LEWIS ACID CATALYSED SYNTHESIS OF 1,2-BIS(PERFLUOROALKYL)ETHYLENES

    公开(公告)号:US20220185749A1

    公开(公告)日:2022-06-16

    申请号:US17442641

    申请日:2020-04-17

    Abstract: A method of producing a fluoroolefin includes contacting a compound of formula (1), RfCH═CHF, with a fluorinated ethylene compound of formula (2), CX1X2═CX3X4 in the presence of a Lewis acid catalyst. In the compound of formula (1), Rf is a C1-C10 perfluorinated alkyl group. In the compound of formula (2), X1, X2, X3, and X4 are each independently H, Cl, or F and at least one of X1, X2, X3, and X4 is F. The resulting composition comprises a compound of formula (3), RfCF3(CX5X6CX7X8)nCH═CHCX9X10CX11X12F. In the compound of formula (3), X5, X6, X7, X8, X9, X10, X11, and X12 are each independently H, Cl, or F, n is an integer of 0 or 1, and the total number of each of H, Cl, and F corresponds to the total number of each of H, Cl, and F provided by the fluorinated ethylene compound of formula (2).

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