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公开(公告)号：US20210317238A1
公开(公告)日：2021-10-14
申请号：US16330612
申请日：2017-09-07
发明人： Alexandre Welle , Aurélien Vantomme , Jean-François Carpentier , Gilles Schnee , Olivier Miserque , Evgueni Kirillov
IPC分类号： C08F4/6592 , C08F4/642 , C08F210/02 , C08F210/06
摘要： The present invention relates to new bis(metallocene) compounds, new catalyst compositions, process for preparing the new bis(metallocene) compounds and use of said new catalyst compositions to polymerise olefins. The bis(metallocene) compounds of the invention are homo- or hetero bis(metallocene) molecules in which same or different metallocene moieties are connected by a phenylene bridge. The phenylene bridge is either para-substituted, meta-substituted or ortho-substituted by the two metallocene moieties.
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2.发明授权Isocyantate-free method for preparing poly(carbonate-urethane) or poly(ester-urethane) 有权用于制备聚（碳酸酯 - 氨基甲酸酯）或聚（酯 - 氨基甲酸酯）的无异氰酸酯的方法公开(公告)号：US09365675B2
公开(公告)日：2016-06-14
申请号：US14729499
申请日：2015-06-03
CPC分类号： C08G71/04 , C08G64/0208 , C08G64/0216 , C08G64/0225 , C08G64/0241 , C08G64/305
摘要： Poly(carbonate-urethane) or poly(ester-urethane) may be characterized in that of carbonate soft segments have molecular weights Mn ranging between 10,000 and 250,000 g/mol. The segments' length may be monitored by the ring-opening polymerization condition. The process of preparing the poly(carbonate-urethane) or poly(ester-urethane) may include immortal ring-opening polymerization of a cyclic carbonate or of a cyclic ester or diester monomers in the presence of a first catalyst system and diols or polyols. The process may include chemical modification of the hydroxyl chain-end groups into carboxylic groups in the presence of a second catalyst system. The process may include a coupling reaction with at least 2 equivalents of a second cyclic carbonate, enabling coupling with the carboxylic moiety in the presence of a third catalyst system. The process may include polyaddition of a diamine or a polyamine via ring-opening of the second cyclic carbonate, and obtention of poly(carbonate-urethane) or poly(ester-urethane).
摘要翻译： 聚（碳酸酯 - 氨基甲酸酯）或聚（酯 - 氨基甲酸酯）的特征可以在于碳酸盐软链段的分子量Mn在10,000和250,000g / mol之间。 可以通过开环聚合条件监测段的长度。 制备聚（碳酸酯 - 氨基甲酸酯）或聚（酯 - 氨基甲酸酯）的方法可以包括在第一催化剂体系和二醇或多元醇的存在下环状碳酸酯或环状酯或二酯单体的永久开环聚合。 该方法可以包括在第二催化剂体系的存在下将羟基链端基化学修饰成羧基。 该方法可以包括与至少2当量的第二环状碳酸酯的偶联反应，使得能够在第三催化剂体系的存在下与羧基部分偶联。 该方法可以包括通过第二环状碳酸酯的开环加成二胺或多胺，以及获得聚（碳酸酯 - 氨基甲酸酯）或聚（酯 - 氨基甲酸酯）。
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3.发明申请Isocyantate-free Method for Preparing Poly(carbonate-urethane) or Poly(ester-urethane) 审中-公开不含异氰酸酯的聚（碳酸酯 - 氨基甲酸酯）或聚（酯 - 氨基甲酸酯）公开(公告)号：US20150267001A1
公开(公告)日：2015-09-24
申请号：US14729499
申请日：2015-06-03
CPC分类号： C08G71/04 , C08G64/0208 , C08G64/0216 , C08G64/0225 , C08G64/0241 , C08G64/305
摘要： Poly(carbonate-urethane) or poly(ester-urethane) may be characterised in that of carbonate soft segments have molecular weights Mn ranging between 10,000 and 250,000 g/mol. The segments' length may be monitored by the ring-opening polymerisation condition. The process of preparing the poly(carbonate-urethane) or poly(ester-urethane) may include immortal ring-opening polymerisation of a cyclic carbonate or of a cyclic ester or diester monomers in the presence of a first catalyst system and diols or polyols. The process may include chemical modification of the hydroxyl chain-end groups into carboxylic groups in the presence of a second catalyst system. The process may include a coupling reaction with at least 2 equivalents of a second cyclic carbonate, enabling coupling with the carboxylic moiety in the presence of a third catalyst system. The process may include polyaddition of a diamine or a of amine via ring-opening of the second cyclic carbonate, and obtention of poly(carbonate-urethane) or poly(ester-urethane).
