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42 条记录 (耗时 0.023 秒)

    Mixtures of water-soluble red and yellow or blue reactive dyes and a method of dyeing cellulosic fibers using such dye mixtures
    1.
    发明授权
    Mixtures of water-soluble red and yellow or blue reactive dyes and a method of dyeing cellulosic fibers using such dye mixtures 失效
    水溶性红色和黄色或蓝色活性染料的混合物和使用这种染料混合物染色纤维素纤维的方法

    公开(公告)号：US4872881A

    公开(公告)日：1989-10-10

    申请号：US269146

    申请日：1988-10-31

    申请人： Takashi Fujita ,  Toshio Hihara ,  Yoshio Kogure ,  Riyouichi Sekioka ,  Noboru Nakamura

    发明人： Takashi Fujita ,  Toshio Hihara ,  Yoshio Kogure ,  Riyouichi Sekioka ,  Noboru Nakamura

    IPC分类号： C09B67/22

    CPC分类号： C09B67/0041 ,  C09B67/0042 ,  Y10S8/918

    摘要： A dye mixture and a method of dyeing cellulosic fibers by use of the dye mixture, the dye mixture being capable of dyeing the cellulosic fibers favorably even in the presence of a small amount of an inorganic salt at dyeing, and being composed of a blend of a red water-soluble reactive dye to be represented by the following general formula (I) in the form of free acid, and a specific yellow and/or blue water-soluble reactive dye: ##STR1## (where: each of R.sup.1 and R.sup.2 denotes a hydrogen atom or a lower alkyl group which may contain therein a substituent; R.sup.3 represents a hydrogen atom, a lower alkyl group or a halogen atom and X designates --CH.dbd.CH.sub.2 or --C.sub.2 H.sub.4 OSO.sub.3 H).

    摘要翻译： PCT No.PCT / JP88 / 00226 Sec。 371日期1988年10月31日第 102（e）日期1988年10月31日PCT提交1988年3月1日PCT公布。 出版物WO89 / 00184 日本1989年1月12日。染料混合物和通过使用染料混合物染色纤维素纤维的方法，即使在染色时少量的无机盐的存在下，染料混合物也能有利地染色纤维素纤维， 并且由游离酸形式的由以下通式（I）表示的红色水溶性活性染料和特定的黄色和/或蓝色水溶性活性染料的混合物组成：（ I）（其中：R 1和R 2各自表示氢原子或可含有取代基的低级烷基; R 3表示氢原子，低级烷基或卤素原子，X表示-CH = CH 2 或-C 2 H 4 OSO 3 H）。

    Water-soluble blue dye mixture and dyeing method: anthraquinone reactive dye and formazan reactive dye
    2.
    发明授权
    Water-soluble blue dye mixture and dyeing method: anthraquinone reactive dye and formazan reactive dye 失效
    水溶性蓝色染料混合物和染色方法：蒽醌活性染料和甲an活性染料

    公开(公告)号：US4888028A

    公开(公告)日：1989-12-19

    申请号：US206727

    申请日：1988-06-15

    申请人： Toshio Hihara ,  Riyouichi Sekioka

    发明人： Toshio Hihara ,  Riyouichi Sekioka

    IPC分类号： C09B67/22

    CPC分类号： C09B67/004 ,  Y10S8/917 ,  Y10S8/918 ,  Y10S8/924

    摘要： A water-soluble dye mixture comprising a blue anthraquinone reactive dye represented in its free acid form by the formula: ##STR1## wherein X is --CH.dbd.CH.sub.2 or --C.sub.2 H.sub.4 W wherein W is a group removable by action of alkali and from 0.2 to 5 times by weight to said anthraquinone reactive dye of a blue formazan reactive dye represented in its free acid form by the formula: ##STR2## wherein R is a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, Y is a halogen atom, --NHC.sub.2 H.sub.4 SO.sub.3 H or ##STR3## and X is --CH.dbd.CH.sub.2 or --C.sub.2 H.sub.4 W wherein W is a group removable by action of alkali.

