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公开(公告)号:US12217907B2
公开(公告)日:2025-02-04
申请号:US17539491
申请日:2021-12-01
Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA , NICHIA CORPORATION
Inventor: Masaaki Ito , Daisuke Ichigozaki , Noritsugu Sakuma , Akihito Kinoshita , Michiya Kume , Hisashi Maehara
Abstract: A rare-earth magnet and a method of manufacturing the same are provided. The method includes: preparing Sm—Fe—N magnetic powder; preparing reforming material powder containing metallic zinc; mixing the magnetic powder and the reforming material powder to obtain mixed powder; subjecting the mixed powder to compression molding in a magnetic field to obtain a magnetic-field molded body; subjecting the magnetic-field molded body to pressure sintering to obtain a sintered body; and subjecting the sintered body to heat treatment. A content proportion of the metallic zinc in the reforming material powder is 10 to 30% by mass with respect to the mixed powder. When a temperature and time in conditions for the heat treatment are defined as x° C. and y hours, respectively, the formulas y≥−0.32x+136 and 350≤x≤410 are met.
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公开(公告)号:US11996219B2
公开(公告)日:2024-05-28
申请号:US17478043
申请日:2021-09-17
Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventor: Noritsugu Sakuma , Tetsuya Shoji , Akihito Kinoshita , Akira Kato
CPC classification number: H01F1/057 , H01F41/0253
Abstract: A magnetic material according to the present disclosure includes a main phase having an R2T14B type crystal structure (R is a rare earth element and T is a transition metal element). The main phase has a composition represented by ((Nd, Pr)(1-x-y)LaxR1y))2((Fe(1-z-w)(Co, Ni)zMw))14B (where, R1 is a rare earth element other than Nd, Pr, and La, M is an element other than Fe, Co, Ni, and a rare earth element, and the like, and 0.25≤x≤1.00, 0≤y≤0.10, 0.15≤z≤0.40, and 0≤w≤0.1 are satisfied). A manufacturing method of the magnetic material according to the present disclosure includes melting a raw material containing the elements constituting the main phase and solidifying the melted raw material.
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公开(公告)号:US11935676B2
公开(公告)日:2024-03-19
申请号:US17480568
申请日:2021-09-21
Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventor: Daisuke Ichigozaki , Tetsuya Shoji , Noritsugu Sakuma , Akihito Kinoshita , Masaaki Ito
CPC classification number: H01F1/059 , C22C38/002 , C22C38/005 , C22C38/105 , C23C8/26 , H01F41/0253 , C22C2202/02
Abstract: An Sm—Fe—N-based magnetic material according to the present disclosure includes a main phase having a predetermined crystal structure. The main phase has a composition represented by a molar ratio formula (Sm(1-x-y-z)LaxCeyR1z)2(Fe(1-p-q-s)CopNiqMs)17Nh (where, R1 is a predetermined rare earth element, M is a predetermined element, and 0≤x+y
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公开(公告)号:US11869690B2
公开(公告)日:2024-01-09
申请号:US17578856
申请日:2022-01-19
Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventor: Noritsugu Sakuma , Tetsuya Shoji , Akihito Kinoshita , Akira Kato
CPC classification number: H01F1/0577 , C22C38/005 , C22C38/10 , H01F41/0293 , C22C2202/02 , H01F41/0266
Abstract: A rare earth magnet in which the amount used of a heavy rare earth element is more reduced while maintaining enhancement of the coercive force, and a producing method thereof are provided. The rare earth magnet of the present disclosure has a main phase 10 and a grain boundary phase 20. The main phase 10 has a composition represented by R12T14B. The main phase 10 has a core part 12 and a shell part 14. Denoting the abundances of R2 and Ce (R2 is heavy rare earth element) occupying 4f site of the shell part 14 as R24f and Ce4f, respectively, and denoting the abundances of R2 and Ce occupying 4g site of the shell part 14 as R24g and Ce4g, respectively, the rare earth magnet satisfies 0.44≤R24g/(R24f+R24g)≤0.70 and 0.04≤(Ce4f+Ce4g)/(R24f+R24g). The rare earth magnet-producing method of the present disclosure uses a modifier containing at least R2 and Ce.
