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公开(公告)号:US20130152788A1
公开(公告)日:2013-06-20
申请号:US13692088
申请日:2012-12-03
Applicant: SUD-CHEMIE INC.
Inventor: Wayne Turbeville , Greg Korynta , Todd Cole , Jeffery L. Braden
CPC classification number: B01D53/02 , B01D53/64 , B01D2253/102 , B01D2253/1128 , B01D2257/602 , B01J20/0237 , B01J20/0285 , B01J20/08 , B01J20/106 , B01J20/20 , B01J20/2803 , B01J20/28042 , C10G2300/205 , C10K1/004 , C10K1/32
Abstract: A process for removing mercury from a gas or liquid phase, wherein the gas or liquid phase containing mercury is placed in contact with a composition comprising a precipitated metal sulfide. The precipitated metal sulfide may be made by the process of combining a metal source, sulfide source, and modifier to form the precipitated metal sulfide. The metal source may comprise iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, silver, or gold salts. The metal salt may be selected from metal nitrate, metal sulfate, metal phosphate, metal acetate, metal carbonate, metal hydroxide, metal ammonium carbonate, and metal hydroxycarbonate. The sulfide source is selected from hydrogen sulfide (H2S), carbonyl sulfide (COS), salts of sulfide (S2−), salts of hydrosulfide (HS−), and salts of polysulfide (Sn2−). The modifier may be selected from alumina, silica, aluminosilicate, clay, zeolites, carbon, cement, titania, zirconia.
Abstract translation: 一种从气相或液相中除去汞的方法,其中将含有汞的气相或液相与包含沉淀的金属硫化物的组合物接触。 沉淀的金属硫化物可以通过组合金属源,硫化物源和改性剂以形成沉淀的金属硫化物的方法制备。 金属源可以包括铁,钴,镍,铜,锌,锆,钼,银或金盐。 金属盐可以选自金属硝酸盐,金属硫酸盐,金属磷酸盐,金属乙酸盐,金属碳酸盐,金属氢氧化物,金属碳酸铵和金属羟基碳酸盐。 硫化物源选自硫化氢(H 2 S),硫化羰(COS),硫化物盐(S2-),氢硫化物盐(HS-)和多硫化物盐(Sn2-))。 改性剂可以选自氧化铝,二氧化硅,硅铝酸盐,粘土,沸石,碳,水泥,二氧化钛,氧化锆。
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公开(公告)号:US09381492B2
公开(公告)日:2016-07-05
申请号:US13691977
申请日:2012-12-03
Applicant: Sud-Chemie Inc.
Inventor: Wayne Turbeville , Greg Korynta , Todd Cole , Jeffery L. Braden
CPC classification number: B01J20/20 , B01D15/00 , B01D53/64 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2253/11 , B01D2253/1128 , B01D2255/104 , B01D2255/106 , B01D2255/20707 , B01D2255/20715 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2255/20769 , B01D2255/20792 , B01D2256/245 , B01D2257/602 , B01J20/0237 , B01J20/0248 , B01J20/0285 , B01J20/08 , B01J20/106 , B01J2220/42
Abstract: A process for removing mercury from a gas or liquid phase, wherein the gas or liquid phase containing mercury is placed in contact with a composition comprising a precipitated metal sulfide. The precipitated metal sulfide may be made by the process of combining a metal source, sulfide source, and modifier to form the precipitated metal sulfide. The metal source may comprise iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, silver, or gold salts. The metal salt may be selected from metal nitrate, metal sulfate, metal phosphate, metal acetate, metal carbonate, metal hydroxide, metal ammonium carbonate, and metal hydroxycarbonate. The sulfide source is selected from hydrogen sulfide (H2S), carbonyl sulfide (COS), salts of sulfide (S2-), salts of hydrosulfide (HS—), and salts of polysulfide (Sn2-). The modifier may be selected from alumina, silica, aluminosilicate, clay, zeolites, carbon, cement, titania, zirconia.
Abstract translation: 一种从气相或液相中除去汞的方法,其中将含有汞的气相或液相与包含沉淀的金属硫化物的组合物接触。 沉淀的金属硫化物可以通过组合金属源,硫化物源和改性剂以形成沉淀的金属硫化物的方法制备。 金属源可以包括铁,钴,镍,铜,锌,锆,钼,银或金盐。 金属盐可以选自金属硝酸盐,金属硫酸盐,金属磷酸盐,金属乙酸盐,金属碳酸盐,金属氢氧化物,金属碳酸铵和金属羟基碳酸盐。 硫化物源选自硫化氢(H 2 S),硫化羰(COS),硫化物盐(S2-),氢硫化物盐(HS-)和多硫化物盐(Sn2-))。 改性剂可以选自氧化铝,二氧化硅,硅铝酸盐,粘土,沸石,碳,水泥,二氧化钛,氧化锆。
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公开(公告)号:US08876958B2
公开(公告)日:2014-11-04
申请号:US13692088
申请日:2012-12-03
Applicant: Sud-Chemie Inc.