    Blue disperse dye mixture
    4.
    发明授权
    Blue disperse dye mixture 失效
    蓝色分散染料混合物

    公开(公告)号：US5595575A

    公开(公告)日：1997-01-21

    申请号：US555171

    申请日：1995-11-08

    申请人： Kiyoshi Himeno ,  Toshio Hihara ,  Ryouichi Sekioka

    发明人： Kiyoshi Himeno ,  Toshio Hihara ,  Ryouichi Sekioka

    IPC分类号： C09B67/22 ,  D06P3/54

    CPC分类号： C09B67/0051 ,  C09B67/0046 ,  Y10S8/922

    摘要： A blue disperse dye mixture comprising a monoazo dye of the following formula (1) and at least one azo dye selected from the group consisting of dyes of the following formulas (2), (3), (4) and (5): ##STR1## wherein each of the variables is defined in the specification.

    摘要翻译： 包含下式（1）的单偶氮染料和至少一种选自下式（2），（3），（4）和（5）的染料的偶氮染料的蓝色分散染料混合物：GE （4）（5）其中每个变量在说明书中定义。

    Water-soluble monoazodye containing a triazinyl or pyrimidinyl group and at least one vinyl sulfonyl type group in its structure
    5.
    发明授权
    Water-soluble monoazodye containing a triazinyl or pyrimidinyl group and at least one vinyl sulfonyl type group in its structure 失效
    其结构中含有三嗪基或嘧啶基和至少一个乙烯基磺酰基类的水溶性一抗体

    公开(公告)号：US5380827A

    公开(公告)日：1995-01-10

    申请号：US49410

    申请日：1993-04-20

    申请人： Yousuke Takahashi ,  Yukiharu Shimizu ,  Toshio Hihara ,  Kiyoshi Himeno

    发明人： Yousuke Takahashi ,  Yukiharu Shimizu ,  Toshio Hihara ,  Kiyoshi Himeno

    IPC分类号： C09B62/51 ,  C09B62/44 ,  C09B62/028 ,  C09B62/085 ,  C09B62/245

    CPC分类号： C09B62/4413 ,  C09B62/4424 ,  C09B62/51

    摘要： A water-soluble monoazodye having the following formula (I) in its free acid form: ##STR1## wherein X is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 W wherein W is a leaving group removable by alkali; R.sup.1 is methyl, --NHCONH.sub.2 or --NHCOT.sup.1 wherein T.sup.1 is methyl, ethyl, --CH.sub.2 CH.sub.2 COOH or --CH.dbd.CHCOOH; R.sup.2 is hydrogen, lower alkyl or lower alkoxy;and Z is ##STR2## wherein P is cyano or halogen, each of Q and U which are independent of each other, is halogen, V is halogen or ##STR3## and Y is halogen or a group of the following formula (1) or (2): ##STR4## wherein R.sup.3, A, R.sup.4 and E are as defined in the disclosure and G is as defined above, has a moderate yellow to orange color and is particularly suitable for dyeing cellulose fibers or nitrogen-containing fibers.

    摘要翻译： 具有游离酸形式的下式（I）的水溶性单偶氮：其中X为-CH = CH 2或-CH 2 CH 2 W，其中W为可由碱除去的离去基团; 乙烯基，-CH 2 CH 2 COOH或-CH = CHCOOH; R 1为甲基，-NHCONH 2或-NHCOT 1，其中T 1为甲基， R2是氢，低级烷基或低级烷氧基; 其中P为氰基或卤素，Q和U各自独立地为卤素，V为卤素或式（1）或（2）：（1）N（ESO 2 X ）2（2）其中R3，A，R4和E如本公开中所定义，G如上所定义，具有中等的黄色至橙色，并且特别适用于染色纤维素纤维或含氮纤维。

