公开(公告)号：US06582628B2

公开(公告)日：2003-06-24

申请号：US10151831

申请日：2002-05-21

申请人： Shosaku Kondo ,  Kasuke Ishii ,  Hajime Sato ,  Jeong Chang Lee ,  Noriyuki Suzuki

发明人： Shosaku Kondo ,  Kasuke Ishii ,  Hajime Sato ,  Jeong Chang Lee ,  Noriyuki Suzuki

IPC分类号： H01B104

CPC分类号： H01B1/24 ,  C08J3/203 ,  C08J2327/12 ,  C08K3/04 ,  C08L27/12

摘要： A method for producing an electrically conducting melt-processible fluoropolymer comprising pulverizing a composition of (a) carbon aggregate and (b) coagulum particles of aqueous dispersion polymerized melt-processible fluoropolymer, coating the coagulum particle with the disintegrated particles of carbon black. The preferred composition comprises a structured carbon black such as acetylene black and a melt processible fluoropolymer wherein said melt processible fluoropolymer has two crystallization peaks in a DSC cooling curve when allowed to crystallize from a temperature of not less than its melting point at a cooling rate of 12° C./min; and the ratio of the crystallization peak heights (high temperature side peak/low temperature side peak) is 0.65 or greater; and/or the ratio of the high temperature side crystallization peak area to the total area of the crystallization peaks [high temperature side peak area/(high temperature side peak area+low temperature side peak area)] is 0.18 or greater.

摘要翻译： 一种制造导电的可熔融加工的含氟聚合物的方法，包括将（a）碳骨料和（b）水分散体聚合的可熔融加工的含氟聚合物的凝结物颗粒的组合物粉碎，用碳黑的分解颗粒涂覆凝结物颗粒。 优选的组合物包含结构化炭黑如乙炔黑和可熔融加工的含氟聚合物，其中所述可熔融加工的含氟聚合物在DSC冷却曲线中具有两个结晶峰，当其以不低于其熔点的温度结晶时，以冷却速率 12℃/ min; 结晶峰高（高温侧峰/低温侧峰）的比为0.65以上; 和/或高温侧结晶峰面积与结晶峰的总面积的比[高温侧峰面积/（高温侧峰面积+低温侧峰面积）]为0.18以上。

公开(公告)号：US5397831A

公开(公告)日：1995-03-14

申请号：US69655

申请日：1993-06-01

申请人： Takumi Saito ,  Kasuke Ishii ,  Takao Nishio ,  Susumu Nakamura ,  Matunori Takada ,  Kazuhiro Yamamoto

发明人： Takumi Saito ,  Kasuke Ishii ,  Takao Nishio ,  Susumu Nakamura ,  Matunori Takada ,  Kazuhiro Yamamoto

IPC分类号： C08J3/12 ,  C08J3/20 ,  C08K7/00 ,  C08K7/02 ,  C08L27/12 ,  C08L27/18 ,  C08L87/00 ,  C09D127/12 ,  C09D127/18 ,  C08J5/10 ,  C08K3/10 ,  C08L23/04

CPC分类号： C08L27/18 ,  C08J3/12 ,  C08J2327/18

摘要： This invention provides a tetrafluoroethylene (TFE) copolymer resin powder composition capable, upon rotational lining, of generating a corrosion-resistant, nonstick film, which is a thick film on a metal or a like substrate, essentially free of gas bubbles, and excellent in adhesion and peel resistance. The TFE-copolymer resin powder composition comprises granules which comprise particles of a TFE/perfluoro(alkyl vinyl ether) copolymer (PFA), polyphenylene sulfide (PPS) particles having an average particle size of 0.3-50 .mu.m, and a heat resistant filler. This invention also provides a process for manufacturing the TFE copolymer resin powder composition comprising either (1) granulating a mixture of PFA particles, PPS and a heat resistant filler in the presence of water and an organic liquid, or (2) mixing PFA, PPS, and a heat-resistant filler, compression-molding, and pulverizing.

摘要翻译： 本发明提供一种四氟乙烯（TFE）共聚物树脂粉末组合物，其能够在旋转衬砌时产生耐腐蚀性不粘膜，其是金属等基材上的厚膜，基本上不含气泡，且优异的 附着力和抗剥离性。 TFE共聚物树脂粉末组合物包含颗粒，其包含TFE /全氟（烷基乙烯基醚）共聚物（PFA），平均粒径为0.3-50μm的聚苯硫醚（PPS）颗粒和耐热填料 。 本发明还提供一种制造TFE共聚物树脂粉末组合物的方法，其包括（1）在水和有机液体的存在下制粒PFA颗粒，PPS和耐热填料的混合物，或（2）混合PFA，PPS ，耐热填料，压缩成型和粉碎。