摘要:
Provided are a stainless steel for a proton-exchange membrane fuel cell separator having high durability and a low contact resistance (i.e., high electrical conductivity) and a proton-exchange membrane fuel cell using the same. More specifically, a stainless steel for a proton-exchange membrane fuel cell separator has a composition comprising 0.03% mass % or less of C, 16-45 mass % of Cr, 0.03 mass % or less of N, 0.1-5.0 mass % of Mo, wherein a total of the C content and the N content satisfies 0.03 mass % or less; a balance portion is comprised of Fe and unavoidable impurities; an atomic ratio of Cr/Fe with respect to Al, Cr, and Fe contained in a passive film on a surface of the stainless steel is 1 or greater.
摘要:
Provided are a stainless steel for a proton-exchange membrane fuel cell separator having high durability and a low contact resistance (i.e., high electrical conductivity) and a proton-exchange membrane fuel cell using the same. More specifically, a stainless steel for a proton-exchange membrane fuel cell separator has a composition comprising 0.03% mass % or less of C, 16-45 mass % of Cr, 0.03 mass % or less of N, 0.1-5.0 mass % of Mo, wherein a total of the C content and the N content satisfies 0.03 mass % or less; a balance portion is comprised of Fe and unavoidable impurities; an atomic ratio of Cr/Fe with respect to Al, Cr, and Fe contained in a passive film on a surface of the stainless steel is 1 or greater.
摘要:
An inexpensive metallic material for interconnects of solid-oxide fuel cells, a fuel cell using the metallic material, and a method for producing the metallic material having excellent oxidation resistance and spalling resistance of an oxide layer, high electrical conductivity, and a small difference in thermal expansion from an electrolyte. Specifically, 0.20 percent by mass or less of C, 0.02 to 1.0 percent by mass of Si, 2.0 percent by mass or less of Mn, 10 to 40 percent by mass of Cr, 0.03 to 5.0 percent by mass of Mo, 0.1 to 3.0 percent by mass of Nb, and at least one element selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Zr, and Hf in a total of 1.0 percent by mass or less are added so as to satisfy 0.1≦Mo/Nb≦30, for decreasing the growth rate of the oxide layer and improving the spalling resistance.
摘要翻译:用于固体氧化物燃料电池的互连的廉价的金属材料,使用金属材料的燃料电池以及氧化物层具有优异的耐氧化性和耐剥离性的金属材料的制造方法,高导电性和小的差异 电解液的热膨胀。 具体地,将0.20质量%以下的C,0.02〜1.0质量%的Si,2.0质量%以下的Mn,10〜40质量%的Cr,0.03〜5.0质量%的Mo,0.1〜3.0 添加Nb的质量百分比,以及选自Sc,Y,La,Ce,Pr,Nd,Pm,Sm,Zr和Hf中的至少一种元素总计为1.0质量%以下。 为了满足0.1 <= Mo / Nb <= 30,为了降低氧化物层的生长速度和提高耐剥离性。
摘要:
The present invention provides an inexpensive metallic material for interconnects of solid-oxide fuel cells, a fuel cell using the metallic material, and a method for producing the metallic material having excellent oxidation resistance and spalling resistance of an oxide layer, high electrical conductivity, and a small difference in thermal expansion from an electrolyte. Specifically, 0.20 percent by mass or less of C, 0.02 to 1.0 percent by mass of Si, 2.0 percent by mass or less of Mn, 10 to 40 percent by mass of Cr, 0.03 to 5.0 percent by mass of Mo, 0.1 to 3.0 percent by mass of Nb, and at least one element selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Zr, and Hf in a total of 1.0 percent by mass or less are added so as to satisfy 0.1≦Mo/Nb≦30, for decreasing the growth rate of the oxide layer and improving the spalling resistance.
