Abstract:
The present invention provides polyurethanes including a reaction product of components including (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
Abstract:
The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
Abstract:
Acrylate-terminated urethane polybutadienes are obtained by reaction of low-monomer 1:1 monoadducts of reactive olefinic compounds and diisocyanates with hydroxy-terminated polybutadienes.
Abstract:
Provided is a resin molded article for an automobile interior material, the resin molded article achieving both resin strength permitting formation of a thin film, and crease resistance. This molded article is to be used in an automobile interior material, the resin molded article being obtained by slush-molding a powdered thermoplastic urethane urea resin composition (P) that satisfies (1)-(5) below, said resin composition (P) containing an additive and a thermoplastic urethane urea resin (U) obtained by reacting a high-molecular diol (a), a linear alkane diol (b), a monool (c), a diamine (d), and an organic diisocyanate (e): (1) (a) contains a specific polyester diol; (2) the weight of (b) is within a specific range relative to the total weight of (a)-(e); (3) the tensile strength of a film comprising (P) is 8.0 MPa or higher; (4) the storage modulus of (P) at 130° C. is 0.1-5.0 MPa; (5) the ratio of the storage modulus of (P) at 50° C. to the storage modulus at 23° C. by a specific measurement method is 50% or higher.
Abstract:
The present invention relates to polyurethane elastic fibers obtained by spinning a polyurethane resin. The polyurethane resin includes, as constituent units, a diol (a1) having a number average molecular weight of 500 to 10,000, an organic diisocyanate (b), and a chain extender (a2). The total concentration of urethane groups and urea groups in the polyurethane resin is 1.25 to 2.50 mmol/g based on the weight of the polyurethane resin. Hard segment domains of the polyurethane resin have an average domain size of 20 to 30 nm as measured with an atomic force microscope.
Abstract:
The invention relates to alcohol-modified glycidyl carbamate resins wherein at least some of the glycidol groups in the resin have been replaced with an alcohol. The invention also relates to coating compositions containing the resins.
Abstract:
The invention relates to alcohol-modified glycidyl carbamate resins wherein at least some of the glycidol groups in the resin have been replaced with an alcohol. The invention also relates to coating compositions containing the resins.
Abstract:
The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
Abstract:
It is the object of the present invention to provide a hollow resin particle and an organic-inorganic hybrid particle, which have excellent dispersibility in a binder component and prevent the diffuse reflection of light and can attain an antireflection layer having high alkali resistance when used as a particle constituting an antireflection layer having a low refractive index, and a method of producing the hollow resin particle.
Abstract:
Embodiments relate to a relatively rapid transesterification process including transesterifying condensation polymers such as polyethylene terephthalate (PET), or other polyesters used in commerce, with a modifying monomer mix containing other monomers to manufacture new polymers containing the pre-condensed moieties. The process preferably only involves transesterification as a reaction mechanism. The process preferably produces a rapid buildup of molecular weight and/or polymer uniformity by the high temperature transesterification of the condensation polymer with the modifying monomer mixture. The process can be performed in any suitable vessel including an extrusion line, and it has the advantage of greatly reduced cycle times over currently used condensation polymer utilization processes such as the recycling of PET into other materials.