公开(公告)号：US20020087040A1

公开(公告)日：2002-07-04

申请号：US09986562

申请日：2001-11-09

Applicant: SNAMPROGETTI S.p.A.

Inventor： Mario Marchionna ,  Marco Di Girolamo ,  Domenico Sanfilippo ,  Alberto Paggini

IPC: C07C011/00 ,  C07C002/00

CPC classification number: C07C9/14 ,  C10L1/06

Abstract: A process is described for the production of hydrocarbons with a high octane number starting from mixtures essentially consisting of n-butane and isobutane (such as for example field butanes) comprising a skeleton isomerization section, a dehydrogenation section of paraffins, a selective hydrogenation section of butadiene, two conversion sections of olefins, in which the isobutene is firstly selectively transformed by means of dimerization and/or etherification, followed by the linear butenes by means of alkylation, in order to obtain, by joining the products of the two conversion sections, a product having excellent motoristic properties (octane number, volatility and distillation curve).

Abstract translation: 描述了一种用于生产具有高辛烷值的烃的方法，其起始于基本上由正丁烷和异丁烷（例如现场丁烷）组成的混合物，其包含骨架异构化部分，链烷烃的脱氢部分，选择氢化部分 丁二烯，烯烃的两个转化段，其中首先通过二聚和/或醚化选择性地转化异丁烯，然后通过烷基化进行线性丁烯，以便通过连接两个转化段的产物， 具有优异的运动特性（辛烷值，挥发性和蒸馏曲线）的产品。

公开(公告)号：US20010055559A1

公开(公告)日：2001-12-27

申请号：US09810561

申请日：2001-03-19

Applicant: Snamprogetti S.p.A.

Inventor： Domenico Sanfilippo ,  Alberto Paggini ,  Valerio Piccoli ,  Roberta Miglio ,  Stefano Rossini

IPC: C01B003/02

CPC classification number: C01B3/386 ,  C01B3/063 ,  C01B2203/0261 ,  C01B2203/0805 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1241 ,  Y02E60/36

Abstract: Process for the production of hydrogen consisting in subjecting a solid to oxidation and treating, in a different zone, the oxidized form thus produced with a reducing stream, preferably a hydrocarbon.

Abstract translation: 用于生产氢气的方法，该方法包括使固体氧化并在不同的区域处理由还原料流优选烃形成的氧化形式。

公开(公告)号：US20040010171A1

公开(公告)日：2004-01-15

申请号：US10420895

申请日：2003-04-23

Applicant: SNAMPROGETTI S.p.A.

Inventor： Mario Marchionna ,  Marco Di Girolamo ,  Domenico Sanfilippo ,  Alberto Paggini

IPC: C07C001/00 ,  C07C002/00 ,  C07C004/00 ,  C07C005/00

CPC classification number: C07C9/14 ,  C10L1/06

Abstract: A process is described for the production of hydrocarbons with a high octane number starting from mixtures essentially consisting of n-butane and isobutane (such as for example field butanes) comprising a skeleton isomerization section, a dehydrogenation section of paraffins, a selective hydrogenation section of butadiene, two conversion sections of olefins, in which the isobutene is firstly selectively transformed by means of dimerization and/or etherification, followed by the linear butenes by means of alkylation, in order to obtain, by joining the products of the two conversion sections, a product having excellent motoristic properties (octane number, volatility and distillation curve).

Abstract translation: 描述了一种用于生产具有高辛烷值的烃的方法，其起始于基本上由正丁烷和异丁烷（例如现场丁烷）组成的混合物，其包含骨架异构化部分，链烷烃的脱氢部分，选择氢化部分 丁二烯，烯烃的两个转化段，其中首先通过二聚和/或醚化选择性地转化异丁烯，然后通过烷基化进行线性丁烯，以便通过连接两个转化段的产物， 具有优异的运动特性（辛烷值，挥发性和蒸馏曲线）的产品。

公开(公告)号：US20020016520A1

公开(公告)日：2002-02-07

申请号：US09879190

申请日：2001-06-13

Applicant: SNAMPROGETTI S.p.A.

Inventor： Alberto Paggini ,  Domenico Sanfilippo ,  Elena Picciotto

IPC: C07C002/64

CPC classification number: C07C15/085 ,  C07C2521/04 ,  C07C2523/04 ,  C07C2523/14 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/62 ,  Y02P20/125

Abstract: Integrated process for the preparation of cumene which comprises dehydrogenating a stream of propane to propylene in a dehydrogenation unit and sending the stream leaving the dehydrogenation unit, containing 25-40% by weight of propylene, to an alkylation unit together with a stream of benzene with a molar ratio benzene/propylene ranging from 8 to 10. The alkylation product is distilled in a first distillation column to recover a light fraction, essentially consisting of propane which is recycled to the dehydrogenation, and a heavy fraction which is distilled in a second distillation column to recover non-reacted benzene at the head, recycled to the alkylation unit, and cumene with a purity of over 99%, at the tail.

Abstract translation: 用于制备异丙基苯的综合方法，其包括在脱氢单元中将丙烷流脱氢为丙烯，并将含有25-40重量％丙烯的离开脱氢单元的料流与苯流一起送入烷基化单元 苯/丙烯的摩尔比在8至10之间。烷基化产物在第一蒸馏塔中蒸馏以回收基本上由循环至脱氢的丙烷组成的轻馏分和在第二蒸馏中蒸馏的重馏分 柱，在尾部回收未反应的苯，再循环至烷基化单元，纯度为99％以上的枯烯。