公开(公告)号：US07879450B2

公开(公告)日：2011-02-01

申请号：US11711659

申请日：2007-02-28

申请人： Takashi Matsuda ,  Mikio Shiono ,  Takeshi Hashimoto

发明人： Takashi Matsuda ,  Mikio Shiono ,  Takeshi Hashimoto

IPC分类号： B32B9/04 ,  C08G77/24

CPC分类号： F16J15/108 ,  C08J7/047 ,  C08J2383/04 ,  C08J2471/00 ,  Y10T428/31663

摘要： A rubber article is manufactured by heat curing a heat-curable silicone rubber composition filled with untreated fumed silica to form a substrate, applying a primer composition comprising a fluoroalkylene or fluoropolyether compound having at least one alkenyl radical and at least one hydrolyzable silyl radical onto the substrate surface, and disposing a heat-curable perfluoropolyether elastomer composition thereon and curing the composition for integration. The integrally molded article has characteristics of both silicone rubber and fluoroelastomer.

摘要翻译： 通过将填充有未处理的热解法二氧化硅的可热固化的硅橡胶组合物加热固化以形成基底来制造橡胶制品，将包含具有至少一个烯基的氟代亚烷基或含氟聚醚化合物的底漆组合物和至少一种可水解的甲硅烷基基团 底物表面，并在其上设置可热固化的全氟聚醚弹性体组合物，并固化该组合物用于整合。 一体成形品具有硅橡胶和含氟弹性体的特征。

公开(公告)号：US20070205533A1

公开(公告)日：2007-09-06

申请号：US11711659

申请日：2007-02-28

申请人： Takashi Matsuda ,  Mikio Shiono ,  Takeshi Hashimoto

发明人： Takashi Matsuda ,  Mikio Shiono ,  Takeshi Hashimoto

IPC分类号： B29C69/00 ,  B32B25/00

CPC分类号： F16J15/108 ,  C08J7/047 ,  C08J2383/04 ,  C08J2471/00 ,  Y10T428/31663

摘要： A rubber article is manufactured by heat curing a heat-curable silicone rubber composition filled with untreated fumed silica to form a substrate, applying a primer composition comprising a fluoroalkylene or fluoropolyether compound having at least one alkenyl radical and at least one hydrolyzable silyl radical onto the substrate surface, and disposing a heat-curable perfluoropolyether elastomer composition thereon and curing the composition for integration. The integrally molded article has characteristics of both silicone rubber and fluoroelastomer.

摘要翻译： 通过将填充有未处理的热解法二氧化硅的可热固化的硅橡胶组合物加热固化以形成基底来制造橡胶制品，将包含具有至少一个烯基的氟代亚烷基或含氟聚醚化合物的底漆组合物和至少一种可水解的甲硅烷基基团 底物表面，并在其上设置可热固化的全氟聚醚弹性体组合物，并固化该组合物用于整合。 一体成形品具有硅橡胶和含氟弹性体的特征。

公开(公告)号：US06576737B2

公开(公告)日：2003-06-10

申请号：US09969829

申请日：2001-10-04

申请人： Mikio Shiono ,  Takashi Matsuda ,  Masatoshi Arai

发明人： Mikio Shiono ,  Takashi Matsuda ,  Masatoshi Arai

IPC分类号： C08G7724

CPC分类号： C08L71/02 ,  C08G65/007 ,  C08L83/08 ,  C08L83/14 ,  C08L83/00

摘要： A curable composition comprising (A) a fluorinated amide compound having at least one alkenyl radical, (B) a fluorinated organohydrogensiloxane, (C) a platinum group compound, (D) a first organosiloxane having at least one SiH radical and at least one epoxy and/or trialkoxysilyl radical, and (E) a second organosiloxane having at least one SiH radical, at least one cyclic carboxylic anhydride residue, and at least one monovalent perfluorooxyalkyl or perfluoroalkyl radical cures into a fluorinated elastomer that not only has good solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability and electrical properties, but also firmly bonds to a variety of substrates including PPS, polyamide and polyimide resins.

摘要翻译： 一种可固化组合物，其包含（A）具有至少一个烯基的氟化酰胺化合物，（B）氟化有机氢硅氧烷，（C）铂族化合物，（D）具有至少一个SiH基团和至少一个环氧基的第一有机硅氧烷 和/或三烷氧基甲硅烷基，和（E）具有至少一个SiH基，至少一个环状羧酸酐残基和至少一个一价全氟氧烷基或全氟烷基的第二有机硅氧烷固化成不仅耐溶剂性良好的氟化弹性体， 耐化学性，耐热性，低温性，低透湿性和电性能，而且牢固地粘合到各种基材，包括PPS，聚酰胺和聚酰亚胺树脂。

公开(公告)号：US08314190B2

公开(公告)日：2012-11-20

申请号：US12874768

申请日：2010-09-02

申请人： Mitsuo Muto ,  Takashi Matsuda ,  Mikio Shiono

发明人： Mitsuo Muto ,  Takashi Matsuda ,  Mikio Shiono

IPC分类号： C08G77/00 ,  C08L83/00

CPC分类号： C08G65/007 ,  C08G2650/48 ,  C08L71/02 ,  C08L83/00

摘要： A fluoropolyether base rubber composition comprising (a) a linear fluoropolyether compound containing at least two ester groups in a molecule and a divalent perfluoroalkyl ether structure in its backbone, and having a Mn of 3,000-100,000, and (b) a siloxane polymer containing at least three amino groups in a molecule cures at room temperature into a product having heat resistance, low-temperature performance, chemical resistance, solvent resistance and oil resistance.