摘要翻译： 聚（碳酸酯 - 氨基甲酸酯）或聚（酯 - 氨基甲酸酯）的特征可以在于碳酸盐软链段的分子量Mn在10,000和250,000g / mol之间。 可以通过开环聚合条件监测段的长度。 制备聚（碳酸酯 - 氨基甲酸酯）或聚（酯 - 氨基甲酸酯）的方法可以包括在第一催化剂体系和二醇或多元醇的存在下环状碳酸酯或环状酯或二酯单体的永久开环聚合。 该方法可以包括在第二催化剂体系的存在下将羟基链端基化学修饰成羧基。 该方法可以包括与至少2当量的第二环状碳酸酯的偶联反应，使得能够在第三催化剂体系的存在下与羧基部分偶联。 该方法可以包括通过第二环状碳酸酯的开环加成二胺或胺，以及获得聚（碳酸酯 - 氨基甲酸酯）或聚（酯 - 氨基甲酸酯）。
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公开(公告)号：US20210277155A1
公开(公告)日：2021-09-09
申请号：US16330645
申请日：2017-09-07
发明人： Alexandre Welle , Aurélien Vantomme , Jean-François Carpentier , Gilles Schnee , Olivier Miserque , Evgueni Kirillov
IPC分类号： C08F10/06 , C08F2/02 , C08F4/659 , C08F4/6592
摘要： The present invention relates to a new process for preparing a polypropylene using new bis(metallocene) compounds in catalyst compositions. The bis(metallocene) compounds of the invention are homo- or hetero bis(metallocene) molecules in which same or different metallocene moieties are connected by a phenylene bridge. The phenylene bridge is either para-substituted, meta-substituted or ortho-substituted by the two metallocene moieties
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公开(公告)号：US20210284767A1
公开(公告)日：2021-09-16
申请号：US16330641
申请日：2017-09-07
发明人： Alexandre Welle , Aurélien Vantomme , Jean-François Carpentier , Gilles Schnee , Olivier Miserque , Evgueni Kirillov
IPC分类号： C08F110/02 , C08L23/08 , C08F4/6592 , C08F4/659
摘要： The present invention relates to a new process for preparing a polyethylene using new bis(metallocene) compounds in catalyst compositions. The bis(metallocene) compounds of the invention are homo- or hetero bis(metallocene) molecules in which same or different metallocene moieties are connected by a phenylene bridge. The phenylene bridge is either para-substituted, meta-substituted or ortho-substituted by the two metallocene moieties.
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6.发明授权公开(公告)号：US09371418B2
公开(公告)日：2016-06-21
申请号：US14407834
申请日：2013-06-13
CPC分类号： C08G63/64 , C07D317/36 , C08G63/08 , C08G63/823 , C08G63/83 , C08G64/18
摘要： A process for copolymerizing selectively i) ethylene carbonate with ii) one or more cyclic esters can include contacting the ethylene carbonate with the one or more cyclic esters in the presence of a catalyst. The catalyst can be a Zn-complex with a diaminophenolate ligand (NNO) or a β-diiminate ligand (BDI).
摘要翻译： 选择性地共聚合i）碳酸亚乙酯与ii）一种或多种环酯的方法可以包括在催化剂存在下使碳酸亚乙酯与一种或多种环状酯接触。 该催化剂可以是与二氨基苯酚酸盐配体（NNO）或二胺配体（BDI）的Zn络合物。
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