    Disperse dye mixtures
    6.
    发明授权
    Disperse dye mixtures 失效
    分散染料混合物

    公开(公告)号：US5332404A

    公开(公告)日：1994-07-26

    申请号：US988813

    申请日：1992-12-10

    申请人： Kiyoshi Himeno ,  Toshio Hihara ,  Hirotsugu Tsumura ,  Yoshiharu Hamano

    发明人： Kiyoshi Himeno ,  Toshio Hihara ,  Hirotsugu Tsumura ,  Yoshiharu Hamano

    IPC分类号： C09B67/22 ,  C09B67/38 ,  D06P1/18 ,  D06P3/54

    CPC分类号： C09B67/0051 ,  C09B67/008 ,  D06P1/18 ,  Y10S8/922

    摘要： A disperse dye mixture comprising a monoazo dye of the following formula (1) and a monoazo dye of the following formula (2) blended thereto in an amount of from 0.1 to 10 times by weight of the dye of the formula (1): ##STR1## wherein each of X.sup.1 and X.sup.2 which are independent of each other, is nitro, cyano, sulfomethyl or halogen, each of Y.sup.1, Y.sup.2, Z.sup.1 and Z.sup.2 which are independent of one another, is hydrogen, cyano, nitro, trifluoromethyl, halogen or sulfomethyl, each of W.sup.1 and W.sup.2 which are independent of each other, is hydrogen, halogen, C.sub.1 -C.sub.2 alkyl or alkoxy, and each of R.sup.1 and R.sup.2 which are independent of each other, is C.sub.1 -C.sub.4 alkyl, or C.sub.2 -C.sub.4 alkyl which is substituted by cyano, halogen, hydroxy, hydroxyalkoxy, C.sub.1 -C.sub.4 alkyl, hydroxyalkoxyalkoxy, acyloxyalkoxy, acyloxyalkoxyalkoxy or alkoxyalkoxy.

    摘要翻译： 一种分散染料混合物，其包含下式（1）的单偶氮染料和下式（2）的单偶氮染料，其量为式（1）染料的0.1-10倍重量： （1）其中X1和X2各自独立的是硝基，氰基，磺基甲基或卤素，Y1，Y2，Z1和Z2各自独立地是 氢，氰基，硝基，三氟甲基，卤素或磺基甲基各自独立地为氢，卤素，C 1 -C 2烷基或烷氧基，R 1和R 2各自独立地为 C 1 -C 4烷基或被氰基，卤素，羟基，羟基烷氧基，C 1 -C 4烷基，羟基烷氧基烷氧基，酰氧基烷氧基，酰氧基烷氧基烷氧基或烷氧基烷氧基取代的C 2 -C 4烷基。

    Water soluble monoazo dye-stuffs containing vinylsulfone and halogenotriazine or difluoromonochloro pyrimidine type reactive groups
    7.
    发明授权
    Water soluble monoazo dye-stuffs containing vinylsulfone and halogenotriazine or difluoromonochloro pyrimidine type reactive groups 失效
    含有乙烯基砜和卤代三嗪或二氟单氯嘧啶型反应性基团的水溶性单偶氮染料

    公开(公告)号：US4988801A

    公开(公告)日：1991-01-29

    申请号：US453342

    申请日：1989-12-20

    申请人： Toshio Hihara ,  Kanzi Shimizu ,  Yukiharu Shimizu

    发明人： Toshio Hihara ,  Kanzi Shimizu ,  Yukiharu Shimizu

    IPC分类号： C09B62/085 ,  C09B62/44 ,  C09B62/51 ,  D06P1/38

    CPC分类号： C09B62/4413

    摘要： A water-soluble monoazo colorant represented by formula (I) in a form of a free acid: ##STR1## wherein D represents ##STR2## (wherein W.sup.2 represents lower alkoxy; U represents lower alkyl or lower alkoxy; Z represents --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 OSO.sub.3 H and p and q represent each 0 or 1);W.sup.1 represents lower alkoxy; andV represents ##STR3## (wherein X represents halogen; Y represents halogen, sulfo, --OR.sup.1 wherein R.sup.1 represents lower alkyl or lower alkyl substituted by hydroxy, carboxy or sulfo, --O--R.sup.2 O).sub.m R.sup.3 alkyl and m is an integer of 1 to 6, or aliphatic or aromatic amino each substituted by one or two sulfo or carboxy groups);as well as a dyeing process by using the same. These colorants are useful in the dyeing of fibers. These colorants are useful in the dyeing of fibers.