摘要翻译： 一种含氟聚醚基橡胶组合物，其包含（a）在分子中含有至少两个酯基的直链含氟聚醚化合物和其主链中的二价全氟烷基醚结构，并且具有3,000-100,000的Mn，和（b）含有 分子中至少三个氨基在室温下固化成具有耐热性，低温性能，耐化学性，耐溶剂性和耐油性的产品。

公开(公告)号：US06517946B2

公开(公告)日：2003-02-11

申请号：US09778084

申请日：2001-02-07

申请人： Mikio Shiono ,  Takashi Matsuda

发明人： Mikio Shiono ,  Takashi Matsuda

IPC分类号： B32B1508

CPC分类号： C08L83/08 ,  C08L2666/14 ,  C09J183/08 ,  Y10T428/31663 ,  C08L2666/44

摘要： A curable composition comprising (A) a fluorinated amide compound, (B) a specific fluorinated organohydrogen-siloxane, (C) a platinum group compound, (D) an organosiloxane adhesion-imparting agent, (E) a silica powder having a BET specific surface area of at least 50 m2/g and (F) an organosilane or organosiloxane surface treatment agent for the silica powder provides a cured product endowed with excellent resistance to solvents, chemicals and heat, outstanding low-temperature properties, a low water-vapor permeability and outstanding electrical characteristics. When heated at a relatively low temperature for a relatively short period of time, the composition cures to a form having good adhesion and good durability of adhesion to base materials such as metals and plastics.

摘要翻译： 一种可固化组合物，其包含（A）氟化酰胺化合物，（B）特定氟化有机氢 - 硅氧烷，（C）铂族化合物，（D）有机硅氧烷粘合赋予剂，（E） 表面积至少为50m2 / g，（F）二氧化硅粉末的有机硅烷或有机硅氧烷表面处理剂提供了具有优异的耐溶剂性，耐化学性和耐热性，优异的低温性能，低水蒸汽性 渗透性和优异的电气特性。 当在相对较低的温度下加热相当短的时间时，组合物固化成具有良好粘合性和对金属和塑料等基材的良好耐久性的形式。

公开(公告)号：US06500976B2

公开(公告)日：2002-12-31

申请号：US09970685

申请日：2001-10-05

申请人： Takashi Matsuda ,  Mikio Shiono ,  Kenichi Fukuda

发明人： Takashi Matsuda ,  Mikio Shiono ,  Kenichi Fukuda

IPC分类号： C07F708

CPC分类号： C07F7/0896

摘要： Organosilicon compounds each having in a molecule (A) a perfluoroalkyl group of at least 3 carbon atoms which may be separated by an etheric oxygen atom, (B) a monovalent hydrocarbon group containing a carboxylic acid anhydride structure, and (C) a hydrosilyl (SiH) group are novel and added to thermosetting elastomer compositions as adhesion aids whereby the compositions are improved in adhesion to various materials including metals, alloys, plastics, and ceramics.

摘要翻译： 在（A）分子中具有至少3个碳原子的全氟烷基的有机硅化合物可以被醚性氧原子分离，（B）含有羧酸酐结构的一价烃基，和（C）氢化硅烷基（ SiH）基团是新型的，并且添加到热固性弹性体组合物中作为粘合助剂，由此组合物对包括金属，合金，塑料和陶瓷在内的各种材料的粘合性提高。

公开(公告)号：US08299196B2

公开(公告)日：2012-10-30

申请号：US13085510

申请日：2011-04-13

申请人： Mikio Shiono ,  Noriyuki Koike

发明人： Mikio Shiono ,  Noriyuki Koike

IPC分类号： C08G77/08

CPC分类号： C09D183/08 ,  C08G77/24 ,  C08L71/02

摘要： An adhesive composition is provided comprising (A) a fluorinated amide compound containing at least two vinyl groups and having a polyfluoro structure, (B) a fluorinated organosilicon compound containing a fluorinated organic group, at least two SiH groups, and an alkyl, aryl or aralkyl group, and (C) a platinum catalyst, and (D) an organosiloxane containing a SiH group and an epoxy and/or trialkoxysilyl group. The composition is cured on brief heating into a product which achieves adhesion to various substrates and has solvent resistance, chemical resistance, heat resistance, low-temperature properties, low moisture permeability, electric insulation, and acid resistance.

