公开(公告)号：US06569337B2

公开(公告)日：2003-05-27

申请号：US09867612

申请日：2001-05-31

申请人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida ,  Mitsugu Kotani

发明人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida ,  Mitsugu Kotani

IPC分类号： C02F300

CPC分类号： C02F3/10 ,  Y02W10/15

摘要： There are disclosed a bioreactor carrier comprising a (A) water swellable thermoplastic resin, preferably water swellable thermoplastic polyurethane resin and a (B) specific inorganic filler which is added thereto at the time of producing and/or molding said resin, characterized in that the specific gravity of the carrier on swelling in water is controlled within the range of 1.02 to 1.35; a process for producing the bioreactor carrier; and a process for denitrifying treatment of organic waste water which comprises nitrifying and denitrifying nitrogen components in the organic waste water with microbes by the use of the above bioreactor carrier. The bioreactor carrier has high physical strength, can be readily produced and uniformly fluidized in a reactor, and enables microbial and enzymatic reactions to be effectively performed.

公开(公告)号：US6011110A

公开(公告)日：2000-01-04

申请号：US915717

申请日：1997-08-21

申请人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

发明人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

IPC分类号： C02F3/10 ,  C08G18/48 ,  C12N11/08 ,  C08J3/03

CPC分类号： C02F3/10 ,  C08G18/4833 ,  C08G18/4837 ,  C12N11/08 ,  C08G2210/00 ,  Y02W10/15 ,  Y10S524/916

摘要： A bioreactor carrier is provided which is a thermoplastic organic high molecular compound having a swelling rate of volume in water of 150-4,000% and which is useful as a carrier to which animal cells, plant cells, microorganisms and/or protozoans are fixed to obtain a bioreactor for substance production, harmful substance treatment, waste oil treatment, wastewater treatment, deodorization or the like. A method of producing the carrier includes the steps of reacting long-chain and short-chain polyol compounds and an isocyanate compound to obtain a thermoplastic resin, heating the thermoplastic resin to its melting temperature thereby plasticizing it, extruding the plasticized resin into strands with an extruder, and continuously chopping the strands into pellets.

摘要翻译： 提供了一种生物反应器载体，其是在水中的体积溶胀率为150-4,000％的热塑性有机高分子化合物，其可用作动物细胞，植物细胞，微生物和/或原生动物被固定以获得的载体 用于物质生产，有害物质处理，废油处理，废水处理，除臭等的生物反应器。 制造载体的方法包括使长链和短链多元醇化合物与异氰酸酯化合物反应以获得热塑性树脂的步骤，将热塑性树脂加热至其熔融温度从而使其增塑，将增塑树脂以 挤出机，并连续地将线料切成小粒。

公开(公告)号：US06565751B2

公开(公告)日：2003-05-20

申请号：US09867613

申请日：2001-05-31

申请人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida ,  Mitsugu Kotani

发明人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida ,  Mitsugu Kotani

IPC分类号： C02F300

CPC分类号： C02F3/108 ,  C12N11/08 ,  Y02W10/15

摘要： There are disclosed a bioreactor carrier comprising a (A) water swellable thermoplastic resin, preferably water swellable thermoplastic polyurethane resin and a (B) compatible resin with the resin as the component (A), and as the case may be, a (C) inorganic filler, characterized in that the degree of volumetric swelling of said carrier is controlled within the range of 120 to 3000%, and that the specific gravity of said carrier on swelling in water is controlled within the range of 1.02 to 2.12; a process for producing the bioreactor carrier; and a process for denitrifying treatment of organic waste water which comprises nitrifying and denitrifying nitrogen components in the organic waste water with microbes by using the above bioreactor carrier. The bioreactor carrier has high physical strength, can be readily produced and uniformly fluidized in a reactor, and enables microbial and enzymatic reactions to be effectively performed.

公开(公告)号：US6017625A

公开(公告)日：2000-01-25

申请号：US116221

申请日：1998-07-16

申请人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

发明人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

IPC分类号： C08G18/48 ,  C08G14/10 ,  C08G18/00 ,  D01F6/70 ,  D01F6/94 ,  D07G3/00

CPC分类号： D01F6/70 ,  Y10T428/2913 ,  Y10T428/2967

摘要： A water-insoluble, nonionic water-absorptive polyurethane fiber that combines the properties of high water absorptivity and excellent physical strength is produced by extrusion from a thermoplastic polyurethane resin composition at a temperature higher than its melting point. The thermoplastic polyurethane resin composition, which has a water absorption rate within the range of 200-3,000%, is obtained by reacting a polyisocyanate compound, a water-soluble polyalkylene ether polyol having a weight-average molecular weight of 2,000-13,000 and a chain extender at an equivalent ratio (R ratio) between the equivalent number of NCO groups and the equivalent number of OH groups in the range of 1.0 to 1.8. Also provided is a method of producing the water-absorptive polyurethane fiber.

