公开(公告)号：US20100163099A1

公开(公告)日：2010-07-01

申请号：US12610435

申请日：2009-11-02

申请人： Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith ,  Georeg Wyatt Prejean

发明人： Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith ,  Georeg Wyatt Prejean

IPC分类号： H01L31/048 ,  H01L31/042 ,  H01L21/56

CPC分类号： B32B17/10743 ,  B32B17/10853 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T428/1352 ,  Y10T428/269 ,  Y10T428/31645 ,  Y10T428/31855

摘要： A solar cell module comprising a solar cell layer and an ionomer sheet comprising a sodium/zinc mixed ionomer that is the neutralization product of a precursor acid copolymer; wherein the precursor acid copolymer comprises copolymerized units of an α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms based on the total weight of the precursor acid copolymer; wherein the precursor acid copolymer has a melt flow rate of about 70 to about 1000 g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg; and wherein when about 40% to about 90% of the total content of the carboxylic acid groups present in the precursor acid copolymer are neutralized to carboxylate groups to comprise carboxylate groups and counterions that consist essentially of sodium ions, the resulting sodium ionomer has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry in accordance with ASTM D3418.

摘要翻译： 一种太阳能电池组件，包括太阳能电池层和离子聚合物片，其包含作为前体酸共聚物的中和产物的钠/锌混合离聚​​物; 其中所述前体酸共聚物包括具有2至10个碳原子的α-烯烃和约20至约30重量％共聚单元的基于所述共聚单元的具有3至8个碳原子的α，bgr- - 烯键式不饱和羧酸的共聚单元 前体酸共聚物的总重量; 其中所述前体酸共聚物的熔体流动速率为约70至约1000g / 10min，根据ASTM D1238在190℃和2.16kg下测定; 并且其中当存在于前体酸共聚物中的羧酸基团的总含量的约40％至约90％被中和到羧酸酯基团以包含基本上由钠离子组成的羧酸酯基团和抗衡离子时，所得钠离子共聚物具有冷冻 当通过根据ASTM D3418的差示扫描量热法测定时，不可检测的焓或小于约3.0J / g的焓。

公开(公告)号：US08399095B2

公开(公告)日：2013-03-19

申请号：US12610431

申请日：2009-11-02

申请人： Steven C. Pesek ,  Charles Anthony Smith ,  W Alexander Shaffer ,  Richard Allen Hayes

发明人： Steven C. Pesek ,  Charles Anthony Smith ,  W Alexander Shaffer ,  Richard Allen Hayes

IPC分类号： B32B17/10 ,  B32B27/32 ,  B32B27/36 ,  B32B15/08 ,  H01L31/048 ,  H01L31/042 ,  H01L21/56 ,  C08F8/00 ,  C08F20/06

CPC分类号： B32B17/10743 ,  B32B17/10577 ,  B32B17/10853 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T428/269 ,  Y10T428/31507 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31855 ,  Y10T428/31938

摘要： A solar cell module comprises a solar cell layer and an ionomer sheet. The ionomer sheet comprises a first ionomer that is the neutralized product of a first precursor acid copolymer, which, in turn, comprises copolymerized units of ethylene and about 20 to about 30 wt % of copolymerized acrylic or methacrylic acid. The first precursor acid copolymer has a melt flow rate of about 70 to about 1000 g/10 min. When neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the first precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. The ionomer sheet may further comprise a second ionomer that is different from the first ionomer.

摘要翻译： 太阳能电池模块包括太阳能电池层和离聚物片。 离聚物片材包含第一离聚物，其是第一前体酸共聚物的中和产物，其又包含乙烯的共聚单元和约20至约30重量％的共聚的丙烯酸或甲基丙烯酸。 第一种前体酸共聚物的熔体流动速率为约70至约1000g / 10min。 当中和到约40％至约90％的水平时，当包含基本上由钠阳离子组成的抗衡离子时，第一前体酸共聚物产生熔体流动速率为约0.7至约25g / 10min的钠离聚物， 不可检测或低于约3.0J / g的冷冻焓。 离聚物片材还可以包含与第一离聚物不同的第二离聚物。

公开(公告)号：US08399082B2

公开(公告)日：2013-03-19

申请号：US13486511

申请日：2012-06-01

申请人： Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

发明人： Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B27/32 ,  B32B15/08 ,  B32B17/10 ,  H01L31/048 ,  H01L31/042 ,  H01L21/56 ,  C08F8/00 ,  C08F20/06

CPC分类号： C08L33/02 ,  B32B17/10045 ,  B32B17/10743 ,  B32B17/10761 ,  B32B17/10853 ,  B32B17/10981 ,  B32B2367/00 ,  C08L23/0876 ,  C08L2205/02 ,  C08L2205/025 ,  C09J123/0876 ,  F41H5/0407 ,  Y10T428/1352 ,  Y10T428/269 ,  Y10T428/31645 ,  Y10T428/31855 ,  C08L2666/04

