公开(公告)号：US07192535B2

公开(公告)日：2007-03-20

申请号：US10798410

申请日：2004-03-12

申请人： Takako Takasu ,  Hiroko Yamazaki ,  Satoshi Seo ,  Ryoji Nomura ,  Hideko Inoue

发明人： Takako Takasu ,  Hiroko Yamazaki ,  Satoshi Seo ,  Ryoji Nomura ,  Hideko Inoue

IPC分类号： C09K11/54 ,  H01J1/62 ,  B32B9/00 ,  C07D409/00

CPC分类号： H05B33/14 ,  C07D333/32 ,  C09K11/06 ,  C09K2211/1088 ,  C09K2211/1092 ,  Y10S428/917

摘要： It is intended to provide a novel material having no absorption or low absorption intensity in the visible region and to provide an electroluminescent device excellent in hole injection characteristic by using the novel material. A novel organic material wherein two electron abundant aromatic rings inherently having a low ionization potential, such as a thiophene ring, a furan ring, and pyrrol ring, is intervened by a conjugated substituent such as a phenylene ring is provided. The electroluminescent device having an excellent hole injection characteristic is provided by using this novel organic material.

摘要翻译： 旨在提供在可见光区域中没有吸收或低吸收强度的新型材料，并且通过使用该新型材料提供具有优异的空穴注入特性的电致发光器件。 提供了一种其中固有地具有低电离电位的两个电子丰富的芳族环的新型有机材料，例如噻吩环，呋喃环和吡咯环，通过共轭取代基如亚苯基环进行介导。 通过使用这种新颖的有机材料提供具有优异的空穴注入特性的电致发光器件。

公开(公告)号：US07476451B2

公开(公告)日：2009-01-13

申请号：US10715106

申请日：2003-11-17

申请人： Harue Nakashima ,  Satoshi Seo ,  Takako Takasu ,  Hiroko Yamazaki

发明人： Harue Nakashima ,  Satoshi Seo ,  Takako Takasu ,  Hiroko Yamazaki

IPC分类号： H01L51/50

CPC分类号： H01L51/0077 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1022 ,  C09K2211/1029 ,  C09K2211/183 ,  H01L51/0089 ,  H01L51/5012 ,  H05B33/14 ,  Y10S428/917

摘要： There is provided an electroluminescent element using a material that is excellent in film forming properties and carrier transporting properties, emits a light in the solid state, and can be suitably used also as a host material. The electroluminescent element has an electroluminescence layer between a couple of electrodes, and a complex of a Group 4 metal of the periodic table, which is excellent in the film forming properties and the carrier transporting properties and capable of emitting a light in the solid state, is used in a part of the electroluminescence layer to form the electroluminescent element. The complex of a Group 4 metal of the periodic table has an emission wavelength on a longer wavelength side as compared with conventional host materials such as Alq3, and thereby may be combined with a red light emitting guest material to form a light emitting layer.

摘要翻译： 提供了使用成膜性和载流子传输性优异的材料的电致发光元件，发出固态的光，并且也可以适当地用作主体材料。 电致发光元件在一对电极之间具有电致发光层，并且具有优异的成膜性能和载流子传输性能并能够发出固态光的元素周期表第4族金属的络合物， 用于电致发光层的一部分以形成电致发光元件。 元素周期表的第4族金属的复合物与常规的主体材料如Alq 3相比具有较长波长侧的发射波长，从而可以与红色发光客体材料组合以形成发光层。

公开(公告)号：US08941096B2

公开(公告)日：2015-01-27

申请号：US13150598

申请日：2011-06-01

申请人： Tetsuo Tsutsui ,  Hiroko Yamazaki ,  Satoshi Seo

发明人： Tetsuo Tsutsui ,  Hiroko Yamazaki ,  Satoshi Seo

IPC分类号： H01L51/00 ,  H01L51/50 ,  B82Y10/00 ,  H01L27/30 ,  H01L51/42 ,  H01L51/52 ,  H01L27/32 ,  H01L51/05

CPC分类号： H01L51/504 ,  B82Y10/00 ,  H01L27/302 ,  H01L27/3209 ,  H01L51/005 ,  H01L51/0051 ,  H01L51/0052 ,  H01L51/0053 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0077 ,  H01L51/0078 ,  H01L51/0081 ,  H01L51/0595 ,  H01L51/424 ,  H01L51/4246 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5036 ,  H01L51/5052 ,  H01L51/506 ,  H01L51/5076 ,  H01L51/5278 ,  Y02E10/50 ,  Y02E10/549 ,  Y02P70/521

摘要： By introducing new concepts into a structure of a conventional organic semiconductor element and without using a conventional ultra thin film, an organic semiconductor element is provided which is more reliable and has higher yield. Further, efficiency is improved particularly in a photoelectronic device using an organic semiconductor. Between an anode and a cathode, there is provided an organic structure including alternately laminated organic thin film layer (functional organic thin film layer) realizing various functions by making an SCLC flow, and a conductive thin film layer (ohmic conductive thin film layer) imbued with a dark conductivity by doping it with an acceptor and a donor, or by the like method.

