公开(公告)号：US20050231815A1

公开(公告)日：2005-10-20

申请号：US11098400

申请日：2005-04-05

申请人： Taro Miyauchi ,  Kazuya Ohkawa ,  Tatsufumi Shiba ,  Tomizo Matsuyama

发明人： Taro Miyauchi ,  Kazuya Ohkawa ,  Tatsufumi Shiba ,  Tomizo Matsuyama

IPC分类号： C03C3/062 ,  C03C3/064 ,  C03C3/078 ,  C03C3/089 ,  C03C3/091 ,  C03C3/093 ,  C03C3/095 ,  C03C3/097 ,  C03C21/00 ,  G02B3/00 ,  G02B9/00

CPC分类号： C03C21/002 ,  C03C3/062 ,  C03C3/064 ,  C03C3/078 ,  C03C3/089 ,  C03C3/093 ,  G02B3/0087

摘要： A mother glass composition for graded index lenses, comprising the following glass components in mol %: 40≦SiO2≦65, 1≦TiO2≦10, 0≦MgO≦22, 2≦Li2O≦18, 2≦Na2O≦20, 6≦Li2O+Na2O≦38, and from 0.1 to 15 mol % of any two or more of CaO, SrO and BaO, a graded index lens using the mother glass composition, a manufacturing method of the graded index lens, and an optical product and an optical instrument using the graded index lens, are provided.

摘要翻译： 用于渐变折射率透镜的母玻璃组合物，其包含以摩尔％计的以下玻璃成分：40 <= NIO 2 = 65，1 <= TIO 2 <= 10， 0 <= MgO <= 22，2 <= LI <2> O <= 18，2 <= NA <2> O <= 20,6 <= LI < O + Na 2 O <= 38，以及0.1〜15摩尔％的CaO，SrO和BaO中的任意两种以上，使用母玻璃组合物的渐变折射率透镜， 提供了分级折射率透镜的制造方法，以及使用了渐变折射率透镜的光学产品和光学仪器。

公开(公告)号：US07576021B2

公开(公告)日：2009-08-18

申请号：US11098400

申请日：2005-04-05

申请人： Taro Miyauchi ,  Kazuya Ohkawa ,  Tatsufumi Shiba ,  Tomizou Matsuyama

发明人： Taro Miyauchi ,  Kazuya Ohkawa ,  Tatsufumi Shiba ,  Tomizou Matsuyama

IPC分类号： C03C3/078

CPC分类号： C03C21/002 ,  C03C3/062 ,  C03C3/064 ,  C03C3/078 ,  C03C3/089 ,  C03C3/093 ,  G02B3/0087

摘要： A mother glass composition for graded index lenses, comprising the following glass components in mol %: 40≦SiO2≦65, 1≦TiO2≦10, 0≦MgO≦22, 2≦Li2O≦18, 2≦Na2O ≦20, 6≦Li2O+Na2O≦38, and from 0.1 to 15 mol % of any two or more of CaO, SrO and BaO, a graded index lens using the mother glass composition, a manufacturing method of the graded index lens, and an optical product and an optical instrument using the graded index lens, are provided.

摘要翻译： 用于渐变折射率透镜的母玻璃组合物，其包含以摩尔％计的以下玻璃成分：40 <= SiO 2 = 65,1 / TiO 2 <= 10,0 <= MgO <= 22,2 <= Li 2 O <= 18， 2 <= Na 2 O <= 20,6 <= Li 2 O + Na 2 O <= 38和0.1〜15摩尔％的CaO，SrO和BaO中的任意两种以上，使用母玻璃组合物的渐变折射率透镜，制造方法 的渐变折射率透镜，以及使用渐变折射率透镜的光学产品和光学仪器。

