公开(公告)号：US3647843A

公开(公告)日：1972-03-07

申请号：US3647843D

申请日：1969-11-20

申请人： TENNECO CHEM

发明人： WALKER DAVID G ,  KEYWORTH DONALD A

IPC分类号： C07C7/156 ,  C07F5/06 ,  C10L3/02 ,  C10L3/04 ,  C07F1/08

CPC分类号： C10L3/04 ,  C07C7/156 ,  C07F5/069 ,  C10L3/02 ,  C07C11/24 ,  C07C11/28 ,  C07C11/22

摘要： ACETYLENE REACTS WITH CUPROUS ALUMINUM TETRACHLORIDE UNDER AMBIENT CONDITIONS TO FORM A STABLE COMPLEX THAT IS SOLUBLE IN AROMATIC HYDROCARBONS. SINCE ACETYLENE CAN BE READILY RECOVERED FROM THE, SOLUTIONS CONTAINING THE ACETYLENE-CUPROUS ALUMINUM TETRACHLORIDE ARE USEFUL AS A STORAGE, TRANSPORT, OR REACTION MEDIUM FOR ACETYLENE.

公开(公告)号：US3870482A

公开(公告)日：1975-03-11

申请号：US39867873

申请日：1973-09-19

申请人： TENNECO CHEM

发明人： WALKER DAVID G ,  KEYWORTH DONALD A ,  SUDDUTH JEROME R

IPC分类号： B01D53/72 ,  B01D53/77 ,  C01B32/336 ,  C07C1/00 ,  C07C7/12 ,  C07C11/22 ,  C07C67/00 ,  B01D53/04

CPC分类号： C07C7/12 ,  C01B32/336 ,  C07C11/28 ,  C07C11/30

摘要： Diacetylene and vinylacetylene are separated from gas streams that contain from 1 to 10 mole percent of these compounds by contacting the gas stream with activated carbon the surface of which has been saturated with an inert, non-explosive gas that has carbon adsorption characteristics similar to those of the C4 acetylenic compounds until the surface of the carbon is saturated with adsorbed C4 acetylenic compounds. A stream of inert gas is used to strip the C4 acetylenic compounds from the carbon.

摘要翻译： 将乙炔和乙炔基乙炔从含有1至10摩尔％的这些化合物的气流中分离，通过使气流与活性炭接触，活性炭的表面已被惰性的非爆炸性气体饱和，该气体具有类似于 的C4炔属化合物，直到碳的表面被吸附的C4炔属化合物饱和。 使用惰性气体流从碳上除去C4炔属化合物。

公开(公告)号：US3706181A

公开(公告)日：1972-12-19

申请号：US3706181D

申请日：1970-11-20

申请人： TENNECO CHEM

发明人： WALKER DAVID G ,  KEYWORTH DONALD A

IPC分类号： C07C11/22 ,  C10L3/02 ,  C10L3/04 ,  B01D53/02

CPC分类号： C10L3/04 ,  C07C11/22 ,  C10L3/02

摘要： An improved safe method for the handling, concentration, purification, storage, and transportation of C3 and C4 acetylenic hydrocarbons involves contacting a gas stream that contains 10 mole percent or less of these compounds with activated carbon to form compositions that comprise activated carbon on whose surface about 2 percent to 10 percent, based on the weight of the carbon, of C3 and/or C4 acetylenic compounds have been adsorbed. These activated carbon compositions, which are air stable and which cannot be detonated, can be handled, stored and transported without appreciable danger of explosion. Concentrated and purified acetylenic compounds can be recovered by stripping the carbon with, for example, a nitrogen-methylene chloride mixture. Further improvement in the safety of the method results when the pyrolysis gas is diluted with an inert, non-explosive gas that has carbon adsorption characteristics similar to those of the C4 acetylenic compounds prior to the treatment of the activated carbon with the pyrolysis gas stream.

摘要翻译： 用于处理，浓缩，纯化，储存和运输C3和C4炔烃的改进的安全方法包括将含有10摩尔％或更少这些化合物的气流与活性炭接触以形成包含其表面上的活性炭的组合物 已经吸附了约2％至10％，基于碳的重量，C3和/或C4炔属化合物。 这些空气稳定且不能引爆的活性炭组合物可以被处理，储存和运输，而没有明显的爆炸危险。 浓缩和纯化的炔属化合物可以通过用例如氮 - 二氯甲烷混合物汽提碳来回收。 当利用热解气流处理活性炭之前，用具有类似于C4炔属化合物的碳吸附特性的惰性非爆炸性气体稀释热解气体时，该方法的安全性进一步提高。

公开(公告)号：US3927176A

公开(公告)日：1975-12-16

申请号：US39860673

申请日：1973-09-19

申请人： TENNECO CHEM

发明人： TURNBO ROY GLEN ,  KEYWORTH DONALD A

IPC分类号： B01D53/28 ,  B01D53/14 ,  B01D53/26 ,  B01D53/48 ,  B01D53/72 ,  B01J19/14 ,  B01J20/04 ,  C07C1/00 ,  C07C7/11 ,  C07C9/02 ,  C07C67/00 ,  C10K1/16 ,  B01D53/34

CPC分类号： B01D53/1493 ,  B01D53/263

摘要： Water and certain other impurities are removed from gas streams by contacting the gas streams with a liquid sorbent that comprises a bimetallic salt complex having the generic formula MIMIIXn.Aromatic WHEREIN MI is a Group I-B metal, MII is a Group III-A metal, X is halogen, n is the sum of the valences of MI and MII, and Aromatic is a monocyclic aromatic hydrocarbon having 6 to 12 carbon atoms.

摘要翻译： 通过使气流与包含具有通式MIMIIXn的双金属盐络合物的液体吸附剂接触，从气流中除去水和某些其它杂质。

公开(公告)号：US3923958A

公开(公告)日：1975-12-02

申请号：US34531673

申请日：1973-03-27

申请人： TENNECO CHEM

发明人： TURNBO ROY G ,  KEYWORTH DONALD A

IPC分类号： B01D19/04 ,  B01D53/14 ,  B01D53/34 ,  B01D53/77 ,  B01J19/00 ,  C01B32/40 ,  C07C1/00 ,  C07C7/152 ,  C07C11/00 ,  C07C67/00

CPC分类号： B01D19/0404 ,  B01D53/1493

摘要： Normal paraffinic hydrocarbons having from 5 to 25 carbon atoms are used to prevent or minimize the foaming that occurs when liquid sorbents that comprise bimetallic salt complexes having the generic formula MIMIIXn. Aromatic, wherein MI is a Group I-B metal, MII is a group III-A metal, X is halogen, n is the sum of the valences of MI and MII, and Aromatic is a monocyclic aromatic compound having 6 to 12 carbon atoms, are brought into contact with large volumes of gases. The preferred anti-foaming agents for these processes are mineral oil and non-detergent motor oil.

摘要翻译： 具有5至25个碳原子的正链烷烃用于防止或最小化当包含具有通式MIMIIXn的双金属盐络合物的液体吸附剂时发生的起泡。 芳香族，其中MI为IB族金属，MII为III-A族金属，X为卤素，n为MI与MII的化合价之和，芳香族为碳原子数为6〜12的单环芳香族化合物 与大量气体接触。 用于这些方法的优选消泡剂是矿物油和非洗涤剂机油。