公开(公告)号：US07737630B2

公开(公告)日：2010-06-15

申请号：US11416331

申请日：2006-05-02

申请人： Satoshi Seo ,  Hiroko Yamazaki

发明人： Satoshi Seo ,  Hiroko Yamazaki

IPC分类号： H01J1/62

CPC分类号： H01L51/5096 ,  H01L27/3244 ,  H01L51/0059 ,  H01L51/0078 ,  H01L51/0081 ,  H01L51/5203 ,  H01L2251/5315 ,  H01L2251/558

摘要： An EL element which is thicker and lower-voltage drive without doping acceptor or donor than the conventional one. An EL element in which an electroluminescent film 103 containing an organic compound which can provide electroluminescent, a floating electrode 104, an electron transport supporting layer 105 and a cathode 102 are in order laminated on an anode 101. A film thickness of the electroluminescent film 103 is on the order of a conventional film thickness (on the order of approximately 100 nm), and the electron transport supporting layer 105 may also have a film thickness on the order of the electroluminescent film 103. The EL element can be driven at lower voltage than the conventional one by introducing a hole blocking material into an electron transport supporting layer.

摘要翻译： 与常规的EL元件相比，没有掺杂受体或者掺杂剂的较低和较低电压驱动的EL元件。 其中包含可提供电致发光的有机化合物的电致发光膜103，浮置电极104，电子传输支持层105和阴极102的EL元件依次层压在阳极101上。电致发光膜103的膜厚度 是常规膜厚度（约100nm量级）的顺序，并且电子传输支持层105也可以具有电致发光膜103的数量级的膜厚度。可以以更低的电压驱动EL元件 通过将空穴阻挡材料引入到电子传输支撑层中。

公开(公告)号：US07504771B2

公开(公告)日：2009-03-17

申请号：US11319216

申请日：2005-12-28

申请人： Hiroko Yamazaki ,  Satoshi Seo

发明人： Hiroko Yamazaki ,  Satoshi Seo

IPC分类号： H01J1/62

CPC分类号： H01L51/5044 ,  H01L27/3206 ,  H01L27/3244 ,  H01L33/502 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5028 ,  H01L51/5036 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5088 ,  H01L51/5092 ,  H01L51/5096 ,  H01L51/5206 ,  H01L51/5221 ,  H01L51/5234 ,  H01L51/56

摘要： The present invention provides a white organic light-emitting element high in the emission efficiency. In particular, the invention provides a white organic light-emitting element that has an emission spectrum having peaks in the respective wavelength regions of red color, green color and blue color and is high in the emission efficiency.Since a spectrum region lowest in the emission efficiency is a red region, by introducing a reddish phosphorescent material, a highly efficient white organic light-emitting element is obtained. At this time, in order to inhibit the reddish phosphorescent material from singularly emitting, as shown in FIG. 1, a distance between a second emission region 114 where a reddish phosphorescent material 124 is a luminescent material and a first emission region 113 that exhibits emission in a shorter wavelength side than the second emission region is separated. In a configuration shown in FIG. 1, it is preferable to use an electron transport material in a layer 115 between the first emission region and the second emission region and more preferable to use a hole block material.

摘要翻译： 本发明提供了一种发光效率高的白色有机发光元件。 特别地，本发明提供一种白色有机发光元件，其具有在红色，绿色和蓝色的各个波长区域具有峰值的发射光谱，并且发光效率高。 由于发射效率最低的光谱区域是红色区域，所以通过引入红色磷光材料，获得高效率的白色有机发光元件。 此时，为了抑制红色磷光发光材料的发光，如图1所示。 如图1所示，分离出红色磷光材料124为发光材料的第二发光区域114与第二发光区域的短波长侧发光的第一发光区域113之间的距离。 在图1所示的结构中， 如图1所示，优选在第一发光区域和第二发光区域之间的层115中使用电子传输材料，更优选使用空穴阻挡材料。