摘要翻译： 通过在高于其熔点的温度从热塑性聚氨酯树脂组合物挤出而产生结合了高吸水性和优异的物理强度的性质的水不溶性非离子吸水聚氨酯纤维。 吸水率在200-3000％范围内的热塑性聚氨酯树脂组合物是通过使多异氰酸酯化合物，重均分子量为2,000-13,000的水溶性聚亚烷基醚多元醇和链 以相当数量的NCO基团和OH基团的当量数之间的当量比（R比）在1.0至1.8的范围内。 还提供了一种生产吸水性聚氨酯纤维的方法。

公开(公告)号：US06610205B2

公开(公告)日：2003-08-26

申请号：US09836413

申请日：2001-04-18

申请人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

发明人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

IPC分类号： C02F300

CPC分类号： C02F3/302 ,  C02F3/10 ,  C02F3/301 ,  Y02W10/15 ,  Y10S210/903 ,  Y10S210/905

摘要： There is disclosed a process for nitrifying denitrifying organic waste water to nitrify and denitrify the nitrogenous components in the waste water, which comprises making use of a microbe carrier composed of an organic thermoplastic high molecular compound (thermoplastic polyurethane) in both a nitrifying step and a denitrifying step, preferably in an alternate and repeated manner, wherein the compound has, in a state of complete swelling in water, a water absorption rate in the range of 50 to 3500%, a compressive yield stress of at least 1.0 MPa each being defined by a specific formula, and a particle diameter in the range of 1.0 to 30 mm. The process is capable of efficiently performing nitrifying and denitrifying steps, steadily achieving high treatment performances, contriving compactification of the treatment facility, and curtailing the treatment time and treatment cost, while the microbe carrier can withstand long-term service without any trouble.

摘要翻译： 公开了一种硝化脱氮有机废水以对废水中的含氮组分进行硝化和反硝化的方法，该方法包括在硝化步骤中使用由有机热塑性高分子化合物（热塑性聚氨酯）组成的微生物载体， 反硝化步骤，优选以交替和重复的方式，其中化合物在水中完全溶胀的状态下具有在50至3500％范围内的吸水率，每个定义的压缩屈服应力至少为1.0MPa 通过具体的公式，并且粒径在1.0至30mm的范围内。 该工艺能够有效地进行硝化和反硝化步骤，稳定地实现高处理性能，实现处理设备的紧凑化，并且缩短处理时间和处理成本，而微生物载体可以承受长期的服务而没有任何麻烦。

公开(公告)号：US6133004A

公开(公告)日：2000-10-17

申请号：US36900

申请日：1998-03-09

申请人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

发明人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

IPC分类号： C12M1/00 ,  C02F3/10 ,  C08F26/02 ,  C08L39/00 ,  C12N11/08 ,  C02F3/00 ,  C12M3/00 ,  C12N5/00 ,  C12N11/04

CPC分类号： C02F3/108 ,  Y02W10/15

摘要： A bioreactor carrier is provided composed of a water absorption gel of a crosslinked N-vinylcarboxamide resin which has a great moisture content and excellent physical strength, is not eroded by microorganisms and is easily mass-produced on an industrial scale. The gel is obtained by swelling and gelling a crosslinked N-vinylcarboxamide resin made from an N-vinylcarboxamide such as N-vinylacetoamide. The swollen gel may be in the form of beads of 1.0 to 20 mm, and the resin when swollen with water has a water absorption coefficient of 500 to 3500%. Resin beads may be swollen in a suspension of a biocatalyst such as animal cells, plant cells, microorganisms or protozoans to bind and immobilize the biocatalyst to form a bioreactor. The microorganisms can be nitrate bacteria, denitrification bacteria or Hyphomycetes, and the bioreactor may be used to treat waste water or for deodorizing. The crosslinked N-vinylcarboxamide resin contains a repeating unit shown by formula (A) below crosslinked with a crosslinking agent. ##STR1## wherein R.sup.1 and R.sup.2 represent independently a hydrogen atom or a methyl group.

