公开(公告)号：US06239317B1

公开(公告)日：2001-05-29

申请号：US09019378

申请日：1998-02-05

申请人： Surendra Umesh Kulkarni ,  Vadiraj Subbanna Ekkundi ,  Pradeep Jeevaji Nadkarni ,  Chandrasekhar Dayal Mudaliar ,  Kishore Ramachandra Nivalkar

发明人： Surendra Umesh Kulkarni ,  Vadiraj Subbanna Ekkundi ,  Pradeep Jeevaji Nadkarni ,  Chandrasekhar Dayal Mudaliar ,  Kishore Ramachandra Nivalkar

IPC分类号： C07C3700

CPC分类号： C07C17/10 ,  C07C39/367 ,  C07C41/22 ,  C07C45/46 ,  C07C67/42 ,  C07C25/18 ,  C07C49/84 ,  C07C69/017 ,  C07C69/63 ,  C07C43/29 ,  C07C43/295

摘要： There is described a four step process for the production of halogeno-o-hydroxydiphenyl compounds having the formula in which X is —O—or —CH2—; m is 1 to 3; and n is 1 or 2; wherein in the first step, a diphenyl compound is chlorinated; in a second step the chlorinated compound is acylated in a Friedel-Crafts reaction and optionally again chlorinated after the acylation; in a third step the acyl compound is oxidised; and in a fourth step the oxidized compound is hydrolyzed. The compounds of formula (1) are useful for the protection of organic materials against microorganisms.

摘要翻译： 描述了生产具有X为-O-或-CH 2 - ; m为1至3的甲醛的卤代 - 邻 - 羟基二苯基化合物的四步法; andn为1或2;其中在第一步中，将二苯基化合物氯化; 在第二步中，氯化化合物在Friedel-Crafts反应中被酰化，并且任选地在酰化后再次氯化; 在第三步中，酰基化合物被氧化; 在第四步骤中，氧化的化合物被水解。式（1）的化合物可用于保护有机材料免于微生物。

公开(公告)号：US08314325B2

公开(公告)日：2012-11-20

申请号：US12194008

申请日：2008-08-19

申请人： Kankan Bhaumik ,  Jeremy D. Hurst ,  George Kuriakose ,  Pradeep Jeevaji Nadkarni ,  Meerakani Mohamed Ali Sait ,  Vinodkumar Vasudevan

发明人： Kankan Bhaumik ,  Jeremy D. Hurst ,  George Kuriakose ,  Pradeep Jeevaji Nadkarni ,  Meerakani Mohamed Ali Sait ,  Vinodkumar Vasudevan

IPC分类号： H01L31/042

CPC分类号： H01L31/055 ,  C09B5/62 ,  C09B57/004 ,  Y02E10/52

摘要： A luminescent solar collector comprises a sheet and a light energy converter operatively connected to the sheet, the sheet comprising a thermoplastic polymer and dispersed therein at least two dyes A and B; wherein dye A is a fluorescent dye of Formula (I) and dye B is either a perylene dye of Formula (II) or a diketopyrrolopyrrole dye of Formula (III): wherein R, m, R1, R2, R3, R4, and k are as described herein. The luminescent solar collector has improved output.

摘要翻译： 发光太阳能收集器包括可操作地连接到片材的片材和光能转换器，该片材包含热塑性聚合物并在其中分散有至少两种染料A和B; 其中染料A是式（I）的荧光染料，染料B是式（II）的苝染料或式（III）的二酮吡咯并吡咯染料：其中R，m，R 1，R 2，R 3，R 4和k 如本文所述。 发光太阳能收集器具有改进的输出。

公开(公告)号：US20100043880A1

公开(公告)日：2010-02-25

申请号：US12194199

申请日：2008-08-19

申请人： Kankan Bhaumik ,  Jeremy D. Hurst ,  Pradeep Jeevaji Nadkarni ,  Nedumbamana Sankaran ,  Suresh Velate

发明人： Kankan Bhaumik ,  Jeremy D. Hurst ,  Pradeep Jeevaji Nadkarni ,  Nedumbamana Sankaran ,  Suresh Velate

IPC分类号： H01L31/00

CPC分类号： H01L51/447 ,  C08K5/3437 ,  H01L31/055 ,  H01L51/0053 ,  Y02E10/52 ,  Y02E10/549

摘要： A luminescent solar collector contains a first fluorescent dye and a dye compound of Formula (I) or (II): where R, R′, m, and k are as described herein. The luminescent solar collector has improved output.