摘要翻译： 提供一种粘合剂组合物，其包含（A）含有至少两个乙烯基并具有多氟结构的氟化酰胺化合物，（B）含氟化有机基团的氟化有机硅化合物，至少两个SiH基团和烷基，芳基或 芳族烷基，（C）铂催化剂，（D）含有SiH基和环氧基和/或三烷氧基甲硅烷基的有机硅氧烷。 该组合物在短暂加热下固化成实现对各种基材的粘合性的产品，并具有耐溶剂性，耐化学性，耐热性，低温性，低透湿性，电绝缘性和耐酸性。

公开(公告)号：US08110065B2

公开(公告)日：2012-02-07

申请号：US12124556

申请日：2008-05-21

申请人： Hidenori Koshikawa ,  Mikio Shiono ,  Hiroyasu Hara ,  Takashi Aketa

发明人： Hidenori Koshikawa ,  Mikio Shiono ,  Hiroyasu Hara ,  Takashi Aketa

IPC分类号： C04B37/00 ,  C09J7/02 ,  C08F283/00 ,  C08F283/12 ,  C08G77/00 ,  C08G77/38 ,  C08L83/00

CPC分类号： C08G65/007 ,  C08G2650/48 ,  C08K5/0025 ,  C08L83/00 ,  C08L83/08 ,  C08L2666/34 ,  C09J171/02

摘要： A heat-curable fluoropolyether adhesive composition comprising (A) a linear polyfluoro compound having at least two alkenyl groups and a perfluoropolyether structure, (B) a fluorinated organohydrogensiloxane having at least two SiH groups, (C) a platinum group metal catalyst, (D) an organosiloxane having at least one SiH group and at least one epoxy and/or trialkoxysilyl group, and (E) a compound having at least two allyloxycarbonyl groups can be cured to metal and plastic substrates by heating at a temperature from 20° C. to less than 100° C.

摘要翻译： 一种可热固化的氟聚醚粘合剂组合物，其包含（A）具有至少两个烯基和全氟聚醚结构的线性多氟化合物，（B）具有至少两个SiH基团的氟化有机氢硅氧烷，（C）铂族金属催化剂，（D ）具有至少一个SiH基团和至少一个环氧基和/或三烷氧基甲硅烷基的有机硅氧烷，和（E）具有至少两个烯丙氧基羰基的化合物可以通过在20℃的温度下加热固化到金属和塑料基材上。 至小于100℃

公开(公告)号：US07851066B2

公开(公告)日：2010-12-14

申请号：US12124436

申请日：2008-05-21

申请人： Hiromasa Yamaguchi ,  Mikio Shiono

发明人： Hiromasa Yamaguchi ,  Mikio Shiono

IPC分类号： B32B9/04

CPC分类号： C08G65/007 ,  C08G65/336 ,  C08G77/12 ,  C08G77/24 ,  C08G2650/48 ,  C08L71/02 ,  C08L83/04 ,  C08L2205/02 ,  Y10T428/31663 ,  Y10T428/31786 ,  C08L83/00

摘要： Curable fluoropolyether compositions comprising (a) a polyfluorodialkenyl compound, (b) a fluorinated organohydrogenpolysiloxane, (c) a platinum catalyst, (d) hydrophobic silica powder, (e) a tackifier in the form of a specific silicon compound, and (f) an organosiloxane having a SiH group, an epoxy and/or trialkoxysilyl group, and a perfluoroalkyl or perfluoropolyether group cure to thermoplastic resins to form a durable tight bond at a low temperature within a short time and are readily releasable from metal molds.

摘要翻译： 固化氟聚醚组合物，其包含（a）多氟二烯基化合物，（b）氟化有机氢聚硅氧烷，（c）铂催化剂，（d）疏水性二氧化硅粉末，（e）特定硅化合物形式的增粘剂，和（f） 具有SiH基团，环氧基和/或三烷氧基甲硅烷基的有机硅氧烷和全氟烷基或全氟聚醚基固化成热塑性树脂，以在短时间内在低温下形成耐久的紧密结合，并且容易从金属模上释放。

公开(公告)号：US20090130318A1

公开(公告)日：2009-05-21

申请号：US12265328

申请日：2008-11-05

申请人： Mikio Shiono ,  Kenichi Fukuda ,  Shinichi Sato

发明人： Mikio Shiono ,  Kenichi Fukuda ,  Shinichi Sato

IPC分类号： B05D3/02

CPC分类号： C09J5/02 ,  C08J5/122 ,  C08J2327/12 ,  C08J2377/00 ,  C09J2421/008 ,  C09J2427/008 ,  C09J2477/008

摘要： A bond between fluoroelastomer and polyamide resin is established by applying a silane-based primer composition to a surface of polyamide resin, heat treating at 100-200° C., applying a liquid fluoroelastomer composition to the primer coat at room temperature to 100° C., and heat curing at 100-200° C. for bonding the fluoroelastomer to the polyamide resin. The bond between fluoroelastomer and polyamide resin is maintained over a long period of time even in transmission oils.

摘要翻译： 通过将硅烷类底漆组合物涂布在聚酰胺树脂的表面上，在100〜200℃下进行热处理，将液态含氟弹性体组合物在室温〜100℃下涂布在底涂层上，建立了含氟弹性体和聚酰胺树脂之间的键 并在100-200℃下热固化，以将含氟弹性体粘合到聚酰胺树脂上。 含氟弹性体和聚酰胺树脂之间的粘合剂即使在变速箱油中也能长期保持。