Abstract:
This invention provides lithium manganate which has a high output and is excellent in high-temperature stability. This invention relates to lithium manganate particles which are produced by mixing a lithium compound, a manganese compound, a Y compound and an A compound and then calcining the resulting mixture, and have a composition represented by the following chemical formula 1 and an average secondary particle diameter (D50) of 1 to 15 μm, in which Y is at least one element selected from the group consisting of Al and Mg; A is a sintering aid element having a melting point of not higher than 850° C.; x and y satisfy 0.03≦x≦0.15 and 0≦y≦0.20, respectively; z is in the range of 0 to 2.5 mol % based on Mn, wherein the lithium manganate particles have a sulfur content of not more than 100 ppm. Li1+xMn2-x-yYyO4zA (Chemical Formula 1)
Abstract:
The present invention aims at providing lithium manganate having a high output and an excellent high-temperature stability. The above aim can be achieved by lithium manganate particles having a primary particle diameter of not less than 1 μm and an average particle diameter (D50) of kinetic particles of not less than 1 μm and not more than 10 μm, which are substantially in the form of single crystal particles and have a composition represented by the following chemical formula: Li1+xMn2-x-yYyO4 in which Y is at least one element selected from the group consisting of Al, Mg and Co; x and y satisfy 0.03≦x≦0.15 and 0.05≦y≦0.20, respectively, wherein the Y element is uniformly dispersed within the respective particles, and an intensity ratio of I(400)/I(111) thereof is not less than 33% and an intensity ratio of I(440)/I(111) thereof is not less than 16%.
Abstract translation:本发明的目的在于提供具有高输出和优异的高温稳定性的锰酸锂。 上述目的可以通过一次粒径不小于1μm的锰酸锂颗粒和动态颗粒的平均粒径(D50)不小于1μm和不大于10μm来实现,其基本上在 具有由以下化学式表示的组成的Li1 + xMn2-x-yYyO4,其中Y是选自Al,Mg和Co中的至少一种元素; x和y分别满足0.03 @ x @ 0.15和0.05 @ y @ 0.20,其中Y元素均匀分散在各个颗粒内,其I(400)/ I(111)的强度比不小于33 %,I(440)/ I(111)的强度比不小于16%。