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公开(公告)号：US4520095A
公开(公告)日：1985-05-28
申请号：US538798
申请日：1983-10-04
摘要： A photographic light-sensitive element having at least one light-sensitive silver halide layer and a dye image forming non-diffusible material which, upon a redox reaction under alkaline conditions releases a diffusible cyan dye or precursor thereof wherein said material is ##STR1## wherein Car represents a carrier component having at least on Ball group as a part thereof which alone or together with other such groups in said Car renders said compound non-diffusible during development in alkaline processing solution, said Car being capable of releasing from said compound a diffusible dye or the precursor thereof as the result of a redox reaction under alkaline conditions:R represents a hydrogen atom or an alkyl group having from 1 to 3 carbon atoms;R.sup.1 is ##STR2## wherein R.sup.2 and R.sup.3 are independently selected from a hydrogen atom, or an alkyl, a cycloalkyl or an aryl group having from 1 to 30 carbon atoms, and R.sup.2 and R.sup.3 may be linked through an oxygen atom or nitrogen atom to each other to form a 5-membered or 6-membered ring;X is hydroxyl group or a salt thereof or a group which can be hydrolyzed to a hydroxyl group;Y is ##STR3## wherein R.sup.4 is an acyl, a hydroxyalkyl, an alkoxyalkyl, an alkoxyalkyleneoxyalkyl, a carboxyalkyl, carboxyphenyl, a carboxyalkyl-phenyl, a hydroxyalkyl-phenyl, or an alkoxyphenyl group;R.sup.5 is a hydrogen atom or an alkyl or an aryl having from 1 to 8 carbon atoms, or the same group as defined in R.sup.4, provided the sum of the number of carbon atoms contained in R.sup.4 and R.sup.5 is not more than 10;m is an integer of 0 or 1; andJ.sup.1 and J.sup.2 are independently selected from divalent groups --R.sup.6 --(0).sub.n --R.sub.p.sup.7 -- wherein R.sup.6 and R.sup.7 are independently selected from alkylene having from 1 to 8 carbon atoms, phenylene and phenylene substituted by a chlorine atom, methoxy group, or a methyl group;n is an integer of 0 or 1; p is 1 when n is 1, and p is 1 or 2 when n is 0, provided that when p is 1, the sum of the number of the carbon atoms contained in R.sup.6 and R.sup.7 is not more than 13.
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公开(公告)号：US4460682A
公开(公告)日：1984-07-17
申请号：US449849
申请日：1982-12-15
CPC分类号： G03C8/10 , G03C7/305 , Y10S430/137 , Y10S430/156
摘要： A novel silver halide photographic element which contains a nondiffusible complex capable of releasing a diffusible, photographically useful material is disclosed.Said nondiffusible complex becomes active for ligand exchange upon reduction under alkalin conditions to release a diffusible, photographically useful material, said complex being represented by the following formula: ##STR1## wherein La is a quadridentate ligand group; Lb is a didentate ligand group; BALL is a ballast group; PHOTO is a photographically useful material group; Y is a counter ion; and r is the number of counter ions necessary for neutralizing the electric charge on the CO(III) complex.
摘要翻译： 公开了一种新颖的卤化银照相元件，其含有能够释放可扩散的照相用材料的非扩散性复合物。 所述非扩散性复合物在碱性条件下还原时对于配体交换有活性，以释放可扩散的照相有用材料，所述复合物由下式表示：其中La是四齿配体基团; Lb是二齿配体基团; BALL是一个镇流器组; 照片是照片上有用的材料组; Y是抗衡离子; 并且r是中和CO（III）络合物上的电荷所必需的抗衡离子的数目。
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3.发明授权Photographic element with reducible metal complex that releases photographically useful compound 失效具有释放摄影有用化合物的可还原金属络合物的摄影元件
公开(公告)号：US4421846A
公开(公告)日：1983-12-20
申请号：US333901
申请日：1981-12-23
申请人： Satoru Ikeuchi , Masaru Kanbe , Jiro Takahashi , Ryuichiro Kobayashi , Shunji Suginaka , Noboru Mizukura
发明人： Satoru Ikeuchi , Masaru Kanbe , Jiro Takahashi , Ryuichiro Kobayashi , Shunji Suginaka , Noboru Mizukura
CPC分类号： G03C8/10 , G03C7/305 , Y10S430/137
摘要： A photographic element containing a nondiffusible metal complex capable of releasing a diffusible photographically useful group. The complex contains at least one poly-dentate ligand which contains the photographically useful group. The complex may be activated when reduced under alkaline conditions to release the photographically useful group.
