摘要:
The present invention relates to an arylphenoxy catalyst system producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group IV arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group IV transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes an environmentally-friendly raw material, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.
摘要:
Disclosed is an arylphenoxy catalyst system for producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group 4 arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group 4 transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes non-toxic raw materials, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.
摘要:
Disclosed is an arylphenoxy catalyst system for producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group 4 arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadienyl derivative and arylphenoxide as fixed ligands are located around the group 4 transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes non-toxic raw materials, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.
摘要:
The present invention relates to a transition metal complex useful as a transition metal catalyst in the preparation of an ethylene homopolymer or a copolymer of ethylene and an α-olefin, a catalyst composition comprising the same and a process of preparing an ethylene homopolymer or a copolymer of ethylene and an α-olefin using the same. More particularly, it relates to a transition metal complex having a cyclopentadiene derivative and at least one phenyl oxide ligand substituted at the 2-position of phenyl with, for example, a silyl group having a C1-C30 hydrocarbon group or a C1-C20 hydrocarbon group, around a group IV transition metal, with no crosslinkage between the ligands, a catalyst composition comprising the transition metal complex and a cocatalyst selected from the group consisting of an aluminoxane and a boron compound, and a process for preparing an ethylene homopolymer or a copolymer of ethylene and an α-olefin using the same.
摘要:
The present invention relates to a transition metal complex useful as a transition metal catalyst in the preparation of an ethylene homopolymer or a copolymer of ethylene and an α-olefin, a catalyst composition comprising the same and a process of preparing an ethylene homopolymer or a copolymer of ethylene and an α-olefin using the same. More particularly, it relates to a transition metal complex having a cyclopentadiene derivative and at least one phenyl oxide ligand substituted at the 2-position of phenyl with, for example, a silyl group having a C1-C30 hydrocarbon group or a C1-C20 hydrocarbon group, around a group IV transition metal, with no crosslinkage between the ligands, a catalyst composition comprising the transition metal complex and a cocatalyst selected from the group consisting of an aluminoxane and a boron compound, and a process for preparing an ethylene homopolymer or a copolymer of ethylene and an α-olefin using the same.
摘要:
An organic light emitting diode (OLED) display includes a substrate main body, a plurality of organic light emitting elements on the substrate main body, a column spacer on the substrate main body and between two or more of the plurality of organic light emitting elements, and an encapsulation thin film covering at least one of the organic light emitting elements and having regions divided by the column spacer.
摘要:
A method and system for encrypting data in a wireless communication system are provided. The system includes a first node for generating a first encryption key using a plurality of encryption key parameters when performing authentication with a second node, for changing a second parameter among the plurality of encryption key parameters to generate a second encryption key being identical to the first encryption key, if a first parameter among the plurality of encryption key parameters is changed during re-authentication between the first node and the second node, for generating the second encryption key using the changed first parameter and the changed second parameter, and for encrypting data to be transmitted to the second node using the second encryption key.
摘要:
A flat panel display (FPD) with a reduced time required to change images between frames by improving waveforms of a selection signal and a drive signal. The FPD includes an electrode, an electrophoretic device with charged particles arranged in response to a data signal, and a transistor device controlling transmission of the data signal. An image frame includes a drive section in which the data signal is transmitted to the electrophoretic device to arrange the charged particles and display a grayscale image, and the data signal has a first pulse with a first voltage magnitude and a second pulse with a second voltage magnitude. The frame also includes a shake section for removing an image generated in a previous frame, and the selection signal transmitted to the transistor device during the shake section has a constant predetermined voltage and switches the transistor device on.
摘要:
A pixel circuit may include a pixel unit coupled to a crossing point of a data-line and a scan-line, the pixel unit receiving a first power source voltage and a second power source voltage that are DC power source voltages, an organic light emitting diode coupled to the pixel unit, and a light emitting control transistor coupled between the pixel unit and the organic light emitting diode. Here, the light emitting control transistor may periodically turn on and off in response to a light emitting control signal having a logic high level and a logic low level in a frame, and the light emitting control signal may be simultaneously provided to a plurality of light emitting control transistors in a display panel.
摘要:
An organic light emitting display which minimizes the IR drop of voltages supplied to an organic light emitting display panel includes an organic light emitting display panel having a pixel unit on which an image is displayed and first and second power source pads provided at two or more edges outside the pixel unit to receive first and second voltages from at least two directions, and a voltage supplier Flexible Printed Circuit Board (FPCB) including pads electrically coupled to the first and second power source pads and arranged on the outer circumference of the organic light emitting display so as not to overlap with the pixel unit.