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公开(公告)号：US4332865A
公开(公告)日：1982-06-01
申请号：US193156
申请日：1980-10-02
CPC分类号： H01M6/5072 , H01M6/182 , H01M6/50 , H01M6/5088
摘要： A process for producing a solid electrolyte primary cell comprising a lithium anode and an iodine containing cathode. In the process the cell undergoes preliminary cell discharge of at least 2 mAh per cm.sup.2 of the lithium anode surface immediately after its fabrication. Alternatively, the cell may be stored at a relatively low temperature to undergo preliminary self-discharge of at least 3 mAh per cm.sup.2 of the anode surface.
摘要翻译： 一种制备包含锂阳极和含碘阴极的固体电解质初级电池的方法。 在该过程中，电池在其制造之后立即进行至少2mAh / cm 2的锂阳极表面的初步电池放电。 或者，电池可以在相对低的温度下存储以进行至少3mAh / cm 2的阳极表面的预自动放电。
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公开(公告)号：US4315975A
公开(公告)日：1982-02-16
申请号：US175734
申请日：1980-08-06
申请人： Satoshi Sekido , Tadashi Sotomura , Muneaki Nakai
发明人： Satoshi Sekido , Tadashi Sotomura , Muneaki Nakai
IPC分类号： H01M6/18
CPC分类号： H01M6/182
摘要： A solid-state primary cell comprising a lithium anode, a cathode comprising iodine particles not more than 77 .mu.m in diameter and a charge transfer complex of iodine with an aromatic heterocyclic compound, and a lithium iodide based solid electrolyte. The cell has an anode current collector which can be coated with a polyimide film on part of its surface for giving improved discharge characteristics to the cell.
摘要翻译： 包含锂阳极，包含直径不大于77μm的碘颗粒和碘与芳族杂环化合物的电荷转移络合物的阴极和基于碘化锂的固体电解质的固态初级电池。 电池具有阳极集电器，其可以在其表面的一部分上涂覆聚酰亚胺膜，以使电池具有改善的放电特性。
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公开(公告)号：US4148976A
公开(公告)日：1979-04-10
申请号：US922049
申请日：1978-07-05
CPC分类号： H01M4/60 , H01M6/182 , Y10T29/49108
摘要： A solid-state primary cell comprising a lithium anode, an iodine cathode containing a charge transfer complex and a solid lithium iodide electrolyte doped with a 1-normal-alkyl-pyridinium iodide. The anode surface can be coated with LiOH or Li.sub.3 N. The iodine cathode comprises a complex of iodine and 1-normal-alkyl-pyridinium iodide and preferably contains titanium dioxide powder, alumina gel powder or silica gel powder admixed with the complex.
摘要翻译： 包含锂阳极，含有电荷转移络合物的碘阴极和掺杂有1-正烷基 - 碘化吡啶鎓的固体碘化锂电解质的固态初级电池。 阳极表面可以涂覆LiOH或Li3N。 碘阴极包含碘和1-正烷基 - 吡啶鎓碘化物的络合物，并且优选含有与络合物混合的二氧化钛粉末，氧化铝凝胶粉末或硅胶粉末。
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公开(公告)号：US4789610A
公开(公告)日：1988-12-06
申请号：US95146
申请日：1987-09-11
IPC分类号： H01M4/136 , H01M4/58 , H01M10/054 , H01M10/0562 , H01M6/18
CPC分类号： H01M10/0562 , H01M4/581
摘要： A solid-electrolyte secondary cell comprising a positive and a negative electrode composed of a copper chevrel compound (Cu.sub.x Mo.sub.6 S.sub.8), and copper ion conductive solid electrolyte is provided. This secondary cell is capable of charging with a current as high as about 1 mA/cm.sup.2, can stand high temperatures of up to 100.degree. C. and maintains its initial performance even after long-time charging and discharging. A cell small in voltage drop during dicharge is also provided by using a heat treated mixture of a copper chevrel compound and a copper ion conductive solid electrolyte represented by the formula K.sub.q Rb.sub.1-q Cu.sub.4 I.sub.2-p Cl.sub.3+3 (0.ltoreq.q.ltoreq.0.5, 0.25.ltoreq.p.ltoreq.1.0) for both positive and negative electrodes.
摘要翻译： 提供了由铜螯合物（CuxMo6S8）和铜离子导电性固体电解质构成的正极和负极的固体电解质二次电池。 该二次电池能够以高达约1mA / cm 2的电流充电，可以承受高达100℃的高温，并且即使在长时间充电和放电之后也保持其初始性能。 通过使用铜螯合物和由KqRb1-qCu4I2-pCl3 + 3（0≤q≤0.5）表示的铜离子导电固体电解质的热处理混合物，也提供了在二次加注期间电压降小的电池 ，0.25
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公开(公告)号：USRE31489E
公开(公告)日：1984-01-10
申请号：US301367
申请日：1981-09-11
CPC分类号： H01M4/60 , H01M6/182 , Y10T29/49108
摘要： A solid-state primary cell comprising a lithium anode, an iodine cathode containing a charge transfer complex and a solid lithium iodide electrolyte doped with a 1-normal-alkyl-pyridinium iodide. The anode surface can be coated with LiOH or Li.sub.3 N. The iodine cathode comprises a complex of iodine and 1-normal-alkyl-pyridinium iodide and preferably contains titanium dioxide powder, alumina gel powder or silica gel powder admixed with the complex.
