Abstract:
Problem To provide a polyurethane elastic yarn having good heat setting properties in a wide temperature range and high thermal adhesive strength in a wide temperature range while also maintaining its elastic properties (permanent deformation and elongation). Solution A polyurethane elastic yarn comprising polyurethane polymer [A] and polyurethane polymer [B] below, wherein the ratio of polyurethane polymer [A] to polyurethane polymer [B] in terms of parts by mass is from 1:99 to 30:70 or from 70:30 to 99:1, the exothermic peak (crystallization peak) of the polyurethane elastic yarn as measured by a differential scanning calorimeter (DSC) is in the range from 110° C. to 210° C., and the heat capacity at the exothermic peak is 3.0 J/g or more and 100 J/g or less. Polyurethane polymer [A]: a polyurethane polymer using as starting materials polymer diol A whose main chain repeating unit is an ether or an ester, diisocyanate A whose main skeleton is aromatic or aliphatic, and a single low molecular weight diol A having from 2 to 4 carbon atoms CA serving as a chain extender. Polyurethane polymer [B]: a polyurethane polymer using as starting materials polymer diol A, diisocyanate A, and a single low molecular weight diol B having from 1 to 4 carbon atoms CB more than CA serving as a chain extender.
Abstract:
To provide a polyurethane elastic yarn that is superior in unwinding properties and adhesive properties in respect to a hot melt adhesive agent, and to provide a manufacturing method thereof. A polyurethane elastic yarn wherein the main structural component of the polyurethane is a polymer diol or diisocyanate; and includes a polymer that includes, as the main structural unit, a structural unit that uses an aromatic olefin and/or an aliphatic diolefin as a monomer, and is partially hydrogenated or completely hydrogenated.
Abstract:
Provided is a fragrance-retaining fiber that, after absorption of a fragrance component, retains the fragrance even though a long period of time has passed. In particular, provided is a fragrance-retaining polyurethane-based fiber having, 48 hours after absorption of a fragrance component, a total fragrance component emission of from 0.1 μg/g·h to 1000 μg/g·h.
Abstract:
An elastic fiber of the present invention having an elastic fiber treatment agent attached to the fiber surface, comprises: a hydrocarbon resin (A) having a structure in which a polymer including a structural unit whose monomer is at least one selected from aromatic olefins and aliphatic diolefins as the main structural unit is partially or fully hydrogenated; and a hydrocarbon oil (B). In this way, an elastic fiber and a fiber structure comprising the same are provided that are suitable for obtaining an elastic sheet that has excellent elastic fiber unraveling properties and adhesiveness to hot melt adhesives, and that exhibits good adhesiveness even when processed at a high draft, and for obtaining a sanitary product that is soft to the touch.
Abstract:
The present invention relates to a polyurethane resin including, as constituent units, a diol (a1) having a number average molecular weight of 500 to 10,000, an organic diisocyanate (b), and a chain extender (a2). The total concentration of urethane groups and urea groups in the polyurethane resin is 1.25 to 2.50 mmol/g based on the weight of the polyurethane resin. Hard segment domains of the polyurethane resin have an average domain size of 20 to 30 nm as measured with an atomic force microscope.
Abstract:
[Problem] To provide a polyurethane elastic fiber with excellent spinnability, stretchability, thermal adhesion, and unwinding properties, and a production method therefor. [Solution] A polyurethane elastic fiber having as a main component a polyurethane whose main starting materials are a polymer diol and a diisocyanate, wherein the polyurethane elastic fiber contains the three components in (a) through (c) below.
(a) A thermoplastic polyurethane elastomer (b) A rosin and/or derivative thereof (c) A cellulose ester and/or derivative thereof
Abstract:
The present invention relates to polyurethane elastic fibers obtained by spinning a polyurethane resin. The polyurethane resin includes, as constituent units, a diol (a1) having a number average molecular weight of 500 to 10,000, an organic diisocyanate (b), and a chain extender (a2). The total concentration of urethane groups and urea groups in the polyurethane resin is 1.25 to 2.50 mmol/g based on the weight of the polyurethane resin. Hard segment domains of the polyurethane resin have an average domain size of 20 to 30 nm as measured with an atomic force microscope.