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    METHOD FOR PRODUCING COMPOSITION USING ALCOHOL AS STARTING MATERIAL
    2.
    发明申请
    METHOD FOR PRODUCING COMPOSITION USING ALCOHOL AS STARTING MATERIAL 有权
    使用醇作为起始材料生产组合物的方法

    公开(公告)号：US20100275509A1

    公开(公告)日：2010-11-04

    申请号：US12246386

    申请日：2008-10-06

    申请人： Shuji Sakuma ,  Takashi Tsuchida ,  Tetsuya Yoshioka

    发明人： Shuji Sakuma ,  Takashi Tsuchida ,  Tetsuya Yoshioka

    IPC分类号： C10L1/182

    CPC分类号： C10G3/45 ,  B01J25/02 ,  B01J27/14 ,  B01J35/0006 ,  B01J35/1014 ,  C10G3/47 ,  C10G3/52 ,  C10G45/00 ,  C10G45/32 ,  C10G45/44 ,  C10G2400/02 ,  C10L1/02 ,  Y02P30/20

    摘要： The present invention is to provide compositions comprising organic compounds useful as a chemical industrial material or a fuel composition with the use of an alcohol such as ethanol as a material. It is a method for producing compositions using alcohol as a starting material and comprising: allowing alcohol to contact with an alcohol conversion catalyst such as hydroxyapatite (first step) and conducting a hydrogenation reaction respectively for all reaction products consisting of a liquid phase including alcohols, water and hydrocarbons of 4-12 carbons and a gas phase which is light gas containing paraffins, alcohols and olefins; all liquid phase reaction products consisting of all reaction products from which light gas has been removed; a liquid phase dehydration reaction products consisting of all reaction products from which light gas, unreacted alcohol and product water have been removed; and light gas (second step).

    摘要翻译： 本发明提供包含可用作化学工业材料的有机化合物或使用醇如乙醇作为材料的燃料组合物的组合物。 它是以醇为原料制备组合物的方法，其包括：使醇与醇转化催化剂如羟基磷灰石接触（第一步），并分别对由包括醇的液相组成的所有反应产物进行氢化反应， 4-12个碳原子的水和碳氢化合物，以及含有链烷烃，醇和烯烃的轻质气体的气相; 由所有反应产物组成的所有液相反应产物都被除去; 由除去轻质气体，未反应的醇和产物水的所有反应产物组成的液相脱水反应产物; 和轻气（第二步）。

    METHOD OF SYNTHESIZING CHEMICAL INDUSTRY RAW MATERIALS AND FUEL COMPOSITIONS
    4.
    发明申请
    METHOD OF SYNTHESIZING CHEMICAL INDUSTRY RAW MATERIALS AND FUEL COMPOSITIONS 审中-公开
    合成化学工业原料和燃料组合物的方法

    公开(公告)号：US20090056204A1

    公开(公告)日：2009-03-05

    申请号：US12198059

    申请日：2008-08-25

    申请人： Takashi Tsuchida ,  Shuji Sakuma ,  Tetsuya Yoshioka ,  Jun Kubo

    发明人： Takashi Tsuchida ,  Shuji Sakuma ,  Tetsuya Yoshioka ,  Jun Kubo

    IPC分类号： C10L1/18

    CPC分类号： C07C29/34 ,  C07C31/12 ,  C07C31/10 ,  C07C31/125

    摘要： The present invention is to provide a novel method for manufacturing various organic compounds from 2 or more kinds of alcohol, or 1 kind of alcohol having 3 or more carbon atoms. It is a method for synthesizing 1 kind of, or 2 or more kinds of organic compounds comprising allowing 2 or more kinds of alcohol or 1 kind of alcohol having 3 or more carbon atoms to contact hydroxyapatite (except those supporting metal catalysts or metal ion catalysts acting on alcohol).

    摘要翻译： 本发明提供一种由2种以上的醇或1种具有3个以上碳原子的醇制造各种有机化合物的新方法。 合成1种或2种以上有机化合物的方法，包括使2种以上的醇或1种具有3个以上碳原子的醇与羟基磷灰石接触（除载体金属催化剂或金属离子催化剂 作用于酒精）。

    Method of synthesizing chemical industry raw materials and fuel compositions
    5.
    发明授权
    Method of synthesizing chemical industry raw materials and fuel compositions 有权
    化学工业原料与燃料成分合成方法

    公开(公告)号：US08603201B2

    公开(公告)日：2013-12-10

    申请号：US12391254

    申请日：2009-02-23

    申请人： Takashi Tsuchida ,  Shuji Sakuma ,  Tetsuya Yoshioka ,  Jun Kubo

    发明人： Takashi Tsuchida ,  Shuji Sakuma ,  Tetsuya Yoshioka ,  Jun Kubo

    IPC分类号： C07C29/34 ,  C10L1/18

    CPC分类号： C07B61/00 ,  C07C29/34 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125

    摘要： The present invention is to provide a novel method for manufacturing various organic compounds from two or more kinds of alcohol, or one kind of alcohol having three or more carbon atoms. It is a method for synthesizing one kind of, or two or more kinds of organic compounds comprising allowing two or more kinds of alcohol or one kind of alcohol having three or more carbon atoms to contact a calcium phosphate catalyst such as hydroxyapatite, or hydrotalcite.

