Method of manufacturing a semipermeable membrane from a water-soluble
polymeric resin
    2.
    发明授权
    Method of manufacturing a semipermeable membrane from a water-soluble polymeric resin 失效
    从水溶性聚合物树脂制造半透膜的方法

    公开(公告)号:US3992495A

    公开(公告)日:1976-11-16

    申请号:US503701

    申请日:1974-09-06

    CPC分类号: B01D67/009 C08J7/123

    摘要: Ultrathin membranes for separating substances are obtained by exposing shaped articles comprising a water-soluble polymer or a mixture of a water-soluble polymer and water-insoluble polymer to a plasma of a gas selected from helium, argon, nitrogen, hydrogen, oxygen, carbon monoxide, carbon dioxide, ammonia, a hydrocarbon having 1 to 10 carbon atoms, an epoxide having 2 to 10 carbon atoms, or an alkylamine, or a mixture of these substances to crosslink the surface layer, and then washing the exposed articles with water to remove the unreacted portions. The membrane exhibits outstanding performance characteristics when used in the processes for separating or concentrating substances, such as reverse osmosis, ultrafiltration, and the like.

    摘要翻译: 用于分离物质的超薄膜通过将包含水溶性聚合物或水溶性聚合物和水不溶性聚合物的混合物的成型制品暴露于选自氦,氩,氮,氢,氧,碳的气体的等离子体而获得 一氧化碳,二氧化碳,氨,碳原子数为1〜10的烃,碳原子数为2〜10的环氧化物,或烷基胺,或这些物质的混合物交联表面层,然后用水洗涤曝光物品 去除未反应的部分。 当用于分离或浓缩物质的方法如反渗透,超滤等时,该膜具有优异的性能特征。

    Semipermeable membrane and process of making same
    4.
    发明授权
    Semipermeable membrane and process of making same 失效
    半透膜及其制造方法

    公开(公告)号:US4330406A

    公开(公告)日:1982-05-18

    申请号:US70692

    申请日:1979-08-27

    CPC分类号: B01D67/009 C08J7/123

    摘要: Ultrathin membranes for separating substances are obtained by exposing shaped articles comprising a water-soluble polymer or a mixture of a water-soluble polymer and water-insoluble polymer to a plasma of a gas selected from helium, argon, nitrogen, hydrogen, oxygen, carbon monoxide, carbon dioxide, ammonia, a hydrocarbon having 1 to 10 carbon atoms, an epoxide having 2 to 10 carbon atoms, or an alkylamine, or a mixture of these substances to crosslink the surface layer, and then washing the exposed articles with water to remove the unreacted portions. The membrane exhibits outstanding performance characteristics when used in the processes for separating or concentrating substances, such as reverse osmosis, ultrafiltration, and the like.

    摘要翻译: 用于分离物质的超薄膜通过将包含水溶性聚合物或水溶性聚合物和水不溶性聚合物的混合物的成型制品暴露于选自氦,氩,氮,氢,氧,碳的气体的等离子体而获得 一氧化碳,二氧化碳,氨,碳原子数为1〜10的烃,碳原子数为2〜10的环氧化物,或烷基胺,或这些物质的混合物交联表面层,然后用水洗涤曝光物品 去除未反应的部分。 当用于分离或浓缩物质的方法如反渗透,超滤等时,该膜具有优异的性能特征。

    Process for preparing membranes for separation of substances
    7.
    发明授权
    Process for preparing membranes for separation of substances 失效
    制备用于分离物质的膜的方法

    公开(公告)号:US4046843A

    公开(公告)日:1977-09-06

    申请号:US606005

    申请日:1975-08-20

    CPC分类号: B01D67/009

    摘要: A semipermeable membrane is obtained by casting a cast solution comprising a mixture of a water-insoluble high polymer and a water-soluble high polymer, a mixture of a water-insoluble high polymer and a water-soluble surfactant or a mixture of a water-insoluble high polymer, a water-soluble high polymer and a water-soluble surfactant to form a shaped article, exposing the thus formed shaped article to a plasma to crosslink the surface thereof, and then washing the exposed article with water to remove uncrosslinked water-soluble high polymer or water-soluble surfactant. The membrane can be used for such substance separation methods as reverse osmosis, ultrafiltration and the like.

    摘要翻译: 通过浇铸包含水不溶性高分子聚合物和水溶性高分子的混合物,水不溶性高分子和水溶性表面活性剂的混合物或水溶性高分子的混合物, 不溶性高分子聚合物,水溶性高聚物和水溶性表面活性剂以形成成型制品,将由此形成的成型制品暴露于等离子体以使其表面交联,然后用水洗涤暴露的制品以除去未交联的水溶性聚合物, 可溶性高分子或水溶性表面活性剂。 该膜可用于反渗透,超滤等物质分离方法。

    Method for manufacturing phosphorylated cellulose ester membranes for
use in the separation or concentration of substances
    9.
    发明授权
    Method for manufacturing phosphorylated cellulose ester membranes for use in the separation or concentration of substances 失效
    用于分离或浓缩物质的磷酸化纤维素酯膜的制备方法

    公开(公告)号:US4083904A

    公开(公告)日:1978-04-11

    申请号:US661646

    申请日:1976-02-26

    IPC分类号: B29D27/04

    摘要: A novel phosphorylated cellulose ester membrane containing 0.1 to 10% of phosphorus and having a selective permeability. This permselective phosphorylated cellulose ester membrane consists essentially of a phosphorylated cellulose ester obtained by reacting a phosphorylating reagent such as phosphorus oxychloride with a lower aliphatic acid ester of cellulose, which has a reactive hydroxyl group, in an organic solvent, and then hydrolyzing the resulting ester. The membrane can be used widely in separating materials by processes such as reverse osmosis, ultrafiltration, dialysis, electrodialysis, and the like.

    摘要翻译: 一种新型磷酸化纤维素酯膜,含有0.1〜10%的磷,具有选择性渗透性。 该选择性选择性磷酸化纤维素酯膜基本上由磷酸化纤维素酯组成,所述磷酸化纤维素酯通过磷酸化试剂如磷酰氯与具有反应性羟基的纤维素的低级脂肪酸酯在有机溶剂中反应,然后水解所得酯 。 该膜可以广泛用于通过反渗透,超滤,透析,电渗析等方法分离材料。