)n—, n is an integer of 2 to 4; s is an integer of 1 to 50; R2, R3, and R4 are each independently hydrogen or an alkyl group containing 1 to 6 carbon atoms; and Rf is a perfluoroalkyl group having 1 to 6 carbon atoms; and (i) reacting with (c) water, a linking agent, or a mixture thereof and methods for treating substrates therewith.
摘要翻译: 具有至少一个尿素键的聚合物,其通过以下步骤制备:(i)使(a)至少一种具有异氰酸酯基的二异氰酸酯,多异氰酸酯或其混合物,和(b)至少一种选自式(I)的氟化化合物: Rf(CH 2 CF 2)p(CH 2 CH 2)q(R 1)r -XH式(I)其中p和q各自独立地为1〜3的整数; r为0或1; X是-O - , - NH-或-S-; R 1是选自-S(CH 2)n - ,n是2至4的整数的二价基团; s为1〜50的整数; R2,R3和R4各自独立地为氢或含有1至6个碳原子的烷基; Rf为碳原子数1〜6的全氟烷基; 和(i)与(c)水,连接剂或其混合物反应和用于处理底物的方法。
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公开(公告)号:US08129567B2
公开(公告)日:2012-03-06
申请号:US13093295
申请日:2011-04-25
IPC分类号: C08F9/28
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/792 , D06M2200/11 , D06M2200/12 , Y10T428/2933 , Y10T428/31551 , Y10T428/31558 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31591 , Y10T442/198
摘要: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH Formula (I) wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
摘要翻译: 提供对包含含有至少一个脲键的聚合物的基材的表面效果的组合物,其通过以下步骤制备:(i)使(1)至少一种有机二硫氰酸酯,多异氰酸酯或其混合物反应,和(2)至少一种式I的含氟化合物 Rf-O(CF 2 CF 2)r(CH 2 CH 2)q(R 1)s X H式(I)其中R f是任选被一至三个氧原子间隔的直链或支链C 1至C 7全氟烷基,r为1至3,q为1至3 ,s为0或1,X为O,S或NR 2,其中R 2为H或C 1至C 6烷基,R 1为选自-S(CH 2)n - ,p为1至50的二价基团,R 3为 ,R 4和R 5各自独立地为H或C 1至C 6烷基; (ii),然后与(3)水,连接剂或其混合物反应。
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公开(公告)号:US08048953B2
公开(公告)日:2011-11-01
申请号:US11598337
申请日:2006-11-13
IPC分类号: C08G18/08
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/302 , C08G18/792 , C09D175/04 , D06M2200/11 , D06M2200/12 , Y10T428/3154 , Y10T428/31544 , Y10T428/31551
摘要: A polymer having at least one urea linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2CF2)p(CH2CH2)q(R1)r—XH Formula (I) wherein p and q are each independently an integer of 1 to 3; r is 0 or 1; X is —O—, —NH— or —S—; R1 is a divalent radical selected from the group consisting of —S(CH2)n—, n is an integer of 2 to 4; s is an integer of 1 to 50; R2, R3, and R4 are each independently hydrogen or an alkyl group containing 1 to 6 carbon atoms; and Rf is a linear or branched chain perfluoroalkyl group having 1 to 6 carbon atoms; and (ii) reacting with (c) water, a linking agent, or a mixture thereof and methods for treating substrates to obtain surface effects is disclosed.
摘要翻译: 具有至少一个尿素键的聚合物,其通过以下步骤制备:(i)使(a)至少一种具有异氰酸酯基的二异氰酸酯,多异氰酸酯或其混合物,和(b)至少一种选自式(I)的氟化化合物: Rf(CH 2 CF 2)p(CH 2 CH 2)q(R 1)r -XH式(I)其中p和q各自独立地为1〜3的整数; r为0或1; X是-O - , - NH-或-S-; R 1是选自-S(CH 2)n - ,n是2至4的整数的二价基团; s为1〜50的整数; R2,R3和R4各自独立地为氢或含有1至6个碳原子的烷基; Rf为碳原子数1〜6的直链或支链全氟烷基; 和(ii)与(c)水,连接剂或其混合物反应,以及用于处理底物以获得表面效果的方法。
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公开(公告)号:US20120070580A1
公开(公告)日:2012-03-22
申请号:US13235817
申请日:2011-09-19
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/302 , C08G18/792 , C09D175/04 , D06M2200/11 , D06M2200/12 , Y10T428/3154 , Y10T428/31544 , Y10T428/31551
摘要: A polymer having at least one urea linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2CF2)p(CH2CH2)qR1)r—XH Formula (I) wherein p and q are each independently an integer of 1 to 3; r is 0 or 1; X is —O—, —NH— or —S—; R1 is a divalent radical selected from the group consisting of —S(CH2)n—, n is an integer of 2 to 4; s is an integer of 1 to 50; R2, R3, and R4 are each independently hydrogen or an alkyl group containing 1 to 6 carbon atoms; and Rf is a perfluoroalkyl group having 1 to 6 carbon atoms; and (i) reacting with (c) water, a linking agent, or a mixture thereof and methods for treating substrates therewith.
