Fluorinated alkyl substituted-thieno[3,4-b]thiophene monomers and polymers therefrom
    2.
    发明申请
    Fluorinated alkyl substituted-thieno[3,4-b]thiophene monomers and polymers therefrom 有权
    氟化烷基取代噻吩并[3,4-b]噻吩单体及其聚合物

    公开(公告)号:US20050209419A1

    公开(公告)日:2005-09-22

    申请号:US11128538

    申请日:2005-05-13

    IPC分类号: C08G61/12 C08F4/80

    CPC分类号: C08G61/123 C08G61/126

    摘要: Partially and fully fluorinated alkyl substituted thienothiophene monomers (and polymers thereof) wherein the monomers are represented by the formula: wherein R is a partially or fully fluorinated primary, secondary or tertiary alkyl having from 1 to 8 carbon atoms; and X and X′ are independently selected from the group consisting of H, F, Cl, Br, I, MgCl, MgBr, Mgl, Sn(R′)3, CH═CHR″, —OR″, —COOR″, —S—COR″, —B(OR″)2, —COR″, —C≡CH, and a polymerizable cyclic pi-conjugated carbon-ring structure optionally comprising S, N or O heteroatoms; wherein R′ is a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms, and R″ is H or a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms.

    摘要翻译: 部分和完全氟化的烷基取代的噻吩并噻吩单体(及其聚合物),其中单体由下式表示:其中R是具有1至8个碳原子的部分或完全氟化的伯,仲或叔烷基; 并且X和X'独立地选自H,F,Cl,Br,I,MgCl,MgBr,MgI,Sn(R')3,CH-CHR“, - OR“,-COOR”,-S-COR“,-B(OR”)2,-COR“,-C≡CH和可聚合的环状π-共轭碳 任选地包含S,N或O杂原子的环结构; 其中R'是具有1至6个碳原子的伯,仲或叔烷基,R“是H或具有1至6个碳原子的伯,仲或叔烷基。

    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers
    3.
    发明申请
    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers 失效
    五氟硫烷基取代的噻吩并噻吩单体和导电聚合物

    公开(公告)号:US20060071199A1

    公开(公告)日:2006-04-06

    申请号:US10958054

    申请日:2004-10-04

    IPC分类号: H01B1/12

    CPC分类号: C08G61/126 H01B1/127

    摘要: Thienothiophene monomers having an SF5 group and conducting oligomers and polymers formed by the polymerization of such monomers and their use as hole injection materials, charge transport materials, or as semiconductors. The compound may be of the formula: where X and X′ are independently H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, MgI, Sn(R′)3, where R′ is C1-6 alkyl or —OC1-6 alkyl, boronic acid, boronic ester, —CH=CHR″ (where R″ is H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″ and —COR′″ (where R′″ is H or C1-6 alkyl), —C≡CH, or polymerizable aromatic rings (such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth.

    摘要翻译: 具有SF 5 N基团的噻吩并噻吩单体和通过这些单体的聚合形成的导电低聚物和聚合物及其作为空穴注入材料,电荷传输材料或半导体的用途。 化合物可以具有下式:其中X和X'独立地为H,卤素原子(例如F,Cl,Br和I),MgCl,MgBr,MgI,Sn(R')3 >,其中R'是C 1-6烷基或-OC 1-6 - 烷基,硼酸,硼酸酯,-CH = CHR“(其中R” 是H或C 1-6烷基),-OC 1-6烷基,-COOC 1-6烷基,-S-COR' '和-COR''(其中R“'是H或C 1-6烷基),-C≡CH或可聚合的芳环(例如苯基,萘,吡咯,二噻吩 噻吩并噻吩,噻吩等。

    PENTAFLUOROSULFANYL-SUBSTITUTED THIENOTHIOPHENE MONOMERS AND CONDUCTING POLYMERS
    4.
    发明申请
    PENTAFLUOROSULFANYL-SUBSTITUTED THIENOTHIOPHENE MONOMERS AND CONDUCTING POLYMERS 有权
    取代二苯甲酮单体和导电聚合物

    公开(公告)号:US20060074250A1

    公开(公告)日:2006-04-06

    申请号:US11229516

    申请日:2005-09-20

    IPC分类号: C07D333/16

    摘要: Thienothiophene monomers having an SF5 group and conducting oligomers and polymers formed by the polymerization of such monomers and their use as hole injection materials, charge transport materials, or as semiconductors. The compound may be of the formula: where X and X′ are independently H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, MgI, Sn(R′)3, where R′ comprises C1-6 alkyl or —OC1-6 alkyl, boronic acid, boronic ester, —CH═CHR″ (where R″ comprises H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR″′ and —COR″′ (where R″′ comprises H or C1-6 alkyl), —C≡CH, or polymerizable aromatic rings (such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth).

