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    AMMONIA DECOMPOSITION CATALYST
    1.
    发明申请
    AMMONIA DECOMPOSITION CATALYST 审中-公开
    氨基酸分解催化剂

    公开(公告)号：US20110306489A1

    公开(公告)日：2011-12-15

    申请号：US13203376

    申请日：2010-02-18

    申请人： Susumu Hikazudani ,  Takuma Mori ,  Chikashi Inazumi ,  Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Hironobu Kumagai

    发明人： Susumu Hikazudani ,  Takuma Mori ,  Chikashi Inazumi ,  Haruyuki Nakanishi ,  Hidekazu Arikawa ,  Hironobu Kumagai

    IPC分类号： B01J21/18

    CPC分类号： C01B3/047 ,  B01J21/18 ,  B01J21/185 ,  B01J23/462 ,  B01J23/745 ,  B01J35/0046 ,  B01J35/0053 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/086 ,  B01J37/18 ,  B82Y30/00 ,  C08G14/06 ,  C08L61/04 ,  Y02E60/364

    摘要： Disclosed is an ammonia decomposition catalyst which is obtained by heat-treating a complex at a temperature of 360° C. to 900° C. in a reducing atmosphere, wherein the complex containing a polymer having a molecular weight of 1,000 to 500,000 represented by the formula [I], a transition metal coordinated with the polymer, and an activated carbon or a carbon nanotube added thereto. In a case of using the carbon nanotube, an alkali metal compound or an alkaline earth metal compound is added to the heat-treated complex. R1 represents H or hydrocarbon having 1 to 10 carbon atoms, R2 and R3 each represent H, halogen, nitro, acyl, ester, carboxyl, formyl, nitrile, sulfone, aryl, or alkyl group having 1 to 15 carbon atoms, X and Y each represent H or OH, Z represents CH or N, R4 and R5 each represent H, OH, ether, amino, aryl, or alkyl group having 1 to 15 carbon atoms, x represents a real number of 1 to 2, y represents a real number of 1 to 3, and n represents a real number of 2 to 120. The amount of the transition metal deposited on the catalyst can be increased without deteriorating the dispersion of the metal, so that the amount of the catalyst required to obtain a desired activity can be reduced.

    摘要翻译： 公开了一种氨还原催化剂，其通过在还原气氛中在360℃至900℃的温度下热处理络合物获得，其中所述络合物含有分子量为1,000至500,000的聚合物，其由 式[I]，与聚合物配位的过渡金属，和加入其中的活性炭或碳纳米管。 在使用碳纳米管的情况下，向热处理复合体中添加碱金属化合物或碱土金属化合物。 R1表示H或碳原子数1〜10的烃，R2和R3各自表示H，卤素，硝基，酰基，酯，羧基，甲酰基，腈，砜，芳基或碳原子数1〜15的烷基，X和Y 各自表示H或OH，Z表示CH或N，R 4和R 5各自表示H，OH，醚，氨基，芳基或具有1至15个碳原子的烷基，x表示1至2的实数，y表示 实数1〜3，n表示2〜120的实数。可以提高沉积在催化剂上的过渡金属的量，而不会使金属的分散性恶化，从而获得所需催化剂的量 可以减少所需的活动。

    PROCESS FOR PRODUCING ISOTHIAZOLE DERIVATIVE
    4.
    发明申请
    PROCESS FOR PRODUCING ISOTHIAZOLE DERIVATIVE 有权
    生产异噻唑衍生物的方法

    公开(公告)号：US20120046473A1

    公开(公告)日：2012-02-23

    申请号：US13318323

    申请日：2010-04-30

    申请人： Takayuki Nakamura ,  Hironobu Kumagai ,  Mahito Ogawa

    发明人： Takayuki Nakamura ,  Hironobu Kumagai ,  Mahito Ogawa

    IPC分类号： C07D275/03

    CPC分类号： C07D275/02 ,  C07D275/03

    摘要： A process for producing 3,4-dichloro-5-cyanoisothiazole represented by a general formula (3): the process comprising: reacting a nitrile compound represented by a general formula (1): (wherein “n” denotes an integer of 0 to 2), with sulfur chloride represented by a general formula (2): [Chemical Formula 18] SmCl2   (2) (wherein “m” represents an integer of 1 to 2), or a mixture thereof in an aprotic polar solvent. There is provided a process for producing 3,4-dichloro-5-cyanoisothiazole, which is capable of suppressing by-production of a waste, without using a raw material having a having a strong toxicity; and is capable of providing a product having a higher purity in a high yield and efficiency in an industrial scale, in a simple manner.

    摘要翻译： 由通式（3）表示的制备3,4-二氯-5-氰基异噻唑的方法：该方法包括：使由通式（1）表示的腈化合物：其中“n”表示0至0的整数 2），用通式（2）表示的氯化硫：[化学式18] SmCl 2（2）（其中“m”表示1〜2的整数）或其在非质子极性溶剂中的混合物。 提供一种能够抑制副产物的3,4-二氯-5-氰基异噻唑的方法，而不使用具有强毒性的原料; 并且能够以简单的方式以高产率和高效率的工业规模提供具有较高纯度的产品。

    Substituted sym-triindole
    5.
    发明申请
    Substituted sym-triindole 失效
    取代的sym-三吲哚