公开(公告)号：US07355340B2

公开(公告)日：2008-04-08

申请号：US10706291

申请日：2003-11-13

申请人： Satoko Shitagaki ,  Hiroko Yamazaki ,  Satoshi Seo

发明人： Satoko Shitagaki ,  Hiroko Yamazaki ,  Satoshi Seo

IPC分类号： H01L51/54 ,  C09K11/06

CPC分类号： H01L51/0072 ,  C07D405/14 ,  C09K11/06 ,  C09K2211/1011 ,  C09K2211/1044 ,  C09K2211/1088 ,  H01L51/0055 ,  H01L51/0058 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0081 ,  H01L51/5012 ,  H01L51/5048 ,  H01L2251/308 ,  H05B33/14 ,  Y10S428/917

摘要： The present invention is to provide quinoxaline derivatives, which have excellent electron transportation and hole blocking properties, and which can be formed into a film without being crystallized. According to the invention, quinoxaline derivatives represented by the general [formula 1] are synthesized. (wherein X and Y represent a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group, and R1 to R6 represent individually hydrogen, an alkyl group, an alkoxyl group, a substituted or unsubstituted aryl group, and a substituted or unsubstituted heterocyclic group. Further, an organic semiconductor device including an electroluminescent device containing the foregoing quinoxaline derivatives is formed.)

摘要翻译： 本发明提供具有优异的电子传输和空穴阻挡性能的喹喔啉衍生物，并且可以形成为不结晶的膜。 根据本发明，合成由通式[1]表示的喹喔啉衍生物。 （其中X和Y表示取代或未取代的芳基或取代或未取代的杂环基，R 1〜R 6分别表示氢，烷基，烷氧基，取代或未取代的芳基，取代或未取代的杂环 此外，形成包含含有上述喹喔啉衍生物的电致发光元件的有机半导体器件。）

公开(公告)号：US20060192484A1

公开(公告)日：2006-08-31

申请号：US11416331

申请日：2006-05-02

申请人： Satoshi Seo ,  Hiroko Yamazaki

发明人： Satoshi Seo ,  Hiroko Yamazaki

IPC分类号： H01J1/62 ,  H01J63/04

CPC分类号： H01L51/5096 ,  H01L27/3244 ,  H01L51/0059 ,  H01L51/0078 ,  H01L51/0081 ,  H01L51/5203 ,  H01L2251/5315 ,  H01L2251/558

摘要： An EL element which is thicker and lower-voltage drive without doping acceptor or donor than the conventional one. An EL element in which an electroluminescent film 103 containing an organic compound which can provide electroluminescent, a floating electrode 104, an electron transport supporting layer 105 and a cathode 102 are in order laminated on an anode 101. A film thickness of the electroluminescent film 103 is on the order of a conventional film thickness (on the order of approximately 100 nm), and the electron transport supporting layer 105 may also have a film thickness on the order of the electroluminescent film 103. The EL element can be driven at lower voltage than the conventional one by introducing a hole blocking material into an electron transport supporting layer.

公开(公告)号：US20060164006A1

公开(公告)日：2006-07-27

申请号：US11319216

申请日：2005-12-28

申请人： Hiroko Yamazaki ,  Satoshi Seo

发明人： Hiroko Yamazaki ,  Satoshi Seo

IPC分类号： H01J1/62

CPC分类号： H01L51/5044 ,  H01L27/3206 ,  H01L27/3244 ,  H01L33/502 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5028 ,  H01L51/5036 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5088 ,  H01L51/5092 ,  H01L51/5096 ,  H01L51/5206 ,  H01L51/5221 ,  H01L51/5234 ,  H01L51/56

摘要： The present invention provides a white organic light-emitting element high in the emission efficiency. In particular, the invention provides a white organic light-emitting element that has an emission spectrum having peaks in the respective wavelength regions of red color, green color and blue color and is high in the emission efficiency. Since a spectrum region lowest in the emission efficiency is a red region, by introducing a reddish phosphorescent material, a highly efficient white organic light-emitting element is obtained. At this time, in order to inhibit the reddish phosphorescent material from singularly emitting, as shown in FIG. 1, a distance between a second emission region 114 where a reddish phosphorescent material 124 is a luminescent material and a first emission region 113 that exhibits emission in a shorter wavelength side than the second emission region is separated. In a configuration shown in FIG. 1, it is preferable to use an electron transport material in a layer 115 between the first emission region and the second emission region and more preferable to use a hole block material.

