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公开(公告)号:US11225618B1
公开(公告)日:2022-01-18
申请号:US17425868
申请日:2020-01-28
申请人: SUSTEON INC.
IPC分类号: B01D53/82 , B01J8/02 , B01J19/00 , B01J20/02 , B01J20/28 , B01J20/30 , C10K1/00 , C10K1/26 , C10K1/32 , B01D53/22 , B01D53/34 , B01D53/52 , B01D53/96
摘要: A continuous desulfurization process and process system are described for removal of reduced sulfur species at gas stream concentrations in a range of from about 5 to about 5000 ppmv, using fixed beds containing regenerable sorbents, and for regeneration of such regenerable sorbents. The desulfurization removes the reduced sulfur species of hydrogen sulfide, carbonyl sulfide, carbon disulfide, and/or thiols and disulfides with four or less carbon atoms, to ppbv concentrations. In specific disclosed implementations, regenerable metal oxide-based sorbents are integrated along with a functional and effective process to control the regeneration reaction and process while maintaining a stable dynamic sulfur capacity. A membrane-based process and system is described for producing regeneration and purge gas for the desulfurization.
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2.
公开(公告)号:US20200238252A1
公开(公告)日:2020-07-30
申请号:US16833545
申请日:2020-03-28
发明人: Jiancheng WANG , Qihuang HUO , Huijun CHEN , Lina HAN , Geping SHU , Liping CHANG , Weiren BAO
摘要: This invention introduces a method of preparing a carbon-based sulfur-loading iron-containing adsorbent for mercury removal, which can solve the problems in the prior art that sulfur-rich heavy organic materials have low-value utilization and the elemental mercury in atmosphere is hard to be efficiently and economically removed by the existing mercury removal agents. A carbon-based sulfur-loading iron-containing adsorbent for mercury removal is prepared in this invention. The adsorbent with a porous structure is prepared in situ by performing steps such as chemical activation of sulfur-rich heavy organic materials that are rich in iron. The adsorbent prepared herein has good mercury removal performance in simulated coal-fired flue gas. This invention not only improves the utilization value of sulfur-rich heavy organic materials, but also prevents SOX pollution caused by the combustion of sulfur-rich heavy organic materials and controls mercury pollution in the coal-fired flue gas.
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公开(公告)号:US10653995B2
公开(公告)日:2020-05-19
申请号:US15704918
申请日:2017-09-14
申请人: G4 Insights Inc.
IPC分类号: B01D53/047 , B01D53/22 , C01B3/38 , C10L3/08 , C10L3/10 , C10J3/46 , C10K1/02 , C10K1/32 , C10K3/04 , C10B49/22 , C10B53/02 , C10B57/06
摘要: Disclosed embodiments provide a system and method for producing hydrocarbons from biomass. Certain embodiments of the method are particularly useful for producing substitute natural gas from forestry residues. Certain disclosed embodiments of the method convert a biomass feedstock into a product hydrocarbon by hydropyrolysis. Catalytic conversion of the resulting pyrolysis gas to the product hydrocarbon and carbon dioxide occurs in the presence of hydrogen and steam over a CO2 sorbent with simultaneous generation of the required hydrogen by reaction with steam. A gas separator purifies product methane, while forcing recycle of internally generated hydrogen to obtain high conversion of the biomass feedstock to the desired hydrocarbon product. While methane is a preferred hydrocarbon product, liquid hydrocarbon products also can be delivered.
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4.
公开(公告)号:US20190084833A1
公开(公告)日:2019-03-21
申请号:US16075577
申请日:2017-02-03
发明人: Michael WEEDON , Behzad BAHTOOI , Calvin BARTHOLOMEW , Hamid Reza RADFARNIA , Bryan IMBER , Debanjan CHAKRABARTI
摘要: There is provided a method for producing hydrocarbon compounds. The method comprising: producing a syngas by introducing a fuel stream comprising a reformable fuel into a reforming system (steam reformer, autothermal reformer, cold plasma reformer and/or internal-reforming fuel cell), and wherein the syngas comprises H2, CO and CO2, and has a ratio of [H2]/[CO] of about 1.4 to about 2.5; producing a decarbonated and dehydrated syngas from the syngas having a ratio of [CO2]/[CO+CO2] of no higher than 0.6; performing a Fischer-Tropsch synthesis on the decarbonated and dehydrated syngas in the presence of a cobalt- or iron-based Fischer-Tropsch catalyst, said Fischer-Tropsch catalyst comprising pellets of trilobe, cylindrical, hollow cylinder or spherical construction with diameter about 0.5 mm to about 3.0 mm and aspect ratio of 1 to 3.5, to produce a product stream comprising the hydrocarbon compounds; and recycling aqueous products and/or tail gas.
