公开(公告)号：US07368619B1

公开(公告)日：2008-05-06

申请号：US10868118

申请日：2004-06-15

申请人： Stanley J. Frey ,  Vasant P. Thakkar

发明人： Stanley J. Frey ,  Vasant P. Thakkar

IPC分类号： C07C4/02 ,  C07C6/00 ,  C10G47/00

CPC分类号： C07C6/126 ,  C07C2529/89 ,  C10G2400/30 ,  C07C15/08

摘要： A process for the production of low sulfur diesel and aromatic compounds wherein C9+ hydrocarbons are hydrocracked to produce low sulfur diesel and a naphtha boiling range stream which is transalkylated in an integrated transalkylation zone to produce xylene.

摘要翻译： 一种生产低硫柴油和芳族化合物的方法，其中C 9+烃被加氢裂化以产生低硫柴油和在一体化烷基转移区中烷基转移以产生二甲苯的石脑油沸程流。

公开(公告)号：US07265252B1

公开(公告)日：2007-09-04

申请号：US10739762

申请日：2003-12-18

申请人： Stanley J. Frey ,  Suheil F. Abdo ,  Antoine Negiz ,  Edwin P. Boldingh ,  Vasant P. Thakkar ,  Lubo Zhou

发明人： Stanley J. Frey ,  Suheil F. Abdo ,  Antoine Negiz ,  Edwin P. Boldingh ,  Vasant P. Thakkar ,  Lubo Zhou

IPC分类号： C07C4/02 ,  C07C6/00 ,  C10G47/00

CPC分类号： C07C15/08 ,  C07C6/126 ,  C10G2400/30

摘要： A process for the conversion of a hydrocarbon feedstock to produce xylene compounds. The feedstock is selectively hydrocracked and introduced into a transalkylation zone with a hydrocarbonaceous stream rich in benzene, toluene and C9+ hydrocarbons.

摘要翻译： 烃原料转化生产二甲苯化合物的方法。 原料被选择性地加氢裂化并引入含烷烃流的烷基转移区域中，所述烃物流富含苯，甲苯和C 9 O 12+烃。

公开(公告)号：US20130116495A1

公开(公告)日：2013-05-09

申请号：US13292713

申请日：2011-11-09

申请人： Stanley J. Frey ,  Lewis H. Pettengill ,  Michael R. Van de Cotte

发明人： Stanley J. Frey ,  Lewis H. Pettengill ,  Michael R. Van de Cotte

IPC分类号： C07C7/12

CPC分类号： C07C7/12 ,  B01D15/1828 ,  Y02P20/123 ,  Y02P20/57 ,  C07C15/08

摘要： The present process comprises a means for energy savings in one or more process pumps by driving the one or more pumps with a variable-speed driving means. The invention is particularly useful in the separation of an adsorbed product from a mixture of components using simulated-moving-bed adsorption associated with a large circulating stream pumped with variable-speed driving means for conservation of energy relative to the known art. The improvement is particularly applicable to a process for the separation of para-xylene from mixed C8 aromatics.

摘要翻译： 本方法包括通过用变速驱动装置驱动一个或多个泵来在一个或多个处理泵中节能的装置。 本发明特别可用于使用与用已知技术节约能源的可变速度驱动装置泵送的大循环流相关联的模拟移动床吸附分离吸附产物与组分混合物。 该改进特别适用于从混合的C8芳族化合物中分离对二甲苯的方法。

公开(公告)号：US20130012746A1

公开(公告)日：2013-01-10

申请号：US13616915

申请日：2012-09-14

申请人： Charles P. Luebke ,  Stanley J. Frey

发明人： Charles P. Luebke ,  Stanley J. Frey

IPC分类号： C10G3/00 ,  C07C1/22

CPC分类号： C10G45/04 ,  C10G3/50 ,  C10G3/60 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

摘要： A process has been developed for producing fuel from renewable feedstocks such as plant and animal oils and greases. The process involves treating a first portion of a renewable feedstock by hydrogenating and deoxygenating in a first reaction zone and a second portion of a renewable feedstock by hydrogenating and deoxygenating in a second reaction zone to provide a diesel boiling point range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the first reaction zone to increase the hydrogen solubility of the reaction mixture.