摘要翻译： 提供一种生物反应器载体，其由具有高水分含量和优异的物理强度的交联的N-乙烯基甲酰胺树脂的吸水凝胶组成，不被微生物侵蚀并且易于在工业规模上批量生产。 通过使由N-乙烯基乙酰胺等N-乙烯基酰胺制成的交联的N-乙烯基甲酰胺树脂溶胀，凝胶化而得到凝胶。 溶胀凝胶可以是1.0〜20mm的珠粒，当用水溶胀时，树脂的吸水系数为500〜3500％。 树脂珠可以在生物催化剂如动物细胞，微生物或原生动物的悬浮液中溶胀，以结合和固定生物催化剂以形成生物反应器。 微生物可以是硝酸盐细菌，脱氮菌或真菌，生物反应器可用于处理废水或除臭。 交联的N-乙烯基甲酰胺树脂含有与交联剂交联的下式（A）所示的重复单元。 其中R1和R2独立地表示氢原子或甲基。

公开(公告)号：US06214619B1

公开(公告)日：2001-04-10

申请号：US08990192

申请日：1997-12-12

申请人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

发明人： Takaya Sato ,  Tsutomu Uehara ,  Hiroshi Yoshida

IPC分类号： C12N500

CPC分类号： C02F3/108 ,  Y02W10/15

摘要： A bioreactor carrier is provided using an organic polymer substance having a water absorptivity of 50 to 1,700%, and containing an inorganic salt, organic nitrogen source and/or organic carbon source utilizable as a nutrient by animal cells, plant cells and/or microorganisms which fix to the carrier for uses such as substance production, harmful substance treatment, waste oil treatment, wastewater treatment and deodorization. A preferred polymer substance is a water swellable thermoplastic polyurethane gel having the water absorptivity and a swelling rate of volume of 150 to 4,000%. The polyurethane gel is obtained by reacting together a long-chain diol compound, a short-chain diol compound and a diisocyanate compound. The long-chain diol compound has a number-average molecular weight of 400 to 10,000, and is selected from an ethylene oxide-propylene oxide copolymer having an ethylene oxide content not less than 70% and a polyethylene glycol. The short-chain diol compound has a number-average molecular weight of 30 to 400. The diisocyanate compound has a number-average molecular weight of 100 to 1,000 at an NCO/OH equivalency in the range of 1-5. Microorganisms multiply rapidly at the surface and interior of the carrier. Preferred adherence and proliferation of desired microorganisms is possible by appropriately selecting substances incorporated as microorganism nutrients.

摘要翻译： 使用具有50至1,700％的吸水率的有机聚合物物质提供生物反应器载体，并且包含可用作动物细胞，植物细胞和/或微生物的植物细胞和/或微生物作为营养物的无机盐，有机氮源和/或有机碳源 确定物质生产，有害物质处理，废油处理，废水处理和除臭等用途的承运人。 优选的聚合物物质是水溶胀性热塑性聚氨酯凝胶，其吸水性和体积溶胀率为150至4,000％。 通过使长链二醇化合物，短链二醇化合物和二异氰酸酯化合物反应而得到聚氨酯凝胶。 长链二醇化合物的数均分子量为400〜10,000，选自环氧乙烷含量不低于70％的环氧乙烷 - 环氧丙烷共聚物和聚乙二醇。 短链二醇化合物的数均分子量为30〜400。二异氰酸酯化合物的NCO / OH当量的数均分子量为100〜1000，为1-5。 微生物在载体的表面和内部迅速繁殖。 通过适当选择作为微生物营养素掺入的物质，所需微生物的优选粘附和增殖是可能的。

公开(公告)号：US6096418A

公开(公告)日：2000-08-01

申请号：US64388

申请日：1998-04-22

申请人： Takaya Sato ,  Tsutomu Uehara

发明人： Takaya Sato ,  Tsutomu Uehara

IPC分类号： B41M5/00 ,  B41M5/50 ,  B41M5/52

CPC分类号： B41M5/5236 ,  B41M5/52 ,  Y10T428/25 ,  Y10T428/31971

摘要： To provide a sheet for ink-jet recording having a low ink-spreading property and an excellent sheet-feeding property, a sheet for ink-jet recording which comprises a base material taking the form of sheet and an ink receiving layer which is laminated onto at least one surface of the base material and contains a binder and fine porous polysaccharide particles is produced. Further, the above-mentioned sheet for ink-jet recording wherein the fine porous polysaccharide particles are exposed on the surface of the ink receiving layer to form unevenness thereon is produced.