摘要： An ionomer blend composition comprises a blend of a first ionomer and a second ionomer that is different from the first ionomer. The first ionomer is derived from a first precursor acid copolymer that has a melt flow rate of about 10 to about 4000 g/10 min and that comprises copolymerized units of an α-olefin and about 20 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid. Moreover, the first precursor acid can be neutralized to a level of about 40% to about 90% to form a sodium ionomer that has a MFR of about 0.7 to about 25 g/10 min and a freeze enthalpy that is less than about 3.0 j/g or that is not detectable, when determined by differential scanning calorimetry (DSC). A variety of articles may comprise or be produced from the ionomer blend composition, for example by injection molding.

摘要翻译： 离聚物共混物组合物包含与第一离聚物不同的第一离聚物和第二离聚物的共混物。 第一离聚物衍生自具有约10至约4000g / 10min的熔体流动速率的第一前体酸共聚物，其包含α-烯烃的共聚单元和约20至约30wt％的共聚单元 α，β-烯属不饱和羧酸。 此外，第一前体酸可被中和至约40％至约90％的水平以形成具有约0.7至约25g / 10min的MFR和小于约3.0j的冷冻焓的钠离聚物 / g，或通过差示扫描量热法（DSC）测定时不可检测。 各种制品可以包括或由离聚物共混组合物制备，例如通过注塑成型。

公开(公告)号：US08399098B2

公开(公告)日：2013-03-19

申请号：US12610701

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B27/32 ,  B32B27/36 ,  B32B27/08 ,  B32B27/00 ,  B32B27/40 ,  B32B17/10 ,  C08F20/06 ,  C08F8/00 ,  C08L31/00

CPC分类号： B32B17/10743 ,  B32B17/10018 ,  B32B2367/00 ,  Y10T428/31507 ,  Y10T428/31573 ,  Y10T428/31645 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31913 ,  Y10T428/31938

摘要： A laminate comprises an ionomeric interlayer sheet which, in turn, comprises or is prepared from a sodium/zinc mixed ionomer that comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 70 to about 1000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry.

摘要翻译： 层压材料包括离聚物中间层片材，其又包含钠盐/锌混合离子交换聚合物或由钠/锌混合离聚​​物制备，所述钠/锌混合离聚​​物包含羧酸根基团和基本上由钠阳离子和锌阳离子组成的抗衡离子的组合。 钠/锌混合离聚​​物是前体酸共聚物的中和产物。 前体酸共聚物包括α-烯烃和α，β-烯键式不饱和羧酸的共聚单元，其熔体流动速率为约70至约1000g / 10min。 此外，当将前体酸共聚物中和至约40％至约90％的水平时，并且当包含基本上由钠离子组成的抗衡离子时，产生具有不可检测或较少的冷冻焓的钠离聚物 当用差示扫描量热法测定时，约为3.0J / g。

公开(公告)号：US08399097B2

公开(公告)日：2013-03-19

申请号：US12610688

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B17/10 ,  B32B27/32 ,  B32B15/08 ,  B32B27/36

CPC分类号： C08F220/06 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  Y10T428/31507 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31938

摘要： A safety laminate comprises an interlayer that comprises an ionomer that is the neutralized product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of a first α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of a first α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms; and has a melt flow rate of about 10 to about 4000 g/10 min. When neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. The ionomer composition may further comprise a second ionomer that has a melt flow rate of about 10 g/10 min or less.

摘要翻译： 安全层压板包括中间层，其包含作为前体酸共聚物的中和物的离聚物。 前体酸共聚物包含具有2至10个碳原子的第一α-烯烃和约20至约30重量％的具有3-8个碳原子的第一个α，β-烯属不饱和羧酸的共聚单元的共聚单元; 并具有约10至约4000g / 10min的熔体流动速率。 当中和至约40％至约90％的水平时，当包含基本上由钠阳离子组成的抗衡离子时，前体酸共聚物产生熔体流动速率为约0.7至约25g / 10min的钠离聚物， 不可检测的或低于约3.0J / g的冷冻焓。 离聚物组合物还可以包含熔体流动速率为约10g / 10分钟或更短的第二离聚物。

公开(公告)号：US08399096B2

公开(公告)日：2013-03-19

申请号：US12610678

申请日：2009-11-02

申请人： Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

发明人： Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B17/10 ,  B32B27/32 ,  B32B15/08 ,  B32B27/36 ,  C08F20/06

CPC分类号： C08F8/44 ,  Y10T428/1352 ,  Y10T428/269 ,  Y10T428/31507 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31938 ,  C08F210/02 ,  C08F220/06

摘要： An ionomer composition comprises an ionomer that is the neutralized product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt %, based on the total weight of the precursor acid copolymer, of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms; a melt flow rate of about 10 to about 4000 g/10 min; and, when neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. Further provided are articles comprising the ionomer composition.