摘要翻译： 已经开发了用于从可再生原料如植物油和动物油和油脂生产燃料的方法。 该方法包括通过在第二反应区中通过氢化和脱氧来在第一反应区和第二部分可再生原料中进行氢化和脱氧处理可再生原料的第一部分以提供柴油沸点范围的燃料烃产物。 如果需要，烃产物可被异构化以改善冷流动性能。 一部分烃产物再循环到第一反应区以提高反应混合物的氢溶解度。

公开(公告)号：US08283509B2

公开(公告)日：2012-10-09

申请号：US12630195

申请日：2009-12-03

申请人： Paul A. Sechrist ,  Stanley J. Frey

发明人： Paul A. Sechrist ,  Stanley J. Frey

IPC分类号： C07C7/04

CPC分类号： B01D3/007 ,  B01D3/143 ,  Y02B30/52

摘要： The invention comprises an absorption heat pump to supply energy to a distillation process or an outside process. The streams used to effect the absorption heat pump are to be combined in any case as a feedstream to a conversion process, and energy thus is conserved by avoiding the necessity of reseparating the streams.

摘要翻译： 本发明包括一个用于向蒸馏过程或外部过程供应能量的吸收式热泵。 用于影响吸收式热泵的流在任何情况下都将作为进料流组合到转化过程中，因此通过避免重新分离流的需要来节省能量。

公开(公告)号：US08198502B2

公开(公告)日：2012-06-12

申请号：US12719410

申请日：2010-03-08

申请人： Leonid Bresler ,  Stanley J. Frey

发明人： Leonid Bresler ,  Stanley J. Frey

IPC分类号： C07C7/13

CPC分类号： C07C7/005 ,  C07C7/13 ,  C07C15/08

摘要： The invention is an adsorptive separation process for producing a para-xylene product from a feed stream comprising para-xylene, at least one other C8 aromatic, and a C9 aromatic. An adsorbent comprising X or Y zeolite and a desorbent comprising para-diethylbenzene (p-DEB) are used in an adsorptive separation zone to produce an extract stream comprising para-xylene, p-DEB, and the C9 aromatic and a raffinate stream comprising the at least one other C8 aromatic, the C9 aromatic, and p-DEB. The extract stream is separated in an extract distillation zone to produce a second desorbent stream comprising the C9 aromatic and p-DEB and the raffinate stream is separated in a raffinate distillation zone to produce a third desorbent stream comprising the C9 aromatic and p-DEB. At least a portion of at least one of the second desorbent stream and the third desorbent stream is further separated in a desorbent distillation zone to produce a stream comprising the C9 aromatic.

摘要翻译： 本发明是用于从包含对二甲苯，至少一种其它C 8芳族和C 9芳族的进料流产生对二甲苯产物的吸附分离方法。 包含X或Y沸石的吸附剂和包含对二乙基苯（p-DEB）的解吸剂用于吸附分离区，以产生包含对二甲苯，p-DEB和C9芳族化合物的萃取物料流和含有 至少一种其它C 8芳族，C 9芳族和p-DEB。 萃取物流在提取蒸馏区中分离以产生包含C 9芳族和p-DEB的第二解吸流，并且萃余物流在萃余液蒸馏区中分离以产生包含C 9芳族和p-DEB的第三解吸流。 第二解吸流和第三解吸流中的至少一个的至少一部分在解吸蒸馏区进一步分离以产生包含C 9芳族的物流。

