Heterocyclic fused selenophene monomers
    2.
    发明授权
    Heterocyclic fused selenophene monomers 有权
    杂环稠合硒吩单体

    公开(公告)号:US07982055B2

    公开(公告)日:2011-07-19

    申请号:US11777362

    申请日:2007-07-13

    IPC分类号: C07D495/02

    摘要: A heterocyclic fused selenophenes and a method of making a heterocyclic fused selenophenes of formula (1): wherein X is S or Se, Y is S or Se, wherein one or both of X and Y is Se, R is a substituent group. The monomer being capable of polymerization to form an electrically conductive polymer or oligomer.

    摘要翻译: 一种杂环稠合硒吩酚和制备式(1)的杂环稠合硒吩的方法:其中X是S或Se,Y是S或Se,其中X和Y中的一个或两个是Se,R是取代基。 该单体能够聚合以形成导电聚合物或低聚物。

    Selenium Containing Electrically Conductive Polymers and Method of Making Electrically Conductive Polymers
    6.
    发明申请
    Selenium Containing Electrically Conductive Polymers and Method of Making Electrically Conductive Polymers 有权
    含有导电聚合物的硒和制导导电聚合物的方法

    公开(公告)号:US20090014693A1

    公开(公告)日:2009-01-15

    申请号:US11777386

    申请日:2007-07-13

    申请人: Steffen Zahn

    发明人: Steffen Zahn

    摘要: Monomeric, oligomeric and polymeric electrically conductive compounds and methods of making the compounds having a repeating unit having formula P1, as follows: where X is S or Se, Y is S or Se, wherein one or both of X and Y is Se, R is a substituent group capable of bonding to the ring structure. R may include hydrogen or isotopes thereof, hydroxyl, alkyl, including C1 to C20 primary, secondary or tertiary alkyl groups, arylalkyl, alkenyl, perfluoroalkyl, perfluororaryl, aryl, alkoxy, cycloalkyl, cycloalkenyl, alkanoyl, alkylthio, aryloxy, alkylthioalkyl, alkynyl, alkylaryl, arylalkyl, amido, alkylsulfinyl, alkoxyalkyl, alkylsulfonyl, aryl, arylamino, diarylamino, alkylamino, dialkylamino, arylarylamino, arylthio, heteroaryl, arylsulfinyl, alkoxycarbonyl, arylsulfonyl, carboxyl, halogen, nitro, cyano, sulfonic acid, or alkyl or phenyl substituted with one or more sulfonic acid, phosphoric acid, carboxylic acid, halo, amino, nitro, hydroxyl, cyano or epoxy moieties. Electrical devices utilizing the electrically conductive polymers is also disclosed.

    摘要翻译: 单体,低聚物和聚合物导电化合物和制备具有式P1重复单元的化合物的方法如下:其中X是S或Se,Y是S或Se,其中X和Y中的一个或两个是Se,R 是能够与环结构键合的取代基。 R可包括氢或其同位素,羟基,烷基,包括C1至C20伯,仲或叔烷基,芳基烷基,烯基,全氟烷基,全氟芳基,芳基,烷氧基,环烷基,环烯基,烷酰基,烷硫基,芳氧基,烷硫基烷基,炔基, 烷基芳基,芳基烷基,酰胺基,烷基亚磺酰基,烷氧基烷基,烷基磺酰基,芳基,芳基氨基,二芳基氨基,烷基氨基,二烷基氨基,芳基芳基氨基,芳硫基,杂芳基,芳基亚硫酰基,烷氧基羰基,芳基磺酰基,羧基,卤素,硝基,氰基,磺酸或烷基或苯基取代 与一个或多个磺酸,磷酸,羧酸,卤素,氨基,硝基,羟基,氰基或环氧部分。 还公开了利用导电聚合物的电气装置。

    Electrically conductive polymers and method of making electrically conductive polymers
    7.
    发明申请
    Electrically conductive polymers and method of making electrically conductive polymers 审中-公开
    导电聚合物和制备导电聚合物的方法

    公开(公告)号:US20070278453A1

    公开(公告)日:2007-12-06

    申请号:US11446000

    申请日:2006-06-02

    IPC分类号: H01B1/12

    摘要: A composition of matter including a polymer having a repeating unit having formula P1, as follows: wherein n is an integer greater than 4; Z is Se, S, O, NR1, or PR1, where R1 is hydrogen, alkylaryl, arylalkyl, or aryl; Y is independently selected from NH, O, C(R)2, N(R)2 and S; X is O, S, Se or NH and E is independently selected from functional or non-functional end-groups. R is a substituted or unsubstituted C1-C4 alkyl group. E is independently selected from functional and non-functional end-groups. The repeating structures according to the present invention may be substantially identical, forming a homopolymer, or may have Z, Y, and X independently selected for each unit, resulting in a copolymeric compound. The invention also includes electrical components incorporating the polymer and the method for making the polymer.