Inventor: Wayne Turbeville , Greg Korynta , Todd Cole , Jeffery L. Braden
IPC: B01D53/02 , C10K1/00 , B01J20/10 , B01J20/02 , B01D53/64 , B01J20/08 , B01J20/28 , B01J20/20 , C10K1/32
CPC classification number: B01D53/02 , B01D53/64 , B01D2253/102 , B01D2253/1128 , B01D2257/602 , B01J20/0237 , B01J20/0285 , B01J20/08 , B01J20/106 , B01J20/20 , B01J20/2803 , B01J20/28042 , C10G2300/205 , C10K1/004 , C10K1/32
Abstract: A process for removing mercury from a gas or liquid phase, wherein the gas or liquid phase containing mercury is placed in contact with a composition comprising a precipitated metal sulfide. The precipitated metal sulfide may be made by the process of combining a metal source, sulfide source, and modifier to form the precipitated metal sulfide. The metal source may comprise iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, silver, or gold salts. The metal salt may be selected from metal nitrate, metal sulfate, metal phosphate, metal acetate, metal carbonate, metal hydroxide, metal ammonium carbonate, and metal hydroxycarbonate. The sulfide source is selected from hydrogen sulfide (H2S), carbonyl sulfide (COS), salts of sulfide (S2−), salts of hydrosulfide (HS−), and salts of polysulfide (Sn2−). The modifier may be selected from alumina, silica, aluminosilicate, clay, zeolites, carbon, cement, titania, zirconia.
Abstract translation: 一种从气相或液相中除去汞的方法,其中将含有汞的气相或液相与包含沉淀的金属硫化物的组合物接触。 沉淀的金属硫化物可以通过组合金属源,硫化物源和改性剂以形成沉淀的金属硫化物的方法制备。 金属源可以包括铁,钴,镍,铜,锌,锆,钼,银或金盐。 金属盐可以选自金属硝酸盐,金属硫酸盐,金属磷酸盐,金属乙酸盐,金属碳酸盐,金属氢氧化物,金属碳酸铵和金属羟基碳酸盐。 硫化物源选自硫化氢(H 2 S),硫化羰(COS),硫化物盐(S2-),氢硫化物盐(HS-)和多硫化物盐(Sn2-))。 改性剂可以选自氧化铝,二氧化硅,硅铝酸盐,粘土,沸石,碳,水泥,二氧化钛,氧化锆。
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公开(公告)号:US20140155260A1
公开(公告)日:2014-06-05
申请号:US13691977
申请日:2012-12-03
Applicant: SUD-CHEMIE INC.
Inventor: Wayne Turbeville , Greg Korynta , Todd Cole , Jeffery L. Braden
CPC classification number: B01J20/20 , B01D15/00 , B01D53/64 , B01D2253/102 , B01D2253/104 , B01D2253/106 , B01D2253/108 , B01D2253/11 , B01D2253/1128 , B01D2255/104 , B01D2255/106 , B01D2255/20707 , B01D2255/20715 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2255/20769 , B01D2255/20792 , B01D2256/245 , B01D2257/602 , B01J20/0237 , B01J20/0248 , B01J20/0285 , B01J20/08 , B01J20/106 , B01J2220/42
Abstract: A process for removing mercury from a gas or liquid phase, wherein the gas or liquid phase containing mercury is placed in contact with a composition comprising a precipitated metal sulfide. The precipitated metal sulfide may be made by the process of combining a metal source, sulfide source, and modifier to form the precipitated metal sulfide. The metal source may comprise iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, silver, or gold salts. The metal salt may be selected from metal nitrate, metal sulfate, metal phosphate, metal acetate, metal carbonate, metal hydroxide, metal ammonium carbonate, and metal hydroxycarbonate. The sulfide source is selected from hydrogen sulfide (H2S), carbonyl sulfide (COS), salts of sulfide (S2-), salts of hydrosulfide (HS—), and salts of polysulfide (Sn2-). The modifier may be selected from alumina, silica, aluminosilicate, clay, zeolites, carbon, cement, titania, zirconia
Abstract translation: 一种从气相或液相中除去汞的方法,其中将含有汞的气相或液相与包含沉淀的金属硫化物的组合物接触。 沉淀的金属硫化物可以通过组合金属源,硫化物源和改性剂以形成沉淀的金属硫化物的方法制备。 金属源可以包括铁,钴,镍,铜,锌,锆,钼,银或金盐。 金属盐可以选自金属硝酸盐,金属硫酸盐,金属磷酸盐,金属乙酸盐,金属碳酸盐,金属氢氧化物,金属碳酸铵和金属羟基碳酸盐。 硫化物源选自硫化氢(H 2 S),硫化羰(COS),硫化物盐(S2-),氢硫化物盐(HS-)和多硫化物盐(Sn2-))。 改性剂可以选自氧化铝,二氧化硅,硅铝酸盐,粘土,沸石,碳,水泥,二氧化钛,氧化锆
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