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公开(公告)号:US10221360B2
公开(公告)日:2019-03-05
申请号:US15831358
申请日:2017-12-04
发明人: Daxiang Wang , Pingyu Kuai , Meng Li , Yanfeng Zhang
IPC分类号: C10G2/00 , C10K1/00 , C10K1/12 , C01B3/04 , C01B3/52 , C10J3/84 , C10J3/48 , C10J3/00 , C10K1/32
摘要: A method for Fischer-Tropsch synthesis, the method including: 1) gasifying a raw material to obtain a crude syngas including H2, CO and CO2; 2) electrolyzing a saturated NaCl solution using a chloralkali process to obtain a NaOH solution, Cl2 and H2; 3) removing the CO2 in the crude syngas using the NaOH solution obtained in 2) to obtain a pure syngas; and 4) insufflating the H2 obtained in 2) to the pure syngas to adjust a mole ratio of CO/H2 in the pure syngas, and then introducing the pure syngas for Fischer-Tropsch synthesis reaction. A device for Fischer-Tropsch synthesis includes a gasification device, an electrolyzer, a first gas washing device, and a Fischer-Tropsch synthesis reactor.
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公开(公告)号:US10159962B2
公开(公告)日:2018-12-25
申请号:US14373198
申请日:2013-01-17
申请人: INTRAMICRON, INC.
发明人: Hongyun Yang , Paul S. Dimick
IPC分类号: B01J27/125 , C10K1/32 , B01D53/86 , B01J27/053 , C01B17/04 , B01J27/10 , B01J27/128 , B01J27/138 , C10G25/00 , C10G27/04 , C10G27/08 , C10G27/12 , C10G27/14 , C10K1/00 , C10K1/34
摘要: Catalysts for oxidative sulfur removal and methods of making and using thereof are described herein. The catalysts contain one or more reactive metal salts dispersed on one or more substrates. Suitable reactive metal salts include those salts containing multivariable metals having variable valence or oxidation states and having catalytic activity with sulfur compounds present in gaseous fuel streams. In some embodiments, the catalyst contains one or more compounds that function as an oxygen sponge under the reaction conditions for oxidative sulfur removal. The catalysts can be used to oxidatively remove sulfur-containing compounds from fuel streams, particularly gaseous fuel streams having high sulfur content. Due to the reduced catalyst cost, anticipated long catalyst life and reduced adsorbent consumption, the catalysts described herein are expected to provide a 20-60% reduction in annual desulfurization cost for biogas with sulfur contents ranges from 1000-5000 ppmv compared with the best adsorbent approach.
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公开(公告)号:US20170342339A1
公开(公告)日:2017-11-30
申请号:US15165448
申请日:2016-05-26
申请人: Alter NRG Corp. , Hatch Ltd.
摘要: A system for processing a syngas stream including particulate matter, a combustible gas, and acid components is disclosed. The system includes a gasifier vessel configured to produce a raw syngas stream; a gas cooling apparatus configured to cool the raw syngas stream to produce a cooled syngas stream; an HCl and particulate removal apparatus configured to produce a reduced-HCl syngas stream; a first reheat apparatus configured to produce a first reheated syngas stream; a COS and HCN hydrolysis apparatus configured to produce a hydrolyzed syngas stream; an H2S removal apparatus configured to produce a reduced-H2S syngas stream; a second reheat apparatus configured to produce a second reheated syngas stream; an activated carbon bed apparatus configured to produce a polished syngas stream; and a compression and intercooling apparatus configured to compress and cool the polished syngas stream to produce a clean syngas stream.
