摘要:
Provided is a polymer comprising a repeating unit represented by formula (1), wherein, A1 represents a divalent group in which the bond distance ratio (bond distance of C(α)-A1/bond distance of C(α)-C(β)) is 1.10 or more; R1, R2, R3, R4, R5, and R6, each independently represent a hydrogen atom, alkyl group, alkyloxy group, aryloxy group, arylalkyloxy group, etc. The polymer is useful as a light-emitting material, a charge transporting material, etc.
摘要:
Provided is a polymer comprising a repeating unit represented by formula (1), wherein, A1 represents a divalent group in which the bond distance ratio (bond distance of C(α)-A1/bond distance of C(α)-C(β)) is 1.10 or more; R1, R2, R3, R4, R5, and R6, each independently represent a hydrogen atom, alkyl group, alkyloxy group, aryloxy group, arylalkyloxy group, etc. The polymer is useful as a light-emitting material, a charge transporting material, etc.
摘要:
A polymeric fluorescent substance exhibiting fluorescence in the solid state, having a polystyrene reduced number-average molecular weight of 1×103 to 1×108, and comprising one or more repeating units of formula (1) and one or more repeating units of formula (8), —Ar1—(CR1═CR2)n— (1) —Ar2—(CR36═CR37)n— (8) wherein Ar1 represents a specific arylene or a divalent heterocyclic compound group, and Ar2 represent an arylene or a divalent heterocyclic compound group other than Ar1. By using the polymeric fluorescent substance, a high performance polymer LED can easily be obtained.
摘要:
Provided is a polymeric fluorescent substance comprising a copolymer which has a substituent containing a specific aromatic amine structure below in the side chain, wherein X1 is a divalent hydrocarbon group; Ar2 is an arylene group or the like; Ar3 and Ar4 independently represent an aryl group or the like. The polymeric fluorescent substance is preferably used for a light emitting layer of a polymer LED having high luminance and high light emitting efficiency.
摘要翻译:本发明提供一种聚合物荧光物质,其包含在侧链中具有下述特定芳香胺结构的取代基的共聚物,其中X 1为二价烃基; Ar 2是亚芳基等; Ar 3和Ar 4独立地表示芳基等。 聚合物荧光物质优选用于具有高亮度和高发光效率的聚合物LED的发光层。
摘要:
A block copolymer comprising two or more blocks and having fluorescence in the solid state, wherein blocks thereof may be the same or different, and in each of the blocks, one or more kinds of repeating units are bonded through conjugated bonds, and bonding between the blocks is made by junction unit having conjugated bond, and the polystyrene reduced number average molecular weight of at least one block is 1×103 to 1×108.
摘要:
Provided is a polymer comprising a repeating unit represented by formula (1), wherein, A1 represents a divalent group in which the bond distance ratio (bond distance of C(α)-A1/bond distance of C(α)-C(β)) is 1.10 or more; R1, R2, R3, R4, R5, and R6, each independently represent a hydrogen atom, alkyl group, alkyloxy group, aryloxy group, arylalkyloxy group, etc. The polymer is useful as a light-emitting material, a charge transporting material, etc.
摘要翻译:本发明提供包含由式(1)表示的重复单元的聚合物,其中,A 1表示二价基团,其中键距距离(C(α)-A 1 C(α)-C(β)的 SUP> /键距离)为1.10以上; R 1,R 2,R 3,R 4,R 5, R 6和R 6各自独立地表示氢原子,烷基,烷氧基,芳氧基,芳烷氧基等。该聚合物可用作发光材料,电荷输送材料等。
摘要:
A method for producing a polymeric fluorescent substance characterized by comprising the step of contacting with an alkali a crude polymeric fluorescent substance that is fluorescent in a solid state and has a polystyrene equivalent number average molecular weight of 104 to 108 and one or more repeating units represented by the following formula (1): —Ar1—(CR1═CR2)n— (1) wherein Ar1 is an arylene group or heterocyclic compound group that is unsubstituted or substituted by one or more substituents; R1 and R2 each independently represent a group selected from the group consisting of a hydrogen atom, an alkyl group, an aryl group, a heterocyclic compound group and a cyano group, in which the aryl group and the heterocyclic compound group is optionally substituted by another substituent; and n is 0 or 1.
摘要翻译:一种生产聚合物荧光物质的方法,其特征在于包括以下步骤:与固体状态下荧光的聚合物聚合物荧光物质与碱接触,其聚苯乙烯换算的数均分子量为10 4〜 10&gt;和一个或多个由下式(1)表示的重复单元:<?in-line-formula description =“In-line formula”end =“lead”?> - Ar
摘要:
High-molecular compounds comprising repeating units represented by the general formula (1) or (2) and having number-average molecular weights of 103 to 108 in terms of polystyrene: (1) [wherein Ar1 and Ar2 are each independently a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group; and X1 and X2 are each independently O, S, C(═O), S(═O), SO2, C(R1)(R2), Si(R3)(R4), N(R5), B(R6), P(R7), or P(═O)(R8), with the provisos that X1 and X2 must not be the same and that X1 and Ar2 are bonded respectively to the adjacent carbon atoms constituting the aromatic ring of Ar1, and X2 and Ar1 are bonded respectively to the adjacent carbon atoms constituting the aromatic ring of Ar2] (2) [wherein Ar3 and Ar4 are each independently a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group; and X3 and X4 are each independently N, B, P, C(R9), or Si(R10), with the provisos that X3 and X4 must not be the same and that X3 and Ar4 are bonded respectively to the adjacent carbon atoms constituting the aromatic ring of Ar3, and X4 and Ar3 are bonded respectively to the adjacent carbon atoms constituting the aromatic ring of Ar4].
摘要:
A copolymer has a polystyrene reduced number average molecular weight of 103-108, and includes repeating units represented by formulas (1), (2), and (3), —Ar1— (3) The copolymer has an excellent solubility in an organic solvent, and a high glass transition temperature in good valance. Further, a polymer LED has high performance, such as low-voltage driving and high luminance.
摘要:
Provided is a polymeric fluorescent substance which emits a fluorescence in a solid state, which comprises the following repeating unit in an amount of 20 mol % or more based on the total amount of all repeating units, in the formula, X1 represents a group selected from the group consisting of —CR3═CR4—, —C≡C—, —SiR5R6—, —NR7—, —CO—, —CO—O—, —O—CO—, —SO2—, a carbon-carbon single bond, —O— and —S—. The polymeric fluorescent substance has strong fluorescence, and can be suitably used as a polymer LED and a dye for laser.