    摘要翻译： 本发明提供一种由两种或更多种醇或一种具有三个或更多个碳原子的醇制备各种有机化合物的新方法。 它是合成一种或两种或更多种有机化合物的方法，包括使两种或更多种醇或一种具有三个或更多个碳原子的醇接触磷酸钙催化剂如羟基磷灰石或水滑石。

    Method for producing composition using alcohol as starting material
    6.
    发明授权
    Method for producing composition using alcohol as starting material 有权
    使用醇作为起始原料生产组合物的方法

    公开(公告)号：US08187347B2

    公开(公告)日：2012-05-29

    申请号：US12246386

    申请日：2008-10-06

    申请人： Shuji Sakuma ,  Takashi Tsuchida ,  Tetsuya Yoshioka

    发明人： Shuji Sakuma ,  Takashi Tsuchida ,  Tetsuya Yoshioka

    IPC分类号： C10L1/18

    CPC分类号： C10G3/45 ,  B01J25/02 ,  B01J27/14 ,  B01J35/0006 ,  B01J35/1014 ,  C10G3/47 ,  C10G3/52 ,  C10G45/00 ,  C10G45/32 ,  C10G45/44 ,  C10G2400/02 ,  C10L1/02 ,  Y02P30/20

    摘要： The present invention is to provide compositions comprising organic compounds useful as a chemical industrial material or a fuel composition with the use of an alcohol such as ethanol as a material. It is a method for producing compositions using alcohol as a starting material and comprising: allowing alcohol to contact with an alcohol conversion catalyst such as hydroxyapatite (first step) and conducting a hydrogenation reaction respectively for all reaction products consisting of a liquid phase including alcohols, water and hydrocarbons of 4-12 carbons and a gas phase which is light gas containing paraffins, alcohols and olefins; all liquid phase reaction products consisting of all reaction products from which light gas has been removed; a liquid phase dehydration reaction products consisting of all reaction products from which light gas, unreacted alcohol and product water have been removed; and light gas (second step).

    摘要翻译： 本发明提供包含可用作化学工业材料的有机化合物或使用醇如乙醇作为材料的燃料组合物的组合物。 它是以醇为原料制备组合物的方法，其包括：使醇与醇转化催化剂如羟基磷灰石接触（第一步），并分别对由包括醇的液相组成的所有反应产物进行氢化反应， 4-12个碳原子的水和碳氢化合物，以及含有链烷烃，醇和烯烃的轻质气体的气相; 由所有反应产物组成的所有液相反应产物都被除去; 由除去轻质气体，未反应的醇和产物水的所有反应产物组成的液相脱水反应产物; 和轻气（第二步）。

    Method of synthesizing higher-molecular alcohol
    8.
    发明授权
    Method of synthesizing higher-molecular alcohol 有权
    合成高分子醇的方法

    公开(公告)号：US08080695B2

    公开(公告)日：2011-12-20

    申请号：US11757588

    申请日：2007-06-04

    申请人： Takashi Tsuchida ,  Shuji Sakuma

    发明人： Takashi Tsuchida ,  Shuji Sakuma

    IPC分类号： C07C31/02

    CPC分类号： C07C29/34 ,  C07C31/12

    摘要： The present invention provides a production method with which high molecular alcohols having an even number of carbon atoms such as 1-butanol, hexanol, octanol and decanol, and a mixture of these are efficiently collected through clean processes with the use of ethanol as a raw material. High molecular alcohols are produced from ethanol by using calcium phosphate-based compounds such as hydroxyapatite Ca10(PO4)6(OH)2, tricalcium phosphate Ca3(PO4)2, calcium monohydrogen phosphate CaHPO4.(0˜2)H2O, calcium diphosphate Ca2P2O7, octacalcium phosphate Ca8H2(PO4)6.5H2O, tetracalcium phosphate Ca4(PO4)2O or amorphous calcium phosphate Ca3(PO4)2. nH2O as a catalyst, using ethanol as a starting material, and setting a contact time at 0.4 second or longer.