公开(公告)号：US07858546B2

公开(公告)日：2010-12-28

申请号：US12070157

申请日：2008-02-15

申请人： Taro Miyauchi ,  Tatsufumi Shiba

发明人： Taro Miyauchi ,  Tatsufumi Shiba

IPC分类号： C03C3/078 ,  C03C3/089 ,  C03C3/091 ,  C03C3/093 ,  C03C21/00 ,  C03C15/00

CPC分类号： G02B3/0087 ,  C03C3/062 ,  C03C3/078

摘要： The present invention provides a mother glass composition for gradient-index lens, from which a lead-free Li-based gradient-index lens that is excellent in weather resistance, in particular weather resistance in the presence of water, can be manufactured. The mother glass composition includes the following components, indicated by mol %: 40≦SiO2≦65; 1≦TiO2≦10; 0.1≦MgO≦22; 0.15≦ZnO≦15; 2≦Li2O≦18; 2≦Na2O≦20; 0≦B2O3≦20; 0≦Al2O3≦10; 0≦K2O≦3; 0≦Cs2≦O≦3; 0≦Y2O3≦5; 0≦ZrO2≦2; 0≦Nb2O5≦5; 0≦In2O3≦5; 0≦La2O3≦5; and 0≦Ta2O5≦5. The mother glass composition further includes at least two oxides selected from CaO, SrO, and BaO each in a range of 0.1 mol % to 15 mol %. The total of MgO+ZnO is greater than or equal to 2 mol %. The molar ratio of ZnO/(MgO+ZnO) is in a range of 0.07 to 0.93. The total of Li2O+Na2O is in a range of 6 mol % to 38 mol %. The total of Y2O3+ZrO2+Nb2O5+In2O3+La2O3+Ta2O5 is in a range of 0 mol % to 11 mol %.

摘要翻译： 本发明提供了一种用于梯度折射率透镜的母玻璃组合物，可以制造耐候性优异的无铅Li基梯度折射率透镜，特别是在水的存在下的耐候性。 母玻璃组合物包含以摩尔％表示的以下组分：40＆lt; NlE; SiO 2和nEE; 65; 1＆nlE; TiO2＆nlE; 10; 0.1＆nlE; MgO＆nlE; 22; 0.15＆nlE; ZnO＆nlE; 15; 2＆nlE; Li2O＆nlE; 18; 2＆nlE; Na 2 O＆nlE; 20; 0＆nlE; B2O3＆nlE; 20; 0＆nlE; Al2O3＆nlE; 10; 0＆nlE; K2O＆nlE; 3; 0＆nlE; Cs2＆nlE; O＆nlE; 3; 0＆nlE; Y2O3＆nlE; 5; 0＆nlE; ZrO2＆nlE; 2; 0＆nlE; Nb2O5＆nlE; 5; 0＆nlE; In2O3＆nlE; 5; 0＆nlE; La2O3＆nlE; 5; 和0＆nlE; Ta2O5＆nlE; 5。 母玻璃组合物还包含选自CaO，SrO和BaO中的至少两种氧化物，其分别为0.1mol％至15mol％的范围。 MgO + ZnO的总和大于或等于2摩尔％。 ZnO /（MgO + ZnO）的摩尔比在0.07〜0.93的范围内。 Li2O + Na2O的总量为6mol％〜38mol％。 Y2O3 + ZrO2 + Nb2O5 + In2O3 + La2O3 + Ta2O5的合计为0mol％〜11mol％。

公开(公告)号：US20080213495A1

公开(公告)日：2008-09-04

申请号：US12070157

申请日：2008-02-15

申请人： Taro Miyauchi ,  Tatsufumi Shiba

发明人： Taro Miyauchi ,  Tatsufumi Shiba

IPC分类号： B05D1/18 ,  C03C3/078 ,  C03C3/085 ,  C03C3/087 ,  C03C3/093 ,  C03C3/089 ,  C03C3/095 ,  C03C3/097

CPC分类号： G02B3/0087 ,  C03C3/062 ,  C03C3/078

摘要： The present invention provides a mother glass composition for gradient-index lens, from which a lead-free Li-based gradient-index lens that is excellent in weather resistance, in particular weather resistance in the presence of water, can be manufactured. The mother glass composition includes the following components, indicated by mol %: 40≦SiO2≦65; 1≦TiO2≦10; 0.1≦MgO≦22; 0.15≦ZnO≦15; 2≦Li2O≦18; 2≦Na2O≦20; 0≦B2O3≦20; 0≦Al2O3≦10; 0≦K2O≦3; 0≦Cs2≦O≦3; 0≦Y2O3≦5; 0≦ZrO2≦2; 0≦Nb2O5≦5; 0≦In2O3≦5; 0≦La2O3≦5; and 0≦Ta2O5≦5. The mother glass composition further includes at least two oxides selected from CaO, SrO, and BaO each in a range of 0.1 mol % to 15 mol %. The total of MgO+ZnO is greater than or equal to 2 mol %. The molar ratio of ZnO/(MgO+ZnO) is in a range of 0.07 to 0.93. The total of Li2O+Na2O is in a range of 6 mol % to 38 mol %. The total of Y2O3+ZrO2+Nb2O5+In2O3+La2O3+Ta2O5 is in a range of 0 mol % to 11 mol %.