摘要翻译: 具有至少一个尿素键的聚合物,其通过以下步骤制备:(i)使(a)至少一种具有异氰酸酯基的二异氰酸酯,多异氰酸酯或其混合物,和(b)至少一种选自式(I)的氟化化合物: Rf(CH 2 CF 2)p(CH 2 CH 2)q R 1)r -XH式(I)其中p和q各自独立地为1至3的整数; r为0或1; X是-O - , - NH-或-S-; R 1是选自-S(CH 2)n - ,n是2至4的整数的二价基团; s为1〜50的整数; R2,R3和R4各自独立地为氢或含有1至6个碳原子的烷基; Rf为碳原子数1〜6的全氟烷基; 和(i)与(c)水,连接剂或其混合物反应和用于处理底物的方法。
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公开(公告)号:US20110200820A1
公开(公告)日:2011-08-18
申请号:US13093295
申请日:2011-04-25
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/792 , D06M2200/11 , D06M2200/12 , Y10T428/2933 , Y10T428/31551 , Y10T428/31558 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31591 , Y10T442/198
摘要: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH Formula (I) wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
摘要翻译: 提供对包含含有至少一个脲键的聚合物的基材的表面效果的组合物,其通过以下步骤制备:(i)使(1)至少一种有机二硫氰酸酯,多异氰酸酯或其混合物反应,和(2)至少一种式I的含氟化合物 Rf-O(CF 2 CF 2)r(CH 2 CH 2)q(R 1)s X H式(I)其中R f是任选被一至三个氧原子间隔的直链或支链C 1至C 7全氟烷基,r为1至3,q为1至3 ,s为0或1,X为O,S或NR 2,其中R 2为H或C 1至C 6烷基,R 1为选自-S(CH 2)n - ,p为1至50的二价基团,R 3为 ,R 4和R 5各自独立地为H或C 1至C 6烷基; (ii),然后与(3)水,连接剂或其混合物反应。
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公开(公告)号:US07956124B2
公开(公告)日:2011-06-07
申请号:US12274404
申请日:2008-11-20
IPC分类号: C08K3/00
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/792 , D06M2200/11 , D06M2200/12 , Y10T428/2933 , Y10T428/31551 , Y10T428/31558 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31591 , Y10T442/198
摘要: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH Formula (I) wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
摘要翻译: 提供对包含含有至少一个脲键的聚合物的基材的表面效果的组合物,其通过以下步骤制备:(i)使(1)至少一种有机二硫氰酸酯,多异氰酸酯或其混合物反应,和(2)至少一种式I的含氟化合物 Rf-O(CF 2 CF 2)r(CH 2 CH 2)q(R 1)s X H式(I)其中R f是任选被一至三个氧原子间隔的直链或支链C 1至C 7全氟烷基,r为1至3,q为1至3 ,s为0或1,X为O,S或NR 2,其中R 2为H或C 1至C 6烷基,R 1为选自-S(CH 2)n - ,p为1至50的二价基团,R 3为 ,R 4和R 5各自独立地为H或C 1至C 6烷基; (ii),然后与(3)水,连接剂或其混合物反应。
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公开(公告)号:US20090072183A1
公开(公告)日:2009-03-19
申请号:US12274404
申请日:2008-11-20
IPC分类号: D06M15/687 , C08G18/28
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/792 , D06M2200/11 , D06M2200/12 , Y10T428/2933 , Y10T428/31551 , Y10T428/31558 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31591 , Y10T442/198
摘要: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH Formula (I) wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
摘要翻译: (i)使(1)至少一种有机二硫氰酸酯,多异氰酸酯或其混合物反应制备的至少一种尿素键的聚合物,和 Rf-O(CF2CF2)r(CH2CH2)q(R1)sXH式(I)<?in-line-formula description =“In-line-formula” “直链式”末端=“尾”→其中R f为任选被一至三个氧原子间隔的直链或支链C1至C7全氟烷基,r为1至3,q为1至3,s为0或1 ,X为O,S或NR 2,其中R 2为H或C 1至C 6烷基,R 1为选自-S(CH 2)n - 的二价基团,p为1至50,且R 3,R 4和R 5为 独立地为H或C 1至C 6烷基; (ii),然后与(3)水,连接剂或其混合物反应。
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公开(公告)号:US07470745B2
公开(公告)日:2008-12-30
申请号:US11598333
申请日:2006-11-13
IPC分类号: C08K3/00
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/792 , D06M2200/11 , D06M2200/12 , Y10T428/2933 , Y10T428/31551 , Y10T428/31558 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31591 , Y10T442/198
摘要: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH Formula (I) wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
摘要翻译: (i)使(1)至少一种有机二硫氰酸酯,多异氰酸酯或其混合物反应制备的至少一种尿素键的聚合物,和 Rf-O(CF2CF2)r(CH2CH2)q(R1)sXH式(I)<?in-line-formula description =“In-line-formula” “直链式”末端=“尾”→其中R f为任选被一至三个氧原子间隔的直链或支链C1至C7全氟烷基,r为1至3,q为1至3,s为0或1 ,X为O,S或NR 2,其中R 2为H或C 1至C 6烷基,R 1为选自-S(CH 2)n - 的二价基团,p为1至50,且R 3,R 4和R 5为 独立地为H或C 1至C 6烷基; (ii),然后与(3)水,连接剂或其混合物反应。