摘要翻译： 发光太阳能收集器包含第一荧光染料和式（I）或（II）的染料化合物：其中R，R'，m和k如本文所述。 发光太阳能收集器具有改进的输出。

公开(公告)号：US08728685B2

公开(公告)日：2014-05-20

申请号：US13028807

申请日：2011-02-16

申请人： Andrew A. Burns ,  Sumeet Jain ,  Pradeep Jeevaji Nadkarni ,  Shantaram Narayan Naik ,  Arunkumar Natarajan ,  Kiran ArunKumar Puthamane ,  Michael T. Takemori ,  Vinodkumar Vasudevan

发明人： Andrew A. Burns ,  Sumeet Jain ,  Pradeep Jeevaji Nadkarni ,  Shantaram Narayan Naik ,  Arunkumar Natarajan ,  Kiran ArunKumar Puthamane ,  Michael T. Takemori ,  Vinodkumar Vasudevan

IPC分类号： G03H1/04 ,  G03H1/00

CPC分类号： G03H1/22 ,  G03H1/0011 ,  G03H1/0248 ,  G03H1/0256 ,  G03H1/04 ,  G03H2001/0016 ,  G03H2001/0264 ,  G03H2001/0413 ,  G03H2001/0415 ,  G03H2210/22 ,  G03H2222/15 ,  G03H2240/22 ,  G03H2250/33 ,  G03H2250/34 ,  G03H2250/42 ,  G03H2260/30 ,  G03H2260/31 ,  G03H2260/33 ,  G03H2260/52 ,  G03H2270/21 ,  G11B7/24044 ,  G11B7/245 ,  G11B7/246

摘要： Articles for recording a holographic image are described. The articles include a holographic recording medium having a plurality of surfaces, having a transparent polymeric binder and a photochemically active dye, the holographic recording medium having a holographic image recorded therein formed by exposed areas of the photochemically active dye and unexposed areas of the photochemically active dye; and a first light-blocking layer or material over a first surface of the holographic recording medium from which surface the holographic image is viewed, the light blocking layer or material absorbing light in the wavelength range to which the photochemically active dye is sensitive and allowing transmission of light in a different wavelength range for viewing the holographic image.

摘要翻译： 描述用于记录全息图像的物品。 所述制品包括具有多个表面的全息记录介质，其具有透明聚合物粘合剂和光化学活性染料，所述全息记录介质具有记录在其中的全息图像，所述全息图像由光化学活性染料的曝光区域和光化学活性染料的未曝光区域形成 染料; 以及在所述全息记录介质的第一表面上的第一遮光层或材料，从所述第一表面观察所述全息图像，所述光阻挡层或材料吸收光化学活性染料敏感的波长范围内的光并允许透射 的不同波长范围的光，用于观看全息图像。

公开(公告)号：US07563817B2

公开(公告)日：2009-07-21

申请号：US11300225

申请日：2005-12-14

申请人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanmugam ,  Gurram Kishan ,  Ravindra Vikram Singh

发明人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanmugam ,  Gurram Kishan ,  Ravindra Vikram Singh

IPC分类号： A61K31/405 ,  C07D209/34

CPC分类号： C07D209/46 ,  C08G64/12

摘要： A method for purifying a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprises contacting a crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine with a purification agent, removing a 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound from the crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine, and producing a purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine product comprising less than 200 parts per million of the 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound. The purification agent is selected from the group consisting of an acidic material, an organic acid chloride, an organic anhydride, or a combination thereof. The 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound has a formula: wherein each R1 is independently selected from a group consisting of a hydrocarbyl radical, a nitro radical, and a halogen atom; “a” is an integer from 0 to 4; and Ar1 and Ar2 are independently at each occurrence an aromatic radical. The purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidines have low color, and are useful for preparing polymers, such as polycarbonates having a low color. The polycarbonates are useful for producing articles.

摘要翻译： 纯化2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶的方法包括使粗2-二芳基-3,3-双（羟基芳基）苯并二氮吡啶与纯化剂接触，除去2-芳基-3-（氨基芳基 ）-3-（羟基芳基）苯并二氮嘧啶化合物，并制备纯化的2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶产物，其包含小于200份 百万的2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并嘧啶化合物。 净化剂选自酸性物质，有机酰氯，有机酸酐或其组合。 2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并二氮嘧啶化合物具有下式：其中每个R 1独立地选自烃基，硝基和卤素原子; “a”是从0到4的整数; Ar 1和Ar 2在每次出现时独立地为芳族基团。 纯化的2-芳基-3,3-双（羟基芳基）苯二甲酰亚胺具有低的颜色，并且可用于制备聚合物，例如具有低颜色的聚碳酸酯。 聚碳酸酯可用于制造制品。