摘要翻译： 本发明提供了一种发光效率高的白色有机发光元件。 特别地，本发明提供一种白色有机发光元件，其具有在红色，绿色和蓝色的各个波长区域具有峰值的发射光谱，并且发光效率高。 由于发射效率最低的光谱区域是红色区域，所以通过引入红色磷光材料，获得高效率的白色有机发光元件。 此时，为了抑制红色磷光发光材料的发光，如图1所示。 如图1所示，分离出红色磷光材料124为发光材料的第二发光区域114与第二发光区域的短波长侧发光的第一发光区域113之间的距离。 在图1所示的结构中， 如图1所示，优选在第一发光区域和第二发光区域之间的层115中使用电子传输材料，更优选使用空穴阻挡材料。

公开(公告)号：US06995509B2

公开(公告)日：2006-02-07

申请号：US10744600

申请日：2003-12-24

申请人： Hiroko Yamazaki ,  Satoshi Seo

发明人： Hiroko Yamazaki ,  Satoshi Seo

IPC分类号： H01J1/63

CPC分类号： H01L51/5044 ,  H01L27/3206 ,  H01L27/3244 ,  H01L33/502 ,  H01L51/0058 ,  H01L51/006 ,  H01L51/0081 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5028 ,  H01L51/5036 ,  H01L51/5056 ,  H01L51/5072 ,  H01L51/5088 ,  H01L51/5092 ,  H01L51/5096 ,  H01L51/5206 ,  H01L51/5221 ,  H01L51/5234 ,  H01L51/56

摘要： The present invention provides a white organic light-emitting element high in the emission efficiency. In particular, the invention provides a white organic light-emitting element that has an emission spectrum having peaks in the respective wavelength regions of red color, green color and blue color and is high in the emission efficiency.Since a spectrum region lowest in the emission efficiency is a red region, by introducing a reddish phosphorescent material, a highly efficient white organic light-emitting element is obtained. At this time, in order to inhibit the reddish phosphorescent material from singularly emitting, as shown in FIG. 1, a distance between a second emission region 114 where a reddish phosphorescent material 124 is a luminescent material and a first emission region 113 that exhibits emission in a shorter wavelength side than the second emission region is separated. In a configuration shown in FIG. 1, it is preferable to use an electron transport material in a layer 115 between the first emission region and the second emission region and more preferable to use a hole block material.

摘要翻译： 本发明提供了一种发光效率高的白色有机发光元件。 特别地，本发明提供一种白色有机发光元件，其具有在红色，绿色和蓝色的各个波长区域具有峰值的发射光谱，并且发光效率高。

公开(公告)号：US06838836B2

公开(公告)日：2005-01-04

申请号：US10456609

申请日：2003-06-09

申请人： Satoshi Seo ,  Hiroko Yamazaki

发明人： Satoshi Seo ,  Hiroko Yamazaki

IPC分类号： H05B33/26 ,  H01L51/00 ,  H01L51/50 ,  G09G3/10 ,  H01J1/62

CPC分类号： H01L51/5092 ,  H01L51/0035 ,  H01L51/0051 ,  H01L51/0059 ,  H01L51/0078 ,  H01L51/0081 ,  H01L51/5088 ,  H01L2251/5315

摘要： To provide a light emitting element having a top emission structure, which can be easily manufactured without considering an ionization potential of an electrode (particularly an electrode in contact with a substrate) and a manufacturing method therefor. A light emitting device having the top emission structure according to the present invention includes: a first electrode (101) formed of general-purpose metal (specifically, a wiring material such as Ti or Al) having a light-shielding property or reflectivity; a conductive polymer layer (102) formed by applying a conductive polymer material onto the first electrode (101); an electroluminescence film (103) formed in contact with the conductive polymer layer (102); and a light-transmissive second electrode (104) formed on the electroluminescence film 103, in which the conductive polymer layer (102) is formed of materials including a redox polymer etc., while being free of problems regarding work function (as shown in FIG. 1A).

摘要翻译： 提供一种具有顶部发射结构的发光元件及其制造方法，其可以容易地制造而不考虑电极（特别是与基板接触的电极）的电离电位。 根据本发明的具有顶部发射结构的发光器件包括：由具有遮光性或反射率的通用金属（具体地，诸如Ti或Al的布线材料）形成的第一电极（101） 通过将导电聚合物材料施加到所述第一电极（101）上形成的导电聚合物层（102）; 形成为与导电聚合物层（102）接触的电致发光膜（103）; 以及形成在电致发光膜103上的透光性第二电极（104），其中导电性聚合物层（102）由包含氧化还原性聚合物等的材料形成，同时没有关于功函数的问题（如图 1A）。