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22 条记录 (耗时 0.019 秒)

    Process for preparing monoallylamine
    1.
    发明授权
    Process for preparing monoallylamine 失效
    单烯丙基胺的制备方法

    公开(公告)号：US5208380A

    公开(公告)日：1993-05-04

    申请号：US866268

    申请日：1992-04-13

    申请人： Shinkichi Shimizu ,  Takayuki Shoji ,  Hideki Nakao

    发明人： Shinkichi Shimizu ,  Takayuki Shoji ,  Hideki Nakao

    IPC分类号： C07C209/68

    CPC分类号： C07C209/68

    摘要： A process for preparing monoallylamine represented by the formula (II):CH.sub.2 .dbd.CHCH.sub.2 NH.sub.2 (II)which comprises: catalytically reacting isopropanolamine represented by the formula (I): ##STR1## in a gaseous phase in the presence of a catalyst having dehydrating property. According to the preparation process of the present invention, monoallylamine can be easily obtained in high selectivity and high yield.

    摘要翻译： 一种制备由式（II）表示的单烯丙胺的方法：CH2 = CHCH2NH2（II），其包括：在气相存在下，在催化剂存在下催化反应由式（I）表示的异丙醇胺：（I） 脱水性能。 根据本发明的制备方法，可以容易地以高选择性和高收率获得单烯丙胺。

    Process for preparing nitriles
    2.
    发明授权
    Process for preparing nitriles 失效
    腈类制备方法

    公开(公告)号：US4931561A

    公开(公告)日：1990-06-05

    申请号：US224012

    申请日：1988-07-25

    申请人： Shinkichi Shimizu ,  Takayuki Shoji ,  Kanji Kono ,  Toru Nakaishi

    发明人： Shinkichi Shimizu ,  Takayuki Shoji ,  Kanji Kono ,  Toru Nakaishi

    IPC分类号： C07D213/84 ,  C07D241/24

    CPC分类号： C07D213/84 ,  C07D241/24

    摘要： A heteroaromatic nitrile is prepared in high conversion and yield by catalytically reacting an alkyl-substituted heteroaromatic compound with molecular oxygen and ammonia in the presence of a catalyst having the following composition:Mo(P).sub.x (A).sub.y (B).sub.z (O).sub.w (I)wherein x, y, z and w represent atomic ratios of phosphorus, an element A defined below, an element B defined below and oxygen to molybdenum, respectively and(i) x and z are both 0 (zero), y is from 0.1 to 5, and A is at least one element selected from the group consisting of cerium and tungsten, or(ii) x is from 0.1 to 7, y is from 0 to 5, z is from 0 to 5, A is at least one element selected from the group consisting of cerium, manganese and tungsten, and B is at least one element selected from the group consisting of thallium, titanium, niobium and aluminum, or(iii) x is from 0.5 to 7, y is from 0 to 5, z is from 0.01 to 2. A is at least one element selected from the group consisting of cerium, manganese and tungsten, and B is vanadium,and w is defined from the valencies of molybdenum, phosphorus, the element A, the element B and the values x, y and z.

    Process for producing pyridine bases
    6.
    发明授权
    Process for producing pyridine bases 失效
    制备吡啶碱的方法

    公开(公告)号：US5237068A

    公开(公告)日：1993-08-17

    申请号：US742585

    申请日：1991-08-07

    申请人： Shinkichi Shimizu ,  Nobuyuki Abe ,  Masanori Doba ,  Akira Iguchi

    发明人： Shinkichi Shimizu ,  Nobuyuki Abe ,  Masanori Doba ,  Akira Iguchi

    IPC分类号： C07D213/10

    CPC分类号： C07D213/10

    摘要： The present invention provides a process for producing pyridine bases which comprises reacting an aliphatic aldehyde and/or a ketone with ammonia in the presence of a catalyst in gaseous phase, said catalyst comprising a zeolite containing (a) an element belonging to the platinum group and (b) at least one element selected from the group consisting of the elements of Groups IIB, IIIA and IVA of the periodic table and the having an atomic ratio of Si to elements consisting of Al, B, Fe and/or Ga of about 12 to about 1,000 and a constraint indedx of about 0.8 to about 12.