公开(公告)号：US20120208110A1

公开(公告)日：2012-08-16

申请号：US13028807

申请日：2011-02-16

申请人： Andrew A. Burns ,  Sumeet Jain ,  Pradeep Jeevaji Nadkarni ,  Shantaram Narayan Naik ,  Arunkumar Natarajan ,  Kiran ArunKumar Puthamane ,  Michael T. Takemori ,  Vinodkumar Vasudevan

发明人： Andrew A. Burns ,  Sumeet Jain ,  Pradeep Jeevaji Nadkarni ,  Shantaram Narayan Naik ,  Arunkumar Natarajan ,  Kiran ArunKumar Puthamane ,  Michael T. Takemori ,  Vinodkumar Vasudevan

IPC分类号： G03H1/22 ,  G03H1/00

CPC分类号： G03H1/22 ,  G03H1/0011 ,  G03H1/0248 ,  G03H1/0256 ,  G03H1/04 ,  G03H2001/0016 ,  G03H2001/0264 ,  G03H2001/0413 ,  G03H2001/0415 ,  G03H2210/22 ,  G03H2222/15 ,  G03H2240/22 ,  G03H2250/33 ,  G03H2250/34 ,  G03H2250/42 ,  G03H2260/30 ,  G03H2260/31 ,  G03H2260/33 ,  G03H2260/52 ,  G03H2270/21 ,  G11B7/24044 ,  G11B7/245 ,  G11B7/246

摘要： Articles for recording a holographic image are described. The articles include a holographic recording medium having a plurality of surfaces, having a transparent polymeric binder and a photochemically active dye, the holographic recording medium having a holographic image recorded therein formed by exposed areas of the photochemically active dye and unexposed areas of the photochemically active dye; and a first light-blocking layer or material over a first surface of the holographic recording medium from which surface the holographic image is viewed, the light blocking layer or material absorbing light in the wavelength range to which the photochemically active dye is sensitive and allowing transmission of light in a different wavelength range for viewing the holographic image.

摘要翻译： 描述用于记录全息图像的物品。 所述制品包括具有多个表面的全息记录介质，其具有透明聚合物粘合剂和光化学活性染料，所述全息记录介质具有记录在其中的全息图像，所述全息图像由光化学活性染料的曝光区域和光化学活性染料的未曝光区域形成 染料; 以及在所述全息记录介质的第一表面上的第一遮光层或材料，从所述第一表面观察所述全息图像，所述光阻挡层或材料吸收光化学活性染料敏感的波长范围内的光并允许透射 的不同波长范围的光，用于观看全息图像。

公开(公告)号：US07790832B2

公开(公告)日：2010-09-07

申请号：US11849523

申请日：2007-09-04

申请人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanumgam ,  Gurram Kishan ,  Ravindra Vikram Singh

发明人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanumgam ,  Gurram Kishan ,  Ravindra Vikram Singh

IPC分类号： C08G64/00 ,  C08G63/02

CPC分类号： C07D209/46 ,  C08G64/12

摘要： A method for purifying a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprises contacting a crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine with a purification agent, removing a 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound from the crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine, and producing a purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine product comprising less than 200 parts per million of the 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound. The purification agent is selected from the group consisting of an acidic material, an organic acid chloride, an organic anhydride, or a combination thereof. The 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound has a formula: wherein each R1 is independently selected from a group consisting of a hydrocarbyl radical, a nitro radical, and a halogen atom; “a” is an integer from 0 to 4; and Ar1 and Ar2 are independently at each occurrence an aromatic radical. The purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidines have low color, and are useful for preparing polymers, such as polycarbonates having a low color. The polycarbonates are useful for producing articles.

摘要翻译： 纯化2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶的方法包括使粗2-二芳基-3,3-双（羟基芳基）苯并二氮吡啶与纯化剂接触，除去2-芳基-3-（氨基芳基 ）-3-（羟基芳基）苯并二氮嘧啶化合物，并制备纯化的2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶产物，其包含小于200份 百万的2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并嘧啶化合物。 净化剂选自酸性物质，有机酰氯，有机酸酐或其组合。 2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并二氮嘧啶化合物具有下式：其中每个R 1独立地选自烃基，硝基和卤素原子; “a”是从0到4的整数; Ar 1和Ar 2在每次出现时独立地为芳族基团。 纯化的2-芳基-3,3-双（羟基芳基）苯二甲酰亚胺具有低的颜色，并且可用于制备聚合物，例如具有低颜色的聚碳酸酯。 聚碳酸酯可用于制造制品。