    摘要翻译: 包括具有式P1重复单元的聚合物的物质组成如下:其中n是大于4的整数; Z是Se,S,O,NR 1或PR 1,其中R 1是氢,烷基芳基,芳基烷基或芳基; Y独立地选自NH,O,C(R)2 N,N(R)2和S; X是O,S,Se或NH,E独立地选自官能或非官能的端基。 R是取代或未取代的C 1 -C 4烷基。 E独立地选自功能性和非功能性端基。 根据本发明的重复结构可以基本相同,形成均聚物,或者可以单独选择Z,Y和X,得到共聚合物。 本发明还包括结合聚合物的电子部件和制备聚合物的方法。

    Substituted thienothiophene monomers and conducting polymers
    8.
    发明授权
    Substituted thienothiophene monomers and conducting polymers 失效
    取代的噻吩并噻吩单体和导电聚合物

    公开(公告)号:US07118692B2

    公开(公告)日:2006-10-10

    申请号:US10958068

    申请日:2004-10-04

    IPC分类号: H01B1/12

    摘要: Thienothiophenes compositions comprising a C3-8 secondary or tertiary alkyl group are disclosed. The thienothiophenes may be represented by the formula: where R is C3-8 secondary or tertiary alkyl, e.g., isopropyl, tert-butyl, tert-pentyl, isopentyl, and 2-ethylhexyl, X and X′ are independently selected from the group consisting of H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, Mgl, Sn(R′)3, (where R′ is C1-6 alkyl or —OC1-6 alkyl), boronic acid, boronic ester, —CH═CHR″ (where R″ is H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″, —COR′″ (where R′″ is H or C1-6 alkyl), —C≡CH, and polymerizable aromatic rings such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth.

    摘要翻译: 公开了包含C 3-8仲仲或叔烷基的噻吩并噻吩类组合物。 噻吩并噻吩可以由下式表示:其中R是C 3-8仲仲或叔烷基,例如异丙基,叔丁基,叔戊基,异戊基和2-乙基己基,X和X 独立地选自H,卤素原子(例如F,Cl,Br和I),MgCl,MgBr,Mg1,Sn(R')3(其中R' 是C 1-6烷基或-OC 1-6烷基),硼酸,硼酸酯,-CH-CHR“(其中R”是H或C C 1-6烷基),-OC 1-6烷基,-COOC 1-6烷基,-S-COR“ - , - COR''(其中R“'是H或C 1-6烷基),-C≡CH,以及可聚合的芳环如苯基,萘,吡咯,二噻吩,噻吩并噻吩,噻吩和 等等。

    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers
    10.
    发明授权
    Pentafluorosulfanyl-substituted thienothiophene monomers and conducting polymers 失效
    五氟硫烷基取代的噻吩并噻吩单体和导电聚合物

    公开(公告)号:US07094365B2

    公开(公告)日:2006-08-22

    申请号:US10958054

    申请日:2004-10-04

    IPC分类号: H01B1/12 C07D333/00

    CPC分类号: C08G61/126 H01B1/127

    摘要: Thienothiophene monomers having an SF5 group and conducting oligomers and polymers formed by the polymerization of such monomers and their use as hole injection materials, charge transport materials, or as semiconductors. The compound may be of the formula: where X and X′ are independently H, halogen atoms (e.g., F, Cl, Br, and I), MgCl, MgBr, MgI, Sn(R′)3, where R′ is C1-6 alkyl or —OC1-6 alkyl, boronic acid, boronic ester, —CH═CHR″ (where R″ is H or C1-6 alkyl), —OC1-6 alkyl, —COOC1-6 alkyl, —S—COR′″ and —COR′″ (where R′″ is H or C1-6 alkyl), —C≡CH, or polymerizable aromatic rings (such as phenyl, naphthalene, pyrrole, dithiophene, thienothiophene, thiophene and so forth.

    摘要翻译: 具有SF 5 N基团的噻吩并噻吩单体和通过这些单体的聚合形成的导电低聚物和聚合物及其作为空穴注入材料,电荷传输材料或半导体的用途。 化合物可以具有下式:其中X和X'独立地为H,卤素原子(例如F,Cl,Br和I),MgCl,MgBr,MgI,Sn(R')3 >,其中R'是C 1-6烷基或-OC 1-6 - 烷基,硼酸,硼酸酯,-CH-CHR“(其中R” 是H或C 1-6烷基),-OC 1-6烷基,-COOC 1-6烷基,-S-COR' '和-COR''(其中R“'是H或C 1-6烷基),-C≡CH或可聚合的芳环(例如苯基,萘,吡咯,二噻吩 噻吩并噻吩,噻吩等。