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公开(公告)号:US20240186036A1
公开(公告)日:2024-06-06
申请号:US18488076
申请日:2023-10-17
Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventor: Noritsugu Sakuma , Tetsuya Shoji , Akihito Kinoshita
IPC: H01F1/057
CPC classification number: H01F1/057
Abstract: The R-T-B-based rare earth magnet 100 of the present disclosure includes a main phase 10 having an R2T14B-type crystal structure and a grain boundary phase 20. The average grain size of the main phase 10 is from 1.0 to 10,0 μm. The main phase 10 has a core portion 12 and a shell portion 14. The total content ratio of cerium, lanthanum, yttrium and scandium is higher in the core portion 12 than in the shell portion 14. The total content ratio of neodymium, praseodymium, gadolinium, terbium, dysprosium and holmium is higher in the shell portion 14 than in the core portion 12. The R-T-B-based rare earth magnet 100 contains from 0.05 to 0.50 at % of carbon. The content ratio of the carbon is higher in the grain boundary phase 20 than in the main phase 10.
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公开(公告)号:US11664140B2
公开(公告)日:2023-05-30
申请号:US17182993
申请日:2021-02-23
Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventor: Noritsugu Sakuma , Tetsuya Shoji , Akihito Kinoshita
CPC classification number: H01F1/0577 , C22C38/005 , H01F1/058 , H01F41/0266 , H01F41/0293
Abstract: A rare earth magnet includes a main phase and a particle boundary phase and in which an overall composition is represented by a formula, (R2(1-x)R1x)yFe(100-y-w-z-v)CowBzM1v.(R3(1-p)M2p)q.(R4(1-s)M3s)t, where R1 is a light rare earth element, R2 and R3 are a medium rare earth element, R4 is a heavy rare earth element, M1, M2, M3 are a predetermined metal element. The main phase includes a core portion, a first shell portion, and a second shell portion. The content proportion of medium rare earth element is higher in the first shell portion than in the core portion, the content proportion of medium rare earth element is lower in the second shell portion than in the first shell portion. The second shell portion contains heavy rare earth elements.
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公开(公告)号:US11522420B2
公开(公告)日:2022-12-06
申请号:US16811811
申请日:2020-03-06
Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventor: Akihito Kinoshita , Noritsugu Sakuma , Tetsuya Shoji , Kosuke Yonekawa
Abstract: A method of producing a motor core includes preparing a soft magnetic plate containing a transition metal element, preparing a modifying member containing an alloy having a melting point lower than a melting point of the soft magnetic plate, bringing the modifying member into contact with a part of a plate surface of the soft magnetic plate, causing the modifying member to diffuse and penetrate into the soft magnetic plate from a contact surface between the soft magnetic plate and the modifying member and forming a hard magnetic phase-containing part in a part of the soft magnetic plate, and laminating a plurality of soft magnetic plates on each other after the modifying member is brought into contact with the part of the plate surface of the soft magnetic plate.
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公开(公告)号:US12080455B2
公开(公告)日:2024-09-03
申请号:US17475944
申请日:2021-09-15
Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventor: Daisuke Ichigozaki , Tetsuya Shoji , Noritsugu Sakuma , Akihito Kinoshita , Masaaki Ito
CPC classification number: H01F1/059 , C22C38/001 , C22C38/005 , C22C38/105 , C23C8/26 , H01F41/0253 , C22C2202/02
Abstract: An Sm—Fe—N-based magnetic material according to the present disclosure includes a main phase having a predetermined crystal structure. The main phase has a composition represented by (Sm(1-x-y-z)LaxCeyR1z)2(Fe(1-p-q-s)CopNiqMs)17Nh (where, R1 is predetermined rare earth elements and the like, M is predetermined elements and the like, and 0.04≤x+y≤0.50, 0≤z≤0.10, 0≤p+q≤0.10, 0≤s≤0.10, and 2.9≤h≤3.1 are satisfied). A crystal volume of the main phase is 0.833 nm3 to 0.840 nm3. A manufacturing method of the Sm—Fe—N-based magnetic material according to the present disclosure includes nitriding a magnetic material precursor including a crystal phase having a composition represented by (Sm(1-x-y-z)LaxCeyR1z)2(Fe(1-p-q-s)CopNiqMs)17.
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公开(公告)号:US20220093298A1
公开(公告)日:2022-03-24
申请号:US17480568
申请日:2021-09-21
Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
Inventor: Daisuke Ichigozaki , Tetsuya Shoji , Noritsugu Sakuma , Akihito Kinoshita , Masaaki Ito
Abstract: An Sm—Fe—N-based magnetic material according to the present disclosure includes a main phase having a predetermined crystal structure. The main phase has a composition represented by a molar ratio formula (Sm(1-x-y-z)LaxCeyR1z)2(Fe(1-p-q-s)CopNiqMs)17Nh (where, R1 is a predetermined rare earth element, M is a predetermined element, and 0≤x+y
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