公开(公告)号：US07763760B2

公开(公告)日：2010-07-27

申请号：US10870353

申请日：2004-06-16

申请人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni

发明人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni

IPC分类号： C07C17/00

CPC分类号： B01J31/26 ,  B01J27/122 ,  B01J31/02 ,  B01J31/0215 ,  B01J31/04 ,  B01J31/30 ,  B01J2531/16 ,  C07B39/00 ,  C07C17/12 ,  C07C25/125

摘要： A method for ring-halogenating an aromatic compound comprises contacting with chlorine or bromine, a mixture comprising the aromatic compound and a mixed copper salt of formula Cu(Y)X, where Y comprises a counterion derived from an organic acid, where the organic acid has a pKa relative to water of 0 or greater; and X comprises Cl, Br, I, or (SO42−)1/2; to produce a reaction mixture comprising a haloaromatic compound and a copper(II) halide residue.

摘要翻译： 芳族化合物的环卤化方法包括与氯或溴接触，包含芳族化合物和式Cu（Y）X的混合铜盐的混合物，其中Y包含衍生自有机酸的抗衡离子，其中有机酸 相对于水的pKa为0以上; X包括Cl，Br，I或（SO42-）1/2; 以产生包含卤代芳族化合物和卤化铜（II）的反应混合物。

公开(公告)号：US07329720B2

公开(公告)日：2008-02-12

申请号：US11288912

申请日：2005-11-29

申请人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni

发明人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni

IPC分类号： C08G63/12

CPC分类号： C07D209/46

摘要： A method for increasing a mean particle size of a 2-hydrocarbyl-3,3-bis(hydroxyaryl)phthalimidine is provided. The method comprises forming a mixture comprising a feedstream of the 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, and a solvent composition comprising an organic solvent and water, wherein the organic solvent is capable of at least partially dissolving the 2-hydrocarbyl-3,3-bis(hydroxyaryl)phthalimidine and forming an adduct with the 2-hydrocarbyl-3,3-bis(hydroxyaryl)phthalimidine. Then the mixture is heated at a temperature and for a time effective to decompose the adduct and form a 2-hydrocarbyl-3,3-bis(hydroxyaryl)phthalimidine product having a mean particle size greater than 5 microns. The 2-hydrocarbyl-3,3-bis(hydroxyaryl)phthalimidines with increased particle size are useful for producing polymers.

摘要翻译： 提供了增加2-烃基-3,3-双（羟基芳基）苯并吡嗪酮的平均粒度的方法。 该方法包括形成包含2-烃基-3,3-双（4-羟基芳基）苯并嘧啶的进料流和包含有机溶剂和水的溶剂组合物的混合物，其中有机溶剂能够至少部分地将 2-羟基芳基）苯并二氮吡啶，并与2-烃基-3,3-双（羟基芳基）苯并二氮吡啶形成加合物。 然后将混合物在有效分解加合物的温度下加热并形成平均粒度大于5微米的2-烃基-3,3-双（羟基芳基）苯并二氮嘧啶产物。 粒径增加的2-烃基-3,3-双（羟基芳基）苯二甲酰亚胺可用于生产聚合物。

公开(公告)号：US08304647B2

公开(公告)日：2012-11-06

申请号：US12194097

申请日：2008-08-19

申请人： Kankan Bhaumik ,  Jeremy D. Hurst ,  Pradeep Jeevaji Nadkarni ,  Nedumbamana Sankaran ,  Suresh Velate

发明人： Kankan Bhaumik ,  Jeremy D. Hurst ,  Pradeep Jeevaji Nadkarni ,  Nedumbamana Sankaran ,  Suresh Velate

IPC分类号： H01L31/00 ,  C07D471/00

CPC分类号： C09K11/06 ,  C08K5/3437 ,  C09K2211/1011 ,  H01L31/055 ,  H01L51/0053 ,  H01L51/447 ,  Y02E10/52 ,  Y02E10/549

摘要： Disclosed are fluorescent dye compounds of Formula (I): wherein R1, R2, and G are as described herein. The fluorescent dyes are suitable for use in luminescent solar collectors or as a colorant. Methods of making the fluorescent dyes and luminescent solar collectors comprising them are also described.

摘要翻译： 公开了式（I）的荧光染料化合物：其中R1，R2和G如本文所述。 荧光染料适用于发光太阳能收集器或着色剂。 还描述了制造包含它们的荧光染料和发光太阳能收集器的方法。