    摘要翻译： 本发明提供一种制备方法，通过使用乙醇作为原料，通过清洁方法有效地收集具有偶数个碳原子的高分子醇如1-丁醇，己醇，辛醇和癸醇，以及它们的混合物 材料。 高分子醇通过使用磷酸钙基化合物如羟基磷灰石Ca10（PO4）6（OH）2，磷酸三钙Ca3（PO4）2，磷酸一氢钙CaHPO 4（0-2）H 2 O，二磷酸钙Ca 2 P 2 O 7 ，磷酸三钙Ca8H2（PO4）6.5H2O，磷酸四钙Ca4（PO4）2O或无定形磷酸钙Ca3（PO4）2。 nH 2 O作为催化剂，使用乙醇作为原料，并将接触时间设定为0.4秒以上。

    Method of Synthesizing Higher-Molecular Alcohol
    9.
    发明申请
    Method of Synthesizing Higher-Molecular Alcohol 有权
    合成高分子醇的方法

    公开(公告)号：US20070255079A1

    公开(公告)日：2007-11-01

    申请号：US11757588

    申请日：2007-06-04

    申请人： Takashi Tsuchida ,  Shuji Sakuma

    发明人： Takashi Tsuchida ,  Shuji Sakuma

    IPC分类号： C07C31/02

    CPC分类号： C07C29/34 ,  C07C31/12

    摘要： The present invention provides a production method with which high molecular alcohols having an even number of carbon atoms such as 1-butanol, hexanol, octanol and decanol, and a mixture of these are efficiently collected through clean processes with the use of ethanol as a raw material. High molecular alcohols are produced from ethanol by using calcium phosphate-based compounds such as hydroxyapatite Ca10(PO4)6(OH)2, tricalcium phosphate Ca3(PO4)2, calcium monohydrogen phosphate CaHPO4.(0˜2)H2O, calcium diphosphate Ca2P2O7, octacalcium phosphate Ca8H2(PO4)6.5H2O, tetracalcium phosphate Ca4(PO4)2O or amorphous calcium phosphate Ca3(PO4)2.nH2O as a catalyst, using ethanol as a starting material, and setting a contact time at 0.4 second or longer.

    摘要翻译： 本发明提供一种制备方法，通过使用乙醇作为原料，通过清洁方法有效地收集具有偶数个碳原子的高分子醇如1-丁醇，己醇，辛醇和癸醇，以及它们的混合物 材料。 高分子醇通过使用磷酸钙基化合物如羟基磷灰石Ca（PO 4）6（OH）N（OH））由乙醇制备 磷酸三钙Ca 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 PO 3 （0〜2）H 2 O 2，二磷酸钙Ca 2 P 2 O 7，磷酸三钙Ca 8 H 2（PO 4）6 5 H 2 O，四氢化锇 磷酸盐Ca 3（PO 4）2 O 2或无定形磷酸钙Ca 3（PO 4） 作为催化剂，使用乙醇作为起始原料，并将接触时间设定为0.4秒以上，作为催化剂。

    Remineralization promoter and composition for oral cavity
    10.
    发明授权
    Remineralization promoter and composition for oral cavity 有权
    再矿化促进剂和口腔成分

    公开(公告)号：US09034301B2

    公开(公告)日：2015-05-19

    申请号：US12594230

    申请日：2008-04-08

    申请人： Shuji Sakuma ,  Tsutomu Ishizaki ,  Tadayoshi Arakawa

    发明人： Shuji Sakuma ,  Tsutomu Ishizaki ,  Tadayoshi Arakawa

    IPC分类号： A61Q11/00 ,  A61K8/24 ,  A61K33/42 ,  A61K8/55 ,  A61K33/24 ,  C01B25/32

    CPC分类号： A61K8/24 ,  A61K8/55 ,  A61K33/24 ,  A61Q11/00 ,  C01B25/322

    摘要： It is intended to provide a remineralization promoter for tooth enamel and a composition for an oral cavity, which can highly effectively promote the remineralization of tooth enamel and strongly inhibit dental caries. The remineralization promoter for tooth enamel and the composition for an oral cavity are characterized by containing amorphous hydroxyapatite and/or amorphized hydroxyapatite showing two peaks at 2θ=31 to 35° in X-ray diffraction. The amorphized hydroxyapatite is obtained by reacting calcium salt with phosphate in an aqueous solution and drying the reaction solution at a temperature of 10 to 70° C.

    摘要翻译： 旨在提供用于牙釉质的再矿化促进剂和用于口腔的组合物，其可以高度有效地促进牙釉质的再矿化并且强烈抑制龋齿。 用于牙釉质的再矿化促进剂和口腔组合物的特征在于含有无定形羟基磷灰石和/或非晶化羟基磷灰石，其在2θ处显示两个峰;在X射线衍射中为31至35°。 无定形羟基磷灰石是通过在水溶液中使钙盐与磷酸盐反应得到的，并在10-70℃的温度下干燥反应溶液。