    摘要翻译： 本发明提供了一种制备吡啶碱的方法，其包括在气相催化剂存在下使脂族醛和/或酮与氨反应，所述催化剂包含含有（a）属于铂族的元素和 （b）选自周期表第IIB，IIIA和IVA族元素中的至少一种元素，并且Si与由Al，B，Fe和/或Ga组成的元素的原子比为约12 约1,000和约0.8至约12的约束值。

    Catalytic process for the production of acrylonitrile
    7.
    发明授权
    Catalytic process for the production of acrylonitrile 失效
    用于生产丙烯腈的催化工艺

    公开(公告)号：US4058547A

    公开(公告)日：1977-11-15

    申请号：US302882

    申请日：1972-11-01

    申请人： Tatsuo Shiraishi ,  Shinkichi Shimizu ,  Hiroshi Ichihashi

    发明人： Tatsuo Shiraishi ,  Shinkichi Shimizu ,  Hiroshi Ichihashi

    IPC分类号： B01J23/887 ,  B01J27/192 ,  C07C120/14

    CPC分类号： C07C253/26 ,  B01J23/8876 ,  B01J27/192 ,  Y02P20/52

    摘要： In the production of acrylonitrile by a vapor phase reaction of propylene, ammonia and oxygen at an elevated temperature, a process which comprises contacting propylene, ammonia and oxygen with a catalyst composition comprising a catalyst system of the formula: Tl.sub.a P.sub.b Mo.sub.c Fe.sub.d Bi.sub.e X.sub.f O.sub.g wherein X represents one or more of the metals, Ni, Mg and Co, and a, b, c, d, e, f and g represent respectively the relative number of atoms of each component; provided that when c is 12, a is 2 or less, but not 0; b is 0 to 5; d is 0.1 to 5; e is 0.1 to 5; f is 2 to 15; and the value of g depends on the number of the other atoms and is usually from 38.3 to 81.5.

    摘要翻译： 在通过丙烯，氨和氧在升高的温度下的气相反应生产丙烯腈的过程中，包括使丙烯，氨和氧与包含下式催化剂体系的催化剂组合物接触的方法：其中X代表一个或多个 更多的金属，Ni，Mg和Co，以及a，b，c，d，e，f和g分别表示各成分的相对原子数。 条件是当c为12时，a为2或更小，但不为0; b为0〜5; d为0.1〜5; e为0.1〜5; f为2〜15; g的值取决于其他原子的数量，通常为38.3〜81.5。

    Method for production of spherical molded product containing titanium oxide
    8.
    发明授权
    Method for production of spherical molded product containing titanium oxide 失效
    含有氧化钛的球形成型体的制造方法

    公开(公告)号：US4321224A

    公开(公告)日：1982-03-23

    申请号：US108712

    申请日：1979-12-31

    申请人： Shinkichi Shimizu ,  Tadao Nishizaki ,  Masabumi Tsuda

    发明人： Shinkichi Shimizu ,  Tadao Nishizaki ,  Masabumi Tsuda

    IPC分类号： B01D53/86 ,  B01J21/06 ,  B01J35/08 ,  D04H3/16

    CPC分类号： B01J21/063 ,  B01D53/8628 ,  B01J21/06 ,  B01J35/08 ,  Y10S264/51

    摘要： A method for the production of a spherical molded product of a titanium oxide composition comprising adding a titanium oxide composition powder and a mist of an aqueous medium to a seed of an inorganic substance, granulating the mixture with a centrifugal fluidizing coating granulator and calcining the resultant spherical product, which is characteristic in that the granulation of the mixture is carried out by adding the titanium oxide composition powder and the aqueous medium in the ratio of addition rate of 1:0.20 to 1:0.35 by weight, whereby there is obtained a spherical molded product having a larger strength with less abrasion. The spherical molded product obtained by the present invention is useful, for instance, as a catalyst carrier or catalyst for the removal of nitrogen oxides from exhaust gases.

    摘要翻译： 一种制备氧化钛组合物的球形模制产品的方法，包括将氧化钛组合物粉末和水性介质雾雾添加到无机物质的种子中，用离心流化涂料造粒机造粒混合物并煅烧所得物 球形产品，其特征在于通过以按重量比为1:0.20至1:0.35的比率加入氧化钛组合物粉末和水性介质来进行混合物的制粒，从而得到球形 具有较大强度和较少磨损的成型产品。 通过本发明获得的球形成型产品可用作例如用于从废气中除去氮氧化物的催化剂载体或催化剂。