公开(公告)号：US3753907A

公开(公告)日：1973-08-21

申请号：US3753907D

申请日：1971-05-13

Applicant: TEXACO INC

Inventor： HAUGEN H ,  DADURA J

IPC: C07D203/12 ,  C10M159/12 ,  C10M1/48

CPC classification number: C10M159/126 ,  C07D203/12 ,  C10M2207/027 ,  C10M2209/084 ,  C10M2217/023 ,  C10M2219/046 ,  C10M2223/045 ,  C10M2223/12 ,  C10N2210/02

Abstract: WHERE R IS HYDROGEN OR W-AMINOALKYL OF FROM 1 TO 5 CARBONS AND A MONOETHOXYLATED HYDROLYZED POLYALKENEA2S5 REACTANT, SAID DERAVATIVE PREPARED BY: (A) FIRST CONTACTING AN ALIPHATIC POLYALKENE OF AN AVERAGE MOLECULAR WEIGHT OF BETWEEN ABOUT 50 AND 5000 WITH P2S IN THE PRESENCE OF SULFUR AT A FIRST ELEVATED TEMPERATURE, (B) SECOND CONTACTING THE RESULTING POLYALKENE-P2S5 REACTION PRODUCT WITH STEAM AT A SECOND ELEVATED TEMPERATURE, (C) REMOVING INORGANIC PHOSPHORUS ACID FROM THE STEAM TREATED (HYDROLYZD) POLYALKENE-P2S5 REACTION PRODUCT, (D) THIRD CONTACTING THE INORGANIC ACID FREE, STEAM TREATED POLYALKENE-P2S5 REACTION PRODUCT WITH ETHYLENE OXIDE AT A THIRD ELEVATE TEMPERATURE IN A MOLE RATIO OF SAID INORGANIC ACID FREE, STEAM TREATED P2S5POLYALKENE REACTION PRDUCT TO SAID ETHYLENE OXIDE OF BETWEEN ABOUT 1:1 AND 1:1.5 TO FORM SAID MONOETHOXYLATED REACTANT, (E) FOURTH CONTACTINGTHE ETHOXYLATD DERIVATIVE WITH SAID AZIRIDINE AT A FOURTH ELEVATED TEMPERATURE UTILIZING A MOLE RATIO OF SAID DERIVATIVE TO SAID AZIRIDINE OF BETWEEN ABOUT 3:1 AND 1:2 TO FORM SAID DETERGENT-DISPERSANT DERIVATIVE.

R-N
AN AZIRIDINE DETERGENT-DISPERSANT DERIVATIVE, LUBE OIL COMPOSITIONS CONTAINING SAID DERIVATIVE, AND MANUFACTURE THEREOF, SAID DERATIVE BEING THE REACTION PRODUCT OF AN AZIRIDINE OF THE FORMULA:

Abstract translation: 氮丙啶洗涤剂分散剂衍生物，含有所述衍生物的润滑油组合物及其制备，所述衍生物是下式的氮丙啶的反应产物：

公开(公告)号：US3856691A

公开(公告)日：1974-12-24

申请号：US31538272

申请日：1972-12-15

Applicant: TEXACO INC

Inventor： HAUGEN H ,  WEETMAN D

IPC: C10M169/00 ,  C10M1/22

CPC classification number: C10M1/08 ,  C10M2203/108 ,  C10M2205/00 ,  C10M2207/027 ,  C10M2207/046 ,  C10M2215/064 ,  C10M2215/066 ,  C10M2217/023 ,  C10M2219/044 ,  C10M2223/045 ,  C10M2223/065 ,  C10N2210/02 ,  C10N2230/12

Abstract: Lubricating oil composition containing an ashless rust inhibitor prepared from a reaction of glycerol with a C8 to C25 alpha olefin epoxide.

Abstract translation: 含有由甘油与C 8〜C 25α-烯烃环氧化物反应制备的无灰防锈剂的润滑油组合物。

公开(公告)号：US3810838A

公开(公告)日：1974-05-14

申请号：US21023871

申请日：1971-12-20

Applicant: TEXACO INC

Inventor： HAUGEN H

IPC: C07F9/24 ,  C10M1/48

CPC classification number: C10M1/08 ,  C07F9/24 ,  C07F9/247 ,  C10M2201/062 ,  C10M2207/027 ,  C10M2209/084 ,  C10M2219/046 ,  C10M2223/02 ,  C10M2223/045 ,  C10M2223/049 ,  C10M2223/12 ,  C10M2225/00 ,  C10M2225/02 ,  C10M2225/041 ,  C10M2229/02 ,  C10M2229/05 ,  C10N2210/02

Abstract: THE MANUFACTURE OF OLIGOMERIC PHOSPHORODIAMIDATE CHARACTERIZED BY THE FORMULA:

(R''-O-P(=O)(-NH-R)2)N

WHERE R IS ALKARYL OF FROM 12 TO 24 CARBONS R'' IS LOWER ALKYL OF FROM 2 TO 6 CARBONS AND N IS AN AVERAGE INTEGER OF FROM 1 TO 4 AND SULFURIZED DERIVATIVES THEREOF COMPRISING CONTACTING A PRIMARY AMINE OF THE FORMULA:

R-NH2

WHERE R IS AS HERETOFORE DEFINED WITH AN ALKYLDIALOPHOSPHATE CHARACTERIZED BY THE FORMULA:

