摘要:
A polymer article having accelerated degradability triggered by light and/or heat and/or humidity and made of a composition containing (A) a natural and/or a synthetic polymer and (B) a degradation accelerator of the formula (I), wherein n is 1, 2 or 4; X is >C=0, >S(O)2 or >C(X1)(X2); X1 and X2 independently of one another are hydrogen, C1-C20alkyl, C3-C12cycloalkyl unsubstituted or substituted by 1, 2 or 3 C1-C4alkyl; or phenyl unsubstituted or substituted by 1, 2 or 3 C1-C4alkyl; Y is C1-C30alkyl, C2-C30alkenyl, C3-C12cycloalkyl unsubstituted or substituted by 1, 2 or 3 C1C4alkyl; C5-C12cycloalkenyl unsubstituted or substituted by 1, 2 or 3 C1C4alkyl; a bicyclic or tricyclic hydrocarbyl having 6 to 10 carbon atoms, C7-C4phenylalkyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C1-C4alkyl; diphenylmethyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C1-C4alkyl; triphenylmethyl unsubstituted or substituted on the phenyl by 1, 2 or 3 C1-C4alkyl; C2-C30acyl, —COOY0, C1-C30sulfonyl, —Si(Y1)3 or —Si(OY2)3; Y0, Y1 and Y2 independently of one another are hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C12cycloalkyl which is unsubstituted or substituted by 1, 2 or 3 C1-C4alkyl; phenyl which is unsubstituted or substituted by 1, 2 or 3 C1-C4alkyl; or C7-C9phenylalkyl which is unsubstituted or substituted on the phenyl by 1, 2 or 3 C1-C4alkyl; and Z is an organic radical; with the provisos that (1) when Y is C1-C30alkyl, C2-C30alkenyl or C1-C30sulfonyl, component (A) is a polyolefin homo- or copolymer or a blend of a polyolefin homo- or copolymer with another synthetic polymer; and (2) when n is 2 or 4 and, at the same time, component (A) is a polyolefin homo- or copolymer or a blend of a polyolefin homo- or copolymer with another synthetic polymer, Y is additionally hydrogen.
摘要:
A non-agricultural article, which is different from a golf ball or golf ball cover and which is made of a composition containing (a) an organic polymer, and (b-I) a polyacrylic acid sodium salt or a sodium salt of ethylene/methacrylic acid copolymer, and (b-II) manganese stearate.
摘要:
An agricultural article made of a composition containing (a) an organic polymer, and (b-I) a polyacrylic acid sodium salt or a sodium salt of ethylene/methacrylic acid copolymer, and (b-II) manganese stearate.
摘要:
Use of metal complex compounds of formula (1) and/or (1′) [LnMemXp]zYq (1), [L′nMemXp]zYq (1′), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.
摘要:
The present invention relates to the use of certain manganese complexes having bispyridylpyrimidine or bispyridyltriazine ligands or mixtures of such ligands as catalysts for reactions with peroxy compounds for bleaching coloured stains on hard surfaces, especially dishes in automatic dishwashers. The invention relates also to cleaning formulations for hard surfaces comprising such catalysts.
摘要:
Novel metal complexes of tripoadal ligands are useful as catalysts to enhance the action of peroxygen compounds in washing, cleaning and disinfecting processes.
摘要:
The present invention provides a process for inhibiting the re-absorption of migrating dyes in the wash liquor, comprising introducing into a wash liquor containing a peroxide-containing detergent, from 0.5 to 150, preferably from 1.5 to 75, especially from 7.5 to 40 mg, per liter of wash liquor, of one or more compounds having the formula: in which n is 1, 2 or 3; A is an anion; Y is —(CH2)m in which m is an integer ranging from 1 to 8; —(CH2)p—CH(R1)— in which p is an integer ranging from 1 to 7 and R1 is linear or branched C1-C4-alkyl, preferably methyl; —CX═CX— in which X is cyano, linear or branched C1-C8-alkyl or di(linear or branched C1-C8-alkyl)-amino; —(CH2)q—NR1—(CH2)q— in which R1 has its previous significance and q is 1, 2, 3 or 4; or a 1,2-cyclohexylene residue having the formula: R is cyano; halogen; hydroxy; OR1 in which R1 has its previous significance; CO2R2 in which R2 is hydrogen or linear or branched C1-C4-alkyl; nitro; linear or branched C1-C8-alkyl; di-(C4-C12alkyl)amino; NR3R4 in which R3 and R4 are the same or different and each is linear or branched C1-C12-alkyl; or —N⊕R1R3R4 in which R1, R3 and R4 have their previous significance.
摘要:
The invention accordingly relates to the use as catalysts of at least one metal complex of formula (1) [LnMemXp]zYq (1), wherein all substituents have the meanings as defined in the claims for oxidation reactions with organic peroxy acids and/or precursors of organic peroxy acid and H2O2, as well as to novel detergent compositions.
摘要翻译:因此,本发明涉及用作至少一种式(1)金属络合物[LnMemXp] zYq(1)的催化剂的用途,其中所有取代基具有如权利要求中定义的与有机过氧酸和/或前体的氧化反应所定义的含义 的有机过氧酸和H 2 O 2,以及新的洗涤剂组合物。
摘要:
Use of metal complex compounds of formula [LnMemXp]zYq, (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
摘要:
An automatic dishwasher detergent formulation comprising:—(a) a metal complex compounds of formula (1)[LnMem,Xp] zYq wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2); wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; SR13, —SO2R13 or −OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14NR15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them from an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as a catalyst for oxidation reactions; and (b) an enzyme.