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公开(公告)号:US09828247B2
公开(公告)日:2017-11-28
申请号:US15102728
申请日:2014-12-16
申请人: Renergi Pty Ltd
发明人: Chun-Zhu Li , Richard Gunawan , Li Dong
IPC分类号: B01D53/02 , C01B3/58 , C01B3/56 , C10K1/04 , C10K1/32 , C10J3/06 , B01D53/04 , C10J3/58 , C10J3/84
CPC分类号: C01B3/58 , B01D53/04 , B01D2253/102 , B01D2255/20738 , B01D2255/20753 , B01D2257/304 , B01D2257/406 , B01D2257/408 , B01D2257/7027 , C01B3/56 , C01B2203/0227 , C01B2203/042 , C01B2203/0435 , C01B2203/0465 , C01B2203/048 , C01B2203/0883 , C01B2203/1047 , C01B2203/1058 , C01B2203/1082 , C01B2203/146 , C10J3/06 , C10J3/58 , C10J3/84 , C10J2300/0916 , C10J2300/093 , C10J2300/094 , C10J2300/1618 , C10J2300/1853 , C10K1/046 , C10K1/32 , Y02P20/13
摘要: The present disclosure provides a process for cleaning raw product gas. The process includes contacting the raw product gas with a flow of catalyst to reform organic contaminants and inorganic contaminants in the raw product gas and to remove particulates. Further, the process includes cooling the resulting product gas via heat exchange with a heat exchange medium in the presence of char or a solid adsorbent medium to condense remaining organic contaminants and inorganic contaminants on the char or solid adsorbent medium and to filter out fine particulates.
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公开(公告)号:US09802872B2
公开(公告)日:2017-10-31
申请号:US14779941
申请日:2014-03-28
发明人: Luwei Chen , Zhi Qun Tian , Armando Borgna , Hiroyuki Kamata , Yoshinori Izumi
IPC分类号: C07C1/02 , C07C1/04 , C07C1/12 , B01J23/755 , C07C9/04 , C10K3/04 , C10K1/32 , C10G2/00 , B01J37/18 , B01J35/00 , B01J35/02 , B01J35/10 , C10L3/08 , B01J37/02
CPC分类号: C07C1/0435 , B01J23/755 , B01J35/0013 , B01J35/002 , B01J35/0053 , B01J35/008 , B01J35/0086 , B01J35/023 , B01J35/1019 , B01J35/1023 , B01J35/1057 , B01J35/1061 , B01J35/1066 , B01J37/0203 , B01J37/0209 , B01J37/18 , C07C1/02 , C07C1/04 , C07C1/0445 , C07C1/12 , C07C9/04 , C07C2521/08 , C07C2523/755 , C10G2/332 , C10K1/32 , C10K3/04 , C10L3/08 , C10L2290/42 , Y02P20/142
摘要: The invention relates to use of a catalyst comprising particles of nickel dispersed in a porous silica matrix for catalyzing a methanation reaction. There is also described a method for methanation of a feedstock at least comprising gases carbon monoxide and hydrogen, said method comprising contacting the feedstock with the catalyst.
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公开(公告)号:US20170145327A1
公开(公告)日:2017-05-25
申请号:US15300271
申请日:2015-04-14
申请人: GDF SUEZ
发明人: BERNARD MARCHAND , YILMAZ KARA , FRÉDÉRIC LEGRAND
CPC分类号: C10K1/04 , B01D53/0438 , B01D53/0462 , B01D53/265 , B01D2253/102 , B01D2253/108 , B01D2253/202 , B01D2256/245 , B01D2257/70 , B01D2257/80 , B01D2259/40083 , B01D2259/4009 , C10K1/26 , C10K1/32
摘要: A method for treating a synthesis gas from a gasification step. The synthesis gas is cooled to condense heavy organic impurities and water. At the end of the cooling step, light organic impurities and inorganic impurities are adsorped by at least one adsorption bed. The water and heavy tars are separated by decantation from the step of cooling the synthesis gas. At least one adsorption bed is regenerated by temperature-modulated or pressure-modulated desorption.
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