公开(公告)号：US6107526A

公开(公告)日：2000-08-22

申请号：US99163

申请日：1998-06-18

申请人： Stanley J. Frey ,  Scott P. Davis ,  Steven L. Krupa ,  Paul R. Cottrell

发明人： Stanley J. Frey ,  Scott P. Davis ,  Steven L. Krupa ,  Paul R. Cottrell

IPC分类号： C07C41/06 ,  C07C41/42

CPC分类号： C07C41/42 ,  C07C41/06 ,  Y02P20/127

摘要： A catalytic distillation process for producing high purity ethyl tertiary butyl ether that contains less than 0.6 weight percent ethanol, and preferably less than 0.07 weight percent ethanol, has been developed. The high purity ethyl tertiary butyl ether is withdrawn directly from a catalytic distillation column; no downstream processing is necessary to remove excess ethanol from the ether product. A stream containing largely normal butane is generated by a C.sub.4 distillation column along with a stream containing isobutane. The stream containing isobutane is dehydrogenated to form a stream containing isobutylene. Ethanol, the stream containing isobutylene, and the stream containing largely normal butane are introduced to an etherification zone containing a catalytic distillation column. The catalytic distillation column is operated under conditions which result in the reaction of the ethanol with the isobutylene to form ethyl tertiary butyl ether. Excess ethanol forms an azeotrope with the normal butane and is distilled with other hydrocarbons into an overhead stream. The ethyl tertiary butyl ether and no more than 0.6 weight percent ethanol are distilled into a bottoms stream and withdrawn directly from the catalytic distillation column.

摘要翻译： 已经开发了用于生产含有小于0.6重量％乙醇，优选小于0.07重量％乙醇的高纯度乙基叔丁基醚的催化蒸馏方法。 高纯度乙基叔丁基醚直接从催化蒸馏塔中取出; 不需要下游处理来从醚产物中除去过量的乙醇。 含有大量正丁烷的料流是由C4蒸馏塔和含有异丁烷的料流产生的。 含有异丁烷的物流被脱氢以形成含有异丁烯的物流。 将含有异丁烯的物流和含有大量正丁烷的物流引入含有催化蒸馏塔的醚化区。 催化蒸馏塔在乙醇与异丁烯反应形成乙基叔丁基醚的条件下运行。 过量的乙醇与正丁烷形成共沸物，并与其他烃一起蒸馏成塔顶物流。 将乙基叔丁基醚和不超过0.6重量％的乙醇蒸馏到塔底物流中，直接从催化蒸馏塔中取出。

公开(公告)号：US5689033A

公开(公告)日：1997-11-18

申请号：US642092

申请日：1996-05-02

申请人： Paulino Forte ,  Stanley J. Frey

发明人： Paulino Forte ,  Stanley J. Frey

IPC分类号： C07C7/10 ,  C07C41/06

CPC分类号： C07C41/06 ,  C07C7/10

摘要： A process is directed to the removal of impurities such as sulfur compounds, oxygenates, and/or olefins from a light paraffin hydrocarbon feedstock such as a C.sub.4 -C.sub.6 fraction, which may be used subsequently in an isomerization process in an integrated complex for the production of ethers such as MTBE and TAME. The hydrocarbon feedstream is passed to a removal zone wherein the hydrocarbon feedstream is contacted with a selective solvent for the removal of the impurities comprising at least one of sulfur compounds, oxygenates and olefins to provide a rich solvent stream and a treated hydrocarbon stream. The rich solvent comprising the trace impurities is contacted with a stripping medium stream to regenerate the selective solvent in a stripping zone. The removal zone may be a liquid-liquid extraction zone or a gas absorption zone. The selective solvent comprises a water miscible organic liquid having a low molecular weight preferably less than about 400 and more preferably having a molecular weight of less than about 200. The process is particularly useful in removing impurities such as sulfur, oxygenates and/or olefins which are harmful to the isomerization catalyst. The process replaces separate olefins, oxygenate, and sulfur removal processes resulting in simplified processing schemes.

摘要翻译： 一种方法是从轻链烷烃原料如C4-C6馏分中除去杂质如硫化合物，含氧化合物和/或烯烃，其可以随后在用于生产的综合复合物中的异构化方法中使用 的醚类，如MTBE和TAME。 将烃进料流输送到去除区，其中烃进料流与选择性溶剂接触以除去包含硫化合物，含氧化合物和烯烃中的至少一种的杂质，以提供富溶剂流和经处理的烃流。 将包含微量杂质的富溶剂与汽提介质流接触以在汽提区再生出选择性溶剂。 去除区可以是液 - 液萃取区或气体吸收区。 选择性溶剂包括低分子量优选小于约400且更优选分子量小于约200的水混溶性有机液体。该方法特别可用于除去诸如硫，含氧物和/或烯烃的杂质， 对异构化催化剂有害。 该方法代替单独的烯烃，含氧化合物和除硫过程，从而导致简化的处理方案。