摘要翻译： 离聚物组合物包含作为前体酸共聚物的中和物的离聚物。 前体酸共聚物包含基于前体酸共聚物的总重量的具有2至10个碳原子的α-烯烃和约20至约30重量％的共聚单元的共聚单元，α和bgr-烯属不饱和单体 具有3-8个碳原子的羧酸; 约10至约4000g / 10min的熔体流动速率; 并且当被中和至约40％至约90％的水平时，并且当包含基本上由钠阳离子组成的抗衡离子时，前体酸共聚物产生具有约0.7至约25g / 10min的熔体流动速率的钠离聚物 和不可检测或小于约3.0J / g的冷冻焓。 还提供了包含离聚物组合物的制品。

公开(公告)号：US08399081B2

公开(公告)日：2013-03-19

申请号：US12610435

申请日：2009-11-02

申请人： Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith ,  George Wyatt Prejean

发明人： Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith ,  George Wyatt Prejean

IPC分类号： B32B27/32 ,  B32B15/08 ,  B32B17/10 ,  H01L31/048 ,  H01L31/042 ,  H01L21/56 ,  C08F8/00 ,  C08F20/06

CPC分类号： B32B17/10743 ,  B32B17/10853 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T428/1352 ,  Y10T428/269 ,  Y10T428/31645 ,  Y10T428/31855

摘要： A solar cell module comprising a solar cell layer and an ionomer sheet comprising a sodium/zinc mixed ionomer that is the neutralization product of a precursor acid copolymer; wherein the precursor acid copolymer comprises copolymerized units of an α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms based on the total weight of the precursor acid copolymer; wherein the precursor acid copolymer has a melt flow rate of about 70 to about 1000 g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg; and wherein when about 40% to about 90% of the total content of the carboxylic acid groups present in the precursor acid copolymer are neutralized to carboxylate groups to comprise carboxylate groups and counterions that consist essentially of sodium ions, the resulting sodium ionomer has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry in accordance with ASTM D3418.

摘要翻译： 一种太阳能电池组件，包括太阳能电池层和离子聚合物片，其包含作为前体酸共聚物的中和产物的钠/锌混合离聚​​物; 其中所述前体酸共聚物包括具有2至10个碳原子的α-烯烃和约20至约30重量％共聚单元的基于所述共聚单元的具有3至8个碳原子的α，bgr- - 烯键式不饱和羧酸的共聚单元 前体酸共聚物的总重量; 其中所述前体酸共聚物的熔体流动速率为约70至约1000g / 10min，根据ASTM D1238在190℃和2.16kg下测定; 并且其中当存在于前体酸共聚物中的羧酸基团的总含量的约40％至约90％被中和到羧酸酯基团以包含基本上由钠离子组成的羧酸酯基团和抗衡离子时，所得钠离子共聚物具有冷冻 当通过根据ASTM D3418的差示扫描量热法测定时，不可检测的焓或小于约3.0J / g的焓。

公开(公告)号：US08334033B2

公开(公告)日：2012-12-18

申请号：US12610881

申请日：2009-11-02

申请人： Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

发明人： Karlheinz Hausmann ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B27/32 ,  B32B15/08 ,  B32B17/10 ,  C08F8/00 ,  C08F20/06

CPC分类号： B32B17/10036 ,  B32B17/10743 ,  C08F8/44 ,  C08F210/02 ,  C08F2800/20 ,  C08L23/0876 ,  C08L2205/02 ,  Y10T428/1352 ,  Y10T428/265 ,  Y10T428/269 ,  Y10T428/31645 ,  Y10T428/31855 ,  C08L2666/06 ,  C08F220/06

摘要： A sodium/zinc mixed ionomer comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 10 to about 4000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry. Further provided are articles comprising or prepared from the sodium/zinc mixed ionomer.

摘要翻译： 钠/锌混合离聚​​物包括羧酸根基团和基本上由钠阳离子和锌阳离子组成的抗衡离子的组合。 钠/锌混合离聚​​物是前体酸共聚物的中和产物。 前体酸共聚物包括α-烯烃和α，β-烯键式不饱和羧酸的共聚单元，其熔体流动速率为约10至约4000g / 10min。 此外，当将前体酸共聚物中和至约40％至约90％的水平时，并且当包含基本上由钠离子组成的抗衡离子时，产生具有不可检测或较少的冷冻焓的钠离聚物 当用差示扫描量热法测定时，约为3.0J / g。 还提供了包含或由钠/锌混合离聚​​物制备的制品。