摘要翻译： 为了提供具有低油墨铺展性和优异的进纸性能的喷墨记录用片材，一种喷墨记录用片材，其特征在于，包括以片状形式的基材和油墨接收层， 基材的至少一个表面并含有粘合剂，并且制造细多孔多糖颗粒。 此外，制造上述用于喷墨记录的片材，其中细多孔多糖颗粒在油墨接收层的表面上暴露以形成不均匀性。

公开(公告)号：US07258921B2

公开(公告)日：2007-08-21

申请号：US10523816

申请日：2003-08-07

申请人： Toshifumi Hashiba ,  Kazutoshi Hayakawa ,  Satomi Kudo ,  Kaori Satoh ,  Takaya Sato ,  Hiroshi Yoshida

发明人： Toshifumi Hashiba ,  Kazutoshi Hayakawa ,  Satomi Kudo ,  Kaori Satoh ,  Takaya Sato ,  Hiroshi Yoshida

IPC分类号： B32B5/66

CPC分类号： C08G73/00 ,  C08J3/005 ,  C08J3/12 ,  C08J2379/00 ,  C08L79/00 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2998

摘要： A composite particle that can be easily converted to cured particle or half cured particle by the use of carbodiimide resin without changing of the configuration of matrix particle of, for example a thermoplastic resin, excelling in mechanical and functional characteristics by virtue of the reaction capability inherently possessed by a carbodiimide group. In particular, a composite particle comprising matrix particle (A) having a functional group capable of reacting with a carbodiimide group and carbodiimide resin (B), characterized in that the functional group of the matrix particle (A) couples with the carbodiimide group of the carbodiimide resin (B) and that the composite particle is provided with an outer shell layer of carbodiimide resin (B) having an average thickness diameter (L), defined by the following formula [1], ranging from 0.01 to 20 μm: L=(L2−L1)/2 [1] wherein L1 represents the average diameter of matrix particle, and L2 represents the average diameter of composite particle.

摘要翻译： 通过使用碳二亚胺树脂可以容易地转化为固化颗粒或半固化颗粒的复合颗粒，而不改变例如热塑性树脂的基质颗粒的构型，其本身具有优异的机械和功能特性 拥有碳化二亚胺组。 特别是，具有能够与碳二亚胺基反应的官能团的基质粒子（A）和碳二亚胺树脂（B）的复合粒子，其特征在于，所述基质粒子（A）的官能团与所述碳二亚胺基团 碳化二亚胺树脂（B），并且复合颗粒具有由下式[1]定义的平均厚度直径（L）的碳二亚胺树脂（B）的外壳层，其范围为0.01至20μm：L = （L 2 -L 1 -L 1）/ 2 [1]其中L1表示基质颗粒的平均直径，L2表示复合颗粒的平均直径。

公开(公告)号：US20050271875A1

公开(公告)日：2005-12-08

申请号：US10523816

申请日：2003-08-07

申请人： Toshifumi Hashiba ,  Kazutoshi Hayakawa ,  Satomi Kudo ,  Kaori Satoh ,  Takaya Sato ,  Hiroshi Yoshida

发明人： Toshifumi Hashiba ,  Kazutoshi Hayakawa ,  Satomi Kudo ,  Kaori Satoh ,  Takaya Sato ,  Hiroshi Yoshida

IPC分类号： C08G73/00 ,  C08J3/00 ,  C08J3/12 ,  C08L79/00 ,  B32B5/16

CPC分类号： C08G73/00 ,  C08J3/005 ,  C08J3/12 ,  C08J2379/00 ,  C08L79/00 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2998

摘要： A composite particle that can be easily converted to cured particle or half cured particle by the use of carbodiimide resin without changing of the configuration of matrix particle of, for example. a thermoplastic resin, excelling in mechanical and functional characteristics by virtue of the reaction capability inherently possessed by a carbodiimide group. In particular, a composite particle comprising matrix particle (A) having a functional group capable of reacting with a carbodiimide group and carbodiimide resin (B), characterized in that the functional group of the matrix particle (A) couples with the carbodiimide group of the carbodiimide resin (B) and that the composite particle is provided with an outer shell layer of carbodiimide resin (B) having an average thickness diameter (L), defined by the following formula [1], ranging from 0.01 to 20 μm: L=(L2−L1)/2 [1] wherein L1 represents the average diameter of matrix particle, and L2 represents the average diameter of composite particle.

摘要翻译： 例如可以通过使用碳二亚胺树脂容易地转化为固化颗粒或半固化颗粒的复合颗粒，而不改变例如基质颗粒的构型。 一种热塑性树脂，由于碳化二亚胺基固有的反应能力而具有优异的机械性能和功能特性。 特别是，具有能够与碳二亚胺基反应的官能团的基质粒子（A）和碳二亚胺树脂（B）的复合粒子，其特征在于，所述基质粒子（A）的官能团与所述碳二亚胺基团 碳化二亚胺树脂（B），并且复合颗粒具有由下式[1]定义的平均厚度直径（L）的碳二亚胺树脂（B）的外壳层，其范围为0.01至20μm：L = （L 2 -L 1 -L 1）/ 2 [1]其中L1表示基质颗粒的平均直径，L2表示复合颗粒的平均直径。