摘要翻译:本发明提供一种用于固体氧化物燃料电池的互连的便宜的金属材料,使用该金属材料的燃料电池以及具有优异的氧化物层的耐氧化性和耐剥离性,高导电性的金属材料的制造方法和 与电解质的热膨胀差异很小。 具体地,将0.20质量%以下的C,0.02〜1.0质量%的Si,2.0质量%以下的Mn,10〜40质量%的Cr,0.03〜5.0质量%的Mo,0.1〜3.0 添加Nb的质量百分比,以及选自Sc,Y,La,Ce,Pr,Nd,Pm,Sm,Zr和Hf中的至少一种元素总计为1.0质量%以下。 为了满足0.1 <= Mo / Nb <= 30,为了降低氧化物层的生长速度和提高耐剥离性。
摘要:
A metallic material for a conductive member has good corrosion resistance and low contact resistance. The metallic material has 0.3 μm or less of mean spacing of local peaks of the surface roughness profile. A proton-exchange membrane fuel cell includes a proton-exchange membrane, an electrode, a gas diffusing layer, and a separator using the metallic material for a conductive member, where the metallic material for a conductive member includes a stainless steel and includes 0.03% or less C, 0.03% or less N, 16 to 45% Cr, 0.1 to 5.0% Mo, 0.03% or less (C+N), by mass, and balance of Fe and inevitable impurities, and where the metallic material for a conductive member has 0.3 μm or less of mean spacing of local peaks of the surface roughness profile.
摘要:
A method of processing a metallic material includes immersing ferritic stainless steel or austenitic stainless steel in an acid solution containing hydrochloric acid in an amount of two times or more relative to the concentration of nitric acid or an acid solution containing hydrofluoric acid in an amount of one and a half times or more relative to the concentration of nitric acid to adjust surface roughness of the metallic material.
摘要:
Provided are: a metallic material for conductive member, having good corrosion resistance and small contact resistance; a separator for a proton-exchange membrane fuel cell using the metallic material; and a proton-exchange membrane fuel cell using the separator. The metallic material has 0.3 μm or less of mean spacing of local peaks of the surface roughness profile.
摘要:
A stainless steel separator having gas channels including grooves and projections for fuel cells. The separator has a composition including about 0.03 mass percent or less of carbon; about 0.03 mass percent or less of nitrogen, the total content of carbon and nitrogen being about 0.03 mass percent or less; about 16 mass percent to about 45 mass percent chromium; about 0.5 mass percent to about 3.0 mass percent molybdenum; and the balance being iron and incidental impurities. The separator has a contact resistance of about 100 m&OHgr;·cm2 or less. Preferably, the projections have an arithmetic average surface roughness Ra in the range of about 0.01 to about 1.0 &mgr;m and a maximum height Ry in the range of about 0.01 to about 20 &mgr;m. The stainless steel separator preferably further includes about 0.001 to about 0.1 mass percent silver. A fuel cell including this separator exhibits a stable output voltage for a long period of time.
摘要:
A ferritic stainless steel sheet for use in automobile fuel tanks and fuel pipes having smooth surface and resistance to organic acid is provided. The sheet contains, by mass, not more than about 0.1% C, not more than about 1.0 Si, not more than about 1.5 % Mn, not more than about 0.06% P, not more than about 0.03% S, about 11% to about 23% Cr, not more than about 2.0% Ni, about 0.5% to about 3.0% Mo, not more than about 1.0% Al, not more than about 0.04% N, at least one of not more than about 0.8% Nb and not more than about 1.0% Ti, and the balance being Fe and unavoidable impurities, satisfying the relationship: 18≦Nb/(C+N)+2Ti/(C+N)≦60, wherein C, N, Nb, and. Ti in the relationship represent the C, N, Nb, and Ti contents by mass percent, respectively. A process for making the same is also provided.
摘要:
A ferritic stainless steel sheet for use in automobile fuel tanks and fuel pipes having smooth surface and resistance to organic acid is provided. The sheet contains, by mass, not more than about 0.1% C, not more than about 1.0 Si, not more than about 1.5% Mn, not more than about 0.06% P, not more than about 0.03% S, about 11% to about 23% Cr, not more than about 2.0% Ni, about 0.5% to about 3.0% Mo, not more than about 1.0% Al, not more than about 0.04% N, at least one of not more than about 0.8% Nb and not more than about 1.0% Ti, and the balance being Fe and unavoidable impurities, satisfying the relationship: 18≦Nb/(C+N)+2Ti/(C+N)≦60, wherein C, N, Nb, and Ti in the relationship represent the C, N, Nb, and Ti contents by mass percent, respectively. A process for making the same is also provided.