公开(公告)号：US5621150A

公开(公告)日：1997-04-15

申请号：US429402

申请日：1995-04-26

申请人： Henry Rastelli ,  Carmen M. Yon ,  Stanley J. Frey

发明人： Henry Rastelli ,  Carmen M. Yon ,  Stanley J. Frey

IPC分类号： C07C41/36 ,  C07C41/34

CPC分类号： C07C41/36

摘要： The present invention relates to a cyclic process for the preparation of ethyl tert.-alkyl ethers by the reaction of an alcohol, such as ethanol, with an iso-olefin such as isobutylene or isoamylene wherein an effluent from the reaction zone is first separated in a distillation column to provide an overhead effluent stream and a bottoms effluent stream comprising ethyl tert.-alkyl ether and unreacted ethanol, and the ether product is passed to an adsorption zone to remove the unreacted ethanol. When the reaction occurs in the presence of water, a tert. alcohol (e.g., TBA or TAA) is produced and, if returned to the reaction zone, the tertiary alcohol builds up in the process and reduces efficiency. An adsorbent selected from the group consisting of zeolite 13X, silica-bonded silicalite, an alkali-exchanged zeolite with an MFI structure having a silica/alumina ratio greater than 20 and mixtures thereof is employed in an adsorption zone to remove the unreacted ethanol from the ether product to provide ether product essentially free of ethanol and comprising the tertiary alcohol. Thus, the tertiary alcohol is removed with the ether product as a high octane, oxygenate blending component for reformulated gasoline with a low vapor pressure. The invention is useful in recovering unreacted ethanol from the other product stream and returning the unreacted ethanol to the reaction zone without returning TBA. The invention prevents the build-up of tertiary alcohol in the unreacted ethanol stream which adversely affects the operation of the reaction zone and reduces catalyst stability.

摘要翻译： 本发明涉及通过醇如乙醇与异烯烃如异丁烯或异戊烯的反应制备乙基叔烷基醚的环状方法，其中首先将来自反应区的流出物以 提供塔顶流出物流的蒸馏塔和包含乙基叔烷基醚和未反应的乙醇的底部流出物流，并将该醚产物通入吸附区以除去未反应的乙醇。 当反应在水的存在下发生时， 产生醇（例如，TBA或TAA），并且如果返回到反应区，则叔醇在该过程中积聚并降低效率。 选自沸石13X，二氧化硅结合硅沸石，具有二氧化硅/氧化铝比大于20的MFI结构的碱交换沸石及其混合物的吸附剂用于吸附区以从未反应的乙醇中除去未反应的乙醇 醚产物，以提供基本上不含乙醇的醚产物并且包含叔醇。 因此，用乙醚产物作为高辛烷值，低蒸气压的重整汽油的含氧化合物共混组分除去叔醇。 本发明可用于从其他产物流中回收未反应的乙醇并将未反应的乙醇返回到反应区而不返回TBA。 本发明防止叔醇在未反应的乙醇流中的积聚，这对反应区的操作产生不利影响并降低了催化剂的稳定性。

公开(公告)号：US5463134A

公开(公告)日：1995-10-31

申请号：US238606

申请日：1994-05-04

申请人： Stanley J. Frey

发明人： Stanley J. Frey

IPC分类号： C07C7/148 ,  C07C319/16

CPC分类号： C07C7/148 ,  Y02P20/127

摘要： Contaminants such as mercaptans, oxygenates and olefins are removed from paraffin-rich feed streams through the use of catalytic distillation performed using an acid catalyst such as a sulphonated resin in the substantial absence of hydrogen. The mercaptans are reacted with the olefins to form less volatile thioethers removed as part of a net bottoms stream with the treated paraffins being removed as the overhead stream.

摘要翻译： 通过使用在基本上不存在氢气的情况下使用酸催化剂如磺化树脂进行的催化蒸馏，从富链烷烃进料流中除去诸如硫醇，含氧化合物和烯烃的污染物。 硫醇与烯烃反应以形成较少挥发性的硫醚，作为净底部物流的一部分被去除，处理的石蜡作为塔顶馏出物被除去。