    公开(公告)号：US20070191455A1

    公开(公告)日：2007-08-16

    申请号：US10589534

    申请日：2005-02-14

    申请人： Hidetaka Hiyoshi ,  Hironobu Kumagai ,  Hideo Ooi

    发明人： Hidetaka Hiyoshi ,  Hironobu Kumagai ,  Hideo Ooi

    IPC分类号： A61K31/407 ,  C07D487/14

    CPC分类号： C07D487/14 ,  C09B23/005 ,  C09B23/0058 ,  C09B23/105 ,  C09B23/145 ,  C09B57/00 ,  H01L51/0067 ,  H01L51/007 ,  H01L51/0072 ,  Y02E10/549 ,  Y02P70/521

    摘要： A novel substituted Sym-triindole derivative that is applicable to a wide spectrum of uses, such as various electrification preventions, electrification controls, capacitors, batteries, chemical sensors, displays, organic EL materials, solar cells, photodiodes, phototransistors, nonlinear materials, photorefractive materials, rustproof agents, adhesives, fibers, antistatic paints, electrodeposition paints, plating primers, electric corrosion protections and the like. There is provided a substituted Sym-triindole derivative of the general formula (1) (wherein R1, R2, R3 and R4 are each independently hydrogen, a halogen, a C1-C6 alkyl or the like, provided that, in no event, all of R1, R2, R3 and R4 are hydrogen simultaneously).

    摘要翻译： 适用于各种电气化防止，电气化控制，电容器，电池，化学传感器，显示器，有机EL材料，太阳能电池，光电二极管，光电晶体管，非线性材料，光折射等广泛用途的新型取代的对三吲哚衍生物 材料，防锈剂，粘合剂，纤维，抗静电涂料，电沉积涂料，电镀底漆，电腐蚀保护等。 提供通式（1）的取代的对三吲哚衍生物（其中R 1，R 2，R 3和R 3， 如果在任何情况下，全部R 1，R 2，R 2，R 3，R 4， R 3，R 3和R 4同时为氢。

    Substituted sym-triindole
    6.
    发明授权
    Substituted sym-triindole 失效
    取代的sym-三吲哚

    公开(公告)号：US07632954B2

    公开(公告)日：2009-12-15

    申请号：US10589534

    申请日：2005-02-14

    申请人： Hidetaka Hiyoshi ,  Hironobu Kumagai ,  Hideo Ooi

    发明人： Hidetaka Hiyoshi ,  Hironobu Kumagai ,  Hideo Ooi

    IPC分类号： C07D487/22

    CPC分类号： C07D487/14 ,  C09B23/005 ,  C09B23/0058 ,  C09B23/105 ,  C09B23/145 ,  C09B57/00 ,  H01L51/0067 ,  H01L51/007 ,  H01L51/0072 ,  Y02E10/549 ,  Y02P70/521

    摘要： A novel substituted Sym-triindole derivative that is applicable to a wide spectrum of uses, such as various electrification preventions, electrification controls, capacitors, batteries, chemical sensors, displays, organic EL materials, solar cells, photodiodes, phototransistors, nonlinear materials, photorefractive materials, rustproof agents, adhesives, fibers, antistatic paints, electrodeposition paints, plating primers, electric corrosion protections and the like. There is provided a substituted Sym-triindole derivative of the general formula (1) (wherein R1, R2, R3 and R4 are each independently hydrogen, a halogen, a C1-C6 alkyl or the like, provided that, in no event, all of R1, R2, R3 and R4 are hydrogen simultaneously).

    摘要翻译： 适用于各种电气化防止，电气化控制，电容器，电池，化学传感器，显示器，有机EL材料，太阳能电池，光电二极管，光电晶体管，非线性材料，光折射等广泛用途的新型取代的对三吲哚衍生物 材料，防锈剂，粘合剂，纤维，抗静电涂料，电沉积涂料，电镀底漆，电腐蚀保护等。 提供通式（1）的取代的对三吲哚衍生物（其中R 1，R 2，R 3和R 4各自独立地为氢，卤素，C 1 -C 6烷基等，条件是，在任何情况下，全部为 R1，R2，R3和R4同时为氢）。

    Process for producing isothiazole derivative
    7.
    发明授权
    Process for producing isothiazole derivative 有权
    异噻唑衍生物的制备方法

    公开(公告)号：US08563745B2

    公开(公告)日：2013-10-22

    申请号：US13318323

    申请日：2010-04-30

    申请人： Takayuki Nakamura ,  Hironobu Kumagai ,  Mahito Ogawa

    发明人： Takayuki Nakamura ,  Hironobu Kumagai ,  Mahito Ogawa

    IPC分类号： C07D275/03

    CPC分类号： C07D275/02 ,  C07D275/03

    摘要： A process for producing 3,4-dichloro-5-cyanoisothiazole represented by a general formula (3): the process comprising: reacting a nitrile compound represented by a general formula (1): (wherein “n” denotes an integer of 0 to 2), with sulfur chloride represented by a general formula (2): SmCl2  (2) (wherein “m” represents an integer of 1 to 2), or a mixture thereof in an aprotic polar solvent. There is provided a process for producing 3,4-dichloro-5-cyanoisothiazole, which is capable of suppressing by-production of a waste, without using a raw material having a strong toxicity; and is capable of providing a product having a higher purity in a high yield and efficiency in an industrial scale, in a simple manner.

    摘要翻译： 由通式（3）表示的制备3,4-二氯-5-氰基异噻唑的方法：该方法包括：使由通式（1）表示的腈化合物：其中“n”表示0至0的整数 2），由通式（2）表示的氯化硫：SmCl 2（2）（其中“m”表示1〜2的整数）或其在非质子极性溶剂中的混合物。 提供了不使用具有强毒性的原料的3,4-二氯-5-氰基异噻唑的制造方法，其能够抑制废弃物的副产物。 并且能够以简单的方式以高产率和高效率的工业规模提供具有较高纯度的产品。