    Pyrazolone or pyridone type water soluble disazo colorant containing one or two triazine rings
    8.
    发明授权
    Pyrazolone or pyridone type water soluble disazo colorant containing one or two triazine rings 失效
    含有1或2个三嗪环的吡唑啉酮或吡啶酮型水溶性双偶氮染料

    公开(公告)号：US4843150A

    公开(公告)日：1989-06-27

    申请号：US71644

    申请日：1987-07-09

    申请人： Toshio Hihara ,  Yukiharu Shimizu ,  Kanzi Shimizu

    发明人： Toshio Hihara ,  Yukiharu Shimizu ,  Kanzi Shimizu

    IPC分类号： C09B62/09 ,  C09B62/513 ,  D06P1/38

    CPC分类号： C09B62/09 ,  C09B62/513 ,  D06P1/38

    摘要： A water soluble disazo colorant represented by formula (I) in the form of free acid: ##STR1## wherein K represents ##STR2## [wherein A represents a methyl group or a carboxylic group; R.sup.2 represents a hydrogen atom, an alkyl group of 1 to 8 carbon atoms, a sulfoalkyl grouop of 1 to 4 carbon atoms, or an alkyl group of 1 to 4 carbon atoms which is substituted by an alkoxy group of 1 to 4 carbon atoms;R.sup.3 represents a hydrogen atom, a halogen atom, a cyano group, a --CONH.sub.2 group, a carboxyl group, a sulfonic group, or a sulfomethyl group, p represents an integer of 1 or 2];Z represents a fluorine atom or ##STR3## [wherein R.sup.4 represents a hydrogen atom or an alkyl group of 1 to 4 carbon atoms;R.sup.5 and R.sup.6 each represents independently a hydrogen atom, an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, a sulfonic group, or a halogen atom; Y represents --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 W (wherein W represents a group which is released by the action of an alkali)];R.sup.1 represents a hydrogen atom or a lower alkyl group of 1 to 4 carbon atoms;Q represents a divalent aromatic or aliphatic residual group; andl, m, and n each represents an integer of 0 or 1. Such colorants are useful in the dyeing of fibrous materials.

    摘要翻译： 游离酸形式的由式（I）表示的水溶性双偶氮染料：其中K代表甲基或羧基; R2表示氢原子，1〜8个碳原子的烷基，1〜4个碳原子的磺基烷基组合或1〜4个碳原子的烷氧基被1〜4个碳原子取代的烷基; R3表示氢原子，卤素原子，氰基，-CONH2基，羧基，磺基或磺基甲基，p表示1或2的整数]。 Z表示氟原子或其中R4表示氢原子或1-4个碳原子的烷基; R 5和R 6各自独立地表示氢原子，1〜4个碳原子的烷基，1〜4个碳原子的烷氧基，磺酸基或卤素原子。 Y表示-SO 2 CH = CH 2或-SO 2 CH 2 CH 2 W（其中W表示通过碱的作用而释放的基团）]; R1表示氢原子或1〜4个碳原子的低级烷基; Q表示二价芳族或脂族残基; 和l，m和n各自表示0或1的整数。这种着色剂可用于纤维材料的染色。

    Diazo colors and dyeing method using the same
    9.
    发明授权
    Diazo colors and dyeing method using the same 失效
    重氮颜色和染色方法使用相同

    公开(公告)号：US4841029A

    公开(公告)日：1989-06-20

    申请号：US186656

    申请日：1988-04-19

    申请人： Yoshiaki Kato ,  Toshio Hihara

    发明人： Yoshiaki Kato ,  Toshio Hihara

    IPC分类号： C09B62/513 ,  C07D251/70 ,  C09B62/44 ,  D06P1/38 ,  D06P3/82 ,  D06P3/84 ,  D06P3/85 ,  D06P3/872

    CPC分类号： D06P1/38 ,  C09B62/4415

    摘要： A disazo color having three triazine rings, one of which is substituted with a reactive group of --NR.sup.1 --A--SO.sub.2 C.sub.2 H.sub.4 OSO.sub.3 M, wherein R.sup.1 represents a hydrogen atom or a lower alkyl group; A represents a substituted or unsubstituted phenylene or naphthylene group; and M represents a hydrogen atom or an alkali metal. The disazo color is capable of dyeing cellulose-containing fibers under conditions conventionally employed for dyeing polyester fibers with a disperse dye, making it possible to dye mixed fibers of cellulose fiber and polyester fiber in a single-bath through one step.

    摘要翻译： 具有三个三嗪环的二重色，其中一个被-NR1-A-SO2C2H4OSO3M的反应性基团取代，其中R1表示氢原子或低级烷基; A表示取代或未取代的亚苯基或亚萘基; M表示氢原子或碱金属。 双色调能够在通常用于用分散染料染色聚酯纤维的条件下染色含纤维素纤维，使得可以通过一步将单纤维素纤维和聚酯纤维的混合纤维染色。