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公开(公告)号:US20080114147A1
公开(公告)日:2008-05-15
申请号:US11598337
申请日:2006-11-13
IPC分类号: C08G18/00
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/302 , C08G18/792 , C09D175/04 , D06M2200/11 , D06M2200/12 , Y10T428/3154 , Y10T428/31544 , Y10T428/31551
摘要: A polymer having at least one urea linkage prepared by: (i) reacting (a) at least one diisocyanate, polyisocyanate, or mixture thereof, having isocyanate groups, and (b) at least one fluorinated compound selected from the formula (I): Rf(CH2CF2)p(CH2CH2)q(R1)r—XH Formula (I) wherein p and q are each independently an integer of 1 to 3; r is 0 or 1; X is —O—, —NH— or —S—; R1 is a divalent radical selected from the group consisting of —S(CH2)n—, n is an integer of 2 to 4; s is an integer of 1 to 50; R2, R3, and R4 are each independently hydrogen or an alkyl group containing 1 to 6 carbon atoms; and Rf is a linear or branched chain perfluoroalkyl group having 1 to 6 carbon atoms; and (ii) reacting with (c) water, a linking agent, or a mixture thereof and methods for treating substrates to obtain surface effects is disclosed.
摘要翻译: 具有至少一个尿素键的聚合物,其通过以下步骤制备:(i)使(a)至少一种具有异氰酸酯基团的二异氰酸酯,多异氰酸酯或其混合物,和(b)至少一种选自式(I)的氟化化合物: <?in-line-formula description =“In-line Formulas”end =“lead”?> R sub>(CH 2 2 CF 2) (CH 2)CH 2(CH 2)n(CH 2) 其中p和q各自独立地为1〜3的整数,其中p和q各自独立地为1〜3的整数。 r为0或1; X是-O - , - NH-或-S-; R 1是选自-S(CH 2)n - n - ,n是2至4的整数的二价基团 ; s为1〜50的整数; R 2,R 3,R 4和R 4各自独立地为氢或含有1至6个碳原子的烷基; 且R 1是具有1至6个碳原子的直链或支链全氟烷基; 和(ii)与(c)水,连接剂或其混合物反应,以及用于处理底物以获得表面效果的方法。
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公开(公告)号:US20080113199A1
公开(公告)日:2008-05-15
申请号:US11598333
申请日:2006-11-13
CPC分类号: D06M15/576 , C08G18/283 , C08G18/2885 , C08G18/792 , D06M2200/11 , D06M2200/12 , Y10T428/2933 , Y10T428/31551 , Y10T428/31558 , Y10T428/31562 , Y10T428/31565 , Y10T428/31573 , Y10T428/31591 , Y10T442/198
摘要: A composition which provides surface effects to substrates comprising a polymer containing at least one urea linkage prepared by (i) reacting (1) at least one organic diioscyanate, polyisocyanate, or mixture thereof, and (2) at least one fluorochemical compound of Formula I Rf—O(CF2CF2)r(CH2CH2)q(R1)sXH Formula (I) wherein Rf is a linear or branched C1 to C7 perfluoroalkyl optionally interrupted by one to three oxygen atoms, r is 1 to 3, q is 1 to 3, s is 0 or 1, X is O, S, or NR2 wherein R2 is H, or C1 to C6 alkyl, and R1 is a divalent radical selected from —S(CH2)n—, p is 1 to 50, and R3, R4 and R5 are each independently H or C1 to C6 alkyl; (ii) and then reacting with (3) water, a linking agent, or a mixture thereof.
摘要翻译: 提供对包含含有至少一个脲键的聚合物的基材的表面效果的组合物,其通过以下步骤制备:(i)使(1)至少一种有机二硫氰酸酯,多异氰酸酯或其混合物反应,和(2)至少一种式I的含氟化合物 <?in-line-formula description =“In-line Formulas”end =“lead”?> R&lt; f&gt; -O(CF 2 2 CF 2) (CH 2)q(CH 2)2(CH 2)n(CH 2) XH式(I)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中R≠直链或支链 C 1至C 7全氟烷基,任选被一至三个氧原子间隔,r为1至3,q为1至3,s为0或1,X为O ,S或NR 2其中R 2为H或C 1至C 6烷基,且R 1是选自-S(CH 2)n - ,p是1至50,R 3, R 4,R 4和R 5各自独立地为H o R C 1至C 6烷基; (ii),然后与(3)水,连接剂或其混合物反应。
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