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公开(公告)号：US4388385A
公开(公告)日：1983-06-14
申请号：US294017
申请日：1981-08-18
申请人： Satoshi Sekido , Tadashi Sotomura
发明人： Satoshi Sekido , Tadashi Sotomura
CPC分类号： H01M14/005 , H01G9/20
摘要： A photocell comprising a solid electrolyte film or layer and a pair of electrodes sandwiching therebetween the electrolyte film. The solid electrolyte is AgBr, AgI and silver halide-containing double salts and mixed salts. One of the electrodes is optically transparent and the other electrode is made of a material capable of forming a charge transfer complex with the halogen generated on photodissociation of the electrolyte.
摘要翻译： 一种光电池，包括固体电解质膜或层以及一对电极，夹在其间的电解质膜。 固体电解质是AgBr，AgI和含卤化银的双重盐和混合盐。 电极中的一个是光学透明的，另一个电极由能够与电解质的光解产生的卤素形成电荷转移络合物的材料制成。
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公开(公告)号：US07115338B2
公开(公告)日：2006-10-03
申请号：US11135283
申请日：2005-05-24
申请人： Tadashi Sotomura
发明人： Tadashi Sotomura
CPC分类号： H01M6/30 , H01M2/38 , H01M4/38 , H01M4/42 , H01M4/48 , H01M4/50 , H01M4/583 , H01M4/60 , H01M4/661 , H01M8/04082 , H01M8/04276 , H01M12/04 , H01M2004/027 , H01M2004/028 , Y02P70/56
摘要： A positive electrode, a negative electrode, and an electrolyte intervening between the positive electrode and the negative electrode are employed, and a molecule capable of being excited due to absorption of light and electrochemically oxidizing carbohydrate is provided at at least either the negative electrode or the electrolyte, with production of electromotive force occurring between the positive electrode and the negative electrode as a result of supply of carbohydrate while the molecule is irradiated with light and oxidization of carbohydrate by the molecule at the negative electrode. This method makes it possible for the chemical energy which carbohydrates possess to be directly utilized as electrical energy.
摘要翻译： 采用在正极和负极之间插入的正极，负极和电解质，能够在负极或负极的至少一方具有由于吸收光而被激发而进行电化学氧化的碳分子 电解质，由于供给碳水化合物而在正极和负极之间产生电动势，而分子被光照射并且在负极处被分子氧化碳水化合物。 这种方法使碳水化合物所具有的化学能直接用作电能。
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公开(公告)号：US06596431B1
公开(公告)日：2003-07-22
申请号：US09759317
申请日：2001-01-16
申请人： Tadashi Sotomura , Isao Taniguchi
发明人： Tadashi Sotomura , Isao Taniguchi
IPC分类号： H01M460
摘要： For utilizing the chemical energy of a sugar directly as electric energy, electrolytic oxidation of a sugar on the negative electrode associated with cleavage of a carbon-carbon bond thereof is employed, thereby generating an electromotive force between the positive electrode and the negative electrode having an electrolyte therebetween. For an efficient oxidation of a sugar, it is effective for the negative electrode to have a component capable of forming a coordination compound with a sugar via a hydroxyl group thereof. Such a component may comprise a metal element capable of forming an amphoteric hydroxide. Use of an oxygen electrode as the positive electrode gives a battery capable of efficiently converting the chemical energy of a sugar into electric energy.
摘要翻译： 为了将糖的化学能直接用作电能，使用与其碳 - 碳键相切的负极上的糖的电解氧化，从而在具有碳 - 碳键的正极和负极之间产生电动势，具有 电解液。 为了有效地氧化糖，对于负极具有能够通过其羟基与糖形成配位化合物的成分是有效的。 这种组分可以包含能够形成两性氢氧化物的金属元素。 使用氧电极作为正极，能够提供能够将糖的化学能有效地转化为电能的电池。
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9.发明授权Composite electrode, method of producing the same, and lithium secondary battery using the same 有权复合电极及其制造方法以及使用该电极的锂二次电池公开(公告)号：US06245458B1
公开(公告)日：2001-06-12
申请号：US09211779
申请日：1998-12-15
申请人： Tadashi Sotomura
发明人： Tadashi Sotomura
IPC分类号： H01M460
摘要： To provide a composite electrode, which does not lose large capacity and high energy density of sulfur and proceeds oxidation-reduction reaction rapidly even at room temperature. There is disclosed in the specification that a composite electrode comprising a composition containing an organic sulfide compound having at least a thiol or thiolate group in the molecule, polyaniline, and sulfur.
摘要翻译： 为了提供即使在室温下也不会失去大容量和高能量密度的硫并迅速进行氧化还原反应的复合电极。 在说明书中公开了一种复合电极，其包含含有分子中至少具有硫醇或硫醇基的有机硫化物的组合物，聚苯胺和硫。
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10.发明授权Electrode including organic disulfide compound and method of producing the same 失效含有有机二硫化物的电极及其制造方法
公开(公告)号：US5869206A
公开(公告)日：1999-02-09
申请号：US820210
申请日：1997-03-18
申请人： Tadashi Sotomura
发明人： Tadashi Sotomura
IPC分类号： G01N27/333 , G02F1/155 , H01M4/13 , H01M4/137 , H01M4/139 , H01M4/1399 , H01M4/36 , H01M4/60
CPC分类号： H01M4/137 , H01M4/02 , G02F2001/1555 , H01M4/60
摘要： An electrode of the present invention comprises a complex of at least one organic disulfide compound and at least one copper ion. The electrode maintains a high charging and discharging efficiency and has favorable charge and discharge cycle characteristic without losing a high energy density that is characteristic of the organic disulfide compound.
摘要翻译： 本发明的电极包含至少一种有机二硫化物和至少一种铜离子的络合物。 该电极保持高的充放电效率并且具有良好的充放电循环特性，而不会失去有机二硫化物化合物特征的高能量密度。
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