R''-O-P(=O)(-X)2

WHERE R'' IS AS HERETOFORE DEFINED AND X IS A HALOGEN SELECTED FROM CHLORINE OR BROMINE UTILIZING A MOLE RATIO OF AMINE TO SAID PHOSPHATE OF BETWEEN ABOUT 1.7:1 AND 2.3:1 IN THE ABSENCE OF SOLVENT AND CATALYST AT A TEMPERATURE BETWEEN ABOUT 170 AND 200*C. WHILE CONTINUOUSLY BLOWING THE REACTION MIXTURE WITH AN INERT GAS, RECOVERING THE OLIGOMERIC PHOSPHORODIAMIDATE PRODUCT AND OPTIONALLY CONTACTING SAIDD PRODUCT WITH PHOSPHORUS PENTASULFIDE UTILIZING A MOLE RATIO OF PENTASULFIDE TO PRODUCT OF BETWEEN ABOUT 0.05:1 AND 0.5:1 AT A TEMPERATURE BETWEEN ABOUT 80 AND 150*C. IN THE PRESENCE OF AN INERT SOLVENT WHILE CONTINUOUSLY BLOWING THE REACTION MIXTURE WITH AN INERT GAS AND RECOVERING THE SULFURIZED PHOSPHORODIAMIDATE REACTION PRODUCT. BOTH THE PHOSPHORODIAMIDATE PRODUCT AND SULFURIZED PHOSPORODIAMIDATE REACTION PRODUCT WHEN INCORPORATED IN A HYDROCARBON LUBRICATING OIL IN AN AMOUNT OF BETWEEN ABOUT 1.0 AND 10 WT. PERCENT FUNCTION AS A COMBINATION CORROSION, OXIDATION AND WEAR INHIBITOR (LOAD CARRYING AND EXTREME PRESSURE ADDITIVE).

Abstract translation: 制备低聚磷酰胺，其特征在于下式：

公开(公告)号：US3761414A

公开(公告)日：1973-09-25

申请号：US3761414D

申请日：1971-09-15

Applicant: TEXACO INC

Inventor： HAUGEN H ,  CHAFETZ H

IPC: C07C67/00 ,  C07C313/00 ,  C07C319/14 ,  C07C323/20 ,  C10M135/20 ,  C10M135/30 ,  C10M159/22 ,  C10M169/00 ,  C10N10/04 ,  C10N30/04 ,  C10N30/10 ,  C10N30/12 ,  C10N40/25 ,  C10M1/20

CPC classification number: C07C323/00 ,  C10M135/20 ,  C10M135/30 ,  C10M159/22 ,  C10M2219/02 ,  C10M2219/087 ,  C10M2219/088 ,  C10M2219/089 ,  C10M2221/00 ,  C10M2221/02 ,  C10M2221/043 ,  C10M2225/041 ,  C10N2270/02

Abstract: A LUBRICATING OIL COMPOSITION CONTAINING SULFURIZED NORMAL CALCIUM ALKYLPHENOLATE DETERGENT DISPERSANT OF IMPROVED ANTICORROSIVE PROPERTIES AND RESISTANCE TO OXIDATION, SAID DISPERSANT PREPARED BY A THREE-STEP PROCEDURE COMPRISING (1) REACTING AT A TEMPERATURE BETWEEN ABOUT 200 AND 425* F. IN THE PRESENCE OF A HYDROCARBON LUBRICATING OIL AN ALKYLPHENOL WITH A FIRST ADDITION OF CALCIUM ALKOXYALKOXIDE UTILIZING BETWEEN ABOUT 45 AND 90 WT. PERCENT OF THE STOICHIOMETRIC AMOUNT REQUIRED TO CONVERT THE ALKYLPHENOL TO CALCIUM ALKYLPHENOLATE, (2) CONTACTING AT A TEMPERATURE BETWEEN ABOUT 350 AND 425*F. THE RESULTANT REACTION MIXTURE WITH SULFUR UTILIZING A MOLE RATIO OF SULFURTO INITIAL ALKYLPHENOL OF BETWEEN ABOUT 0.5:1 AND 8:1 WHILE PASSING AN INERT GAS THROUGH THE REACTION MIXTURE AT A RATE OF BETWEEN ABOUT 0.1 AND 10 S.C.F.H./GALLON AT BETWEEN ABOUT 350 AND 425*F. UNTIL HYDROGEN SULFIDE CONTENT OF LESS THAN ABOUT 3 P.P.M. IS OBTAINED, (3) REACTING THE BLOWN MIXTURE WITH A SECOND ADDITION OF CALCIUM ALKOXYALKOXIDE AT A TEMPERATURE OF BETWEEN ABOUT 350 AND 425*F., SAID FIRST AND SECOND ADDITION TOTALING BETWEEN ABOUT 100 AND 120% OF THE STOICHIOMETRIC AMOUNT OF CALCIUM ALKOXYALKOXIDE TO FORM SAID CALCIUM ALKYLPHENOLATE, SAID COMPOSITION PREFERABLY CONTAINING A SUPPLEMENTARY DETERGENT DISPERSANT COMPRISING AN ETHYLENE OXIDE DERIVTIVE OF AN INORGANIC PHOSPHORUS ACID FREE, STEAM HYDROLYZED, POLYBUTENE-P2S5 REACTION PRODUCT.