    摘要翻译: 具有SF 5 N基团的噻吩并噻吩单体和通过这些单体的聚合形成的导电低聚物和聚合物及其作为空穴注入材料,电荷传输材料或半导体的用途。 化合物可以具有下式:其中X和X'独立地为H,卤素原子(例如F,Cl,Br和I),MgCl,MgBr,MgI,Sn(R')3 >,其中R'包含C 1-6烷基或-OC 1-6 - 烷基,硼酸,硼酸酯,-CH-CHR“(其中R” 包括H或C 1-6烷基),-OC 1-6烷基,-COOC 1-6烷基,-S-COR' '和-COR'''(其中R“'包括H或C 1-6烷基),-C≡CH或可聚合的芳环(例如苯基,萘,吡咯,二噻吩 噻吩并噻吩,噻吩等)。

    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers
    5.
    发明申请
    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers 失效
    五氟硫烷基取代的噻吩并噻吩单体和导电聚合物

    公开(公告)号:US20060208233A1

    公开(公告)日:2006-09-21

    申请号:US11439553

    申请日:2006-05-23

    IPC分类号: H01B1/12

    摘要: Thienothiophene monomers having an SF5 group and conducting oligomers and polymers formed by the polymerization of such monomers and their use as hole injection materials, charge transport materials, or as semiconductors. The compound may be of the formula: where X and X′ are independently H, halogen atoms (e.g., F, Cl, Br, and 1), MgCl, MgBr, Mgl, Sn(R′)3, where R′ comprises C1-6 alkyl or —OC16 alkyl, boronic acid, boronic ester, -CH=CHR″ (where R″ comprises H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″ and —COR ″ (where R ″ comprises H or c1-6 alkyl), —C≡CH, or polymerizable aromatic rings (such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth).

    摘要翻译: 具有SF 5 N基团的噻吩并噻吩单体和通过这些单体的聚合形成的导电低聚物和聚合物及其作为空穴注入材料,电荷传输材料或半导体的用途。 化合物可以具有下式:其中X和X'独立地为H,卤素原子(例如F,Cl,Br和1),MgCl,MgBr,Mg1,Sn(R')3 >,其中R'包含C 1-6烷基或-OC 1 - 亚烷基,硼酸,硼酸酯,-CH = CHR' '(其中R“包括H或C 1-6烷基),-OC 1-6烷基,-COOC 1-6烷基 ,-S-COR“和-COR”(其中R“包括H或C 1-6烷基),-C≡CH或可聚合芳环(例如苯基,萘 ,吡咯,二噻吩,噻吩并噻吩,噻吩等)。

    Synthesis of pentafluorosulfanylnaphthalene
    6.
    发明申请
    Synthesis of pentafluorosulfanylnaphthalene 失效
    五氟硫烷基萘的合成

    公开(公告)号:US20060069285A1

    公开(公告)日:2006-03-30

    申请号:US10954719

    申请日:2004-09-30

    IPC分类号: C07C309/78

    摘要: This invention relates to 2-pentafluorosulfanylnapthalene, substituted derivatives thereof and to a process for producing naphthalene carrying an SF5 group. A 3-step process is employed wherein 1,4-dihydronaphthalene is reacted with pentafluorosulfanyl halide. Next the resulting 3-halo-2-pentafluorosulfanylnaphthalene or derivative is converted to 2-pentafluorosulfanyl-1,4-dihydronaphthalene or derivative by treatment with a base and subsequently transformed into pentafluorosulfanylnaphthalene by removing hydrogen atoms.

    摘要翻译: 本发明涉及2-五氟硫烷基萘及其取代衍生物,以及一种生产含有SF 5 H 5基团的萘的方法。 使用其中1,4-二氢萘与五氟硫烷基卤化物反应的三步法。 接下来,通过用碱处理将所得3-卤代-2-五氟硫烷基萘或其衍生物转化为2-五氟硫烷基-1,4-二氢萘或衍生物,随后通过除去氢原子转化成五氟硫烷基萘。

    Synthesis of pentafluorosulfuranyl arylenes
    7.
    发明申请
    Synthesis of pentafluorosulfuranyl arylenes 有权
    五氟硫烷基亚芳基的合成

    公开(公告)号:US20050107632A1

    公开(公告)日:2005-05-19

    申请号:US10713231

    申请日:2003-11-14

    IPC分类号: C07B61/00 C07C381/00

    CPC分类号: C07C381/00

    摘要: A new route has been found leading to the formation of pentafluorosulfuranyl arylenes. In its broadest aspect the process comprises: effecting dehydrohalogenation or dehydrogenation of a pentafluorosulfuranyl compound represented by either of the structures: wherein R1 is H, C1-10 alkyl, C1-10 alkoxy, C1-10 thionyl. C1-10 alkyl ether, list more, R2, R4 and R5 are H and R3 is H repeated R1 to form the pentafluorosufuranyl arylene represented by the structures: wherein R1-R5 are as represented in compound represented by the structures A and B.

    摘要翻译: 已经发现导致形成五氟硫烷基亚芳基的新途径。 在其最广泛的方面,该方法包括:进行由以下任一结构表示的五氟硫烷基化合物的脱卤化氢或脱氢:其中R 1是H,C 1-10烷基,C 1-10个亚烷基,C 1〜10 亚硫酰基。 C 1-10烷基醚,更多列举,R 2,R 4和R 5是H和R 3 是H重复R 1 H以形成由以下结构表示的结构的五氟呋喃基亚芳基:其中R 1 -R 5 - 如在由 结构A和B.

    Amine N-oxide based surfactants
    8.
    发明申请
    Amine N-oxide based surfactants 审中-公开
    胺N-氧化物基表面活性剂

    公开(公告)号:US20070031370A1

    公开(公告)日:2007-02-08

    申请号:US11197887

    申请日:2005-08-04

    IPC分类号: A61K31/74

    摘要: Surfactant compositions contain one or more compounds according to formula (I) wherein R1 is methyl, ethyl, or 1-propyl; R is a C4-C20 aryl, alkaryl, aralkyl, cyclic, alicyclic, or secondary, branched or bicyclic alkyl group, or a polyhydroxyalkyl group according to formula (A) wherein u is an integer from 0 to 2 and R2 is H, α-D-glucopyranosyl, β-D-pyranosyl, or β-D-galactopyranosyl; and Z is a linking group selected from the group consisting of 4,4′-methylenebis(cyclohexyl); CH2(CH2)n{N+O—R1—CH2(CH2)o}p, where p is an integer from 1 to 10 and n and o are each independently integers from 1 to 5; (CH2)r[O(CH2)s]tO(CH2)q, where s is an integer from 2 to 4, t is an integer from 0 to 2, and r and q are each individually 2 or 3; (CH2)m, where m is an integer from 2 to 6; and isophorone residue (B)

    摘要翻译: 表面活性剂组合物含有一种或多种根据式(I)的化合物,其中R 1是甲基,乙基或1-丙基; R是C 4 -C 20芳基,烷芳基,芳烷基,环状,脂环族或仲,支链或双环烷基,或根据式(A)的多羟基烷基,其中u是0-2的整数,R 2 H,α-D-吡喃葡萄糖基,β-D-吡喃糖基或β-D-吡喃半乳糖基; 和Z是选自4,4'-亚甲基双(环己基); CH 2(CH 2)n N(N) - - - - - (CH 2) 其中p是1至10的整数,并且n和o分别表示2或2以上的整数。 各自独立地为1至5的整数; (CH 2)n O(CH 2)n O(CH 2) (CH 2)q,其中s为2至4的整数,t为0至2的整数,r和q各自为2或3; (CH 2)2,其中m是2至6的整数; 和异佛尔酮残基(B)

    Formation of hydrogels and use of hydrogels
    9.
    发明申请
    Formation of hydrogels and use of hydrogels 失效
    水凝胶的形成和水凝胶的使用

    公开(公告)号:US20060231228A1

    公开(公告)日:2006-10-19

    申请号:US11450999

    申请日:2006-06-12

    IPC分类号: C08G63/91

    摘要: A composition includes at least one hydrophilic polymer containing primary (—NH2) and/or secondary (—NHR) amine groups and at least one saccharide containing a reducible function. A method of increasing the strength of paper includes the step of contacting the paper with a composition comprising (i) at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function. A hydrogel composition is formed from a mixture of at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function.

    摘要翻译: 组合物包括至少一种含有伯(-NH 2)和/或仲(-NHR)胺基团的至少一种亲水性聚合物和至少一种含有可还原官能团的糖。 提高纸张强度的方法包括使纸与包含(i)至少一种亲水性聚合物的步骤,所述组合物含有至少两个独立地相同或不同的伯胺基或仲胺基的基团,并且在 至少一种含有还原功能的糖。 水凝胶组合物由至少一种含有至少两个独立地相同或不同的伯胺基或仲胺基的亲水性聚合物和至少一种含有还原性功能的糖的亲水性聚合物的混合物形成。