摘要翻译： 含有能够释放漫射照相用组的非扩散金属络合物的照相元件。 复合物含有至少一种含有照相用组的多齿配体。 当在碱性条件下还原时，复合物可以被激活以释放摄影有用的组。
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公开(公告)号：US4407941A
公开(公告)日：1983-10-04
申请号：US355464
申请日：1982-03-08
IPC分类号： C07D231/52 , C07D491/056 , G03C1/06 , G03C5/30 , G03C8/02 , G03C8/08 , G03C8/36 , G03C1/40 , G03C5/54
CPC分类号： C07D231/52 , G03C5/30 , G03C8/02 , G03C8/08 , G03C8/36 , Y10S430/16
摘要： A photographic element comprising a support provided thereon with at least one light-sensitive silver halide emulsion layer containing a nondiffusible compound which receives at least one electron in an alkaline condition to release a photographically useful material and a nondiffusible electron donor or a precursor thereof having the following formula (I) or (II): ##STR1## wherein R.sup.1 represents hydrogen, an alkyl, an aryl or a heterocyclic group, R.sup.2 represents hydrogen, an alkyl, an aryl, a heterocyclic, an amino, a carbamide, a sulfonamide, a sulfamoyl, a carbamoyl or a ureido group, R.sup.3 and R.sup.4 each is hydrogen, --COR.sup.5, --SO.sub.2 R.sup.6 or --CSR.sup.7 wherein R.sup.5 and R.sup.6 each is a substituted or unsubstituted, respectively, alkyl, alkenyl, aryl, heterocyclic, alkylamino, alkyloxy, aryloxy, alkylthio, arylthio, alkyloxycarbonyl or aryloxycarbonyl group, and R.sup.7 is a substituted or unsubstituted alkyllamino or arylamino group, said R.sup.4 being allowed to form a ring together with said R.sup.1.
摘要翻译： 一种照相元件，包括其上提供有至少一种感光卤化银乳剂层的载体，所述至少一种感光卤化银乳剂层含有不可扩散的化合物，其在碱性条件下接收至少一种电子以释放具有照相作用的材料，以及不可溶的电子给体或其前体， 下式（I）或（II）：其中R 1表示氢，烷基，芳基或杂环基，R 2表示氢，烷基，芳基，杂环，氨基，脲，磺酰胺， 氨基甲酰基或脲基，R 3和R 4各自为氢，-COR 5，-SO 2 R 6或-CSR 7，其中R 5和R 6各自为取代或未取代的烷基，烯基，芳基，杂环，烷基氨基，烷氧基， 芳氧基，烷硫基，芳硫基，烷氧基羰基或芳氧基羰基，R7是取代或未取代的烷基氨基或芳基氨基，所述R4与所述R 1一起形成环。
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公开(公告)号：US4499181A
公开(公告)日：1985-02-12
申请号：US500406
申请日：1983-06-02
IPC分类号： G03C8/14 , C07D209/08 , C07D209/40 , C07D403/04 , C09B29/28 , C09B29/50 , G03C7/26 , G03C7/30 , G03C7/305 , G03C8/10 , G03C5/54 , G03C1/10 , G03C1/40 , G03C1/42
CPC分类号： C07D403/04 , C07D209/08 , C07D209/40 , C09B29/28 , C09B29/366 , G03C7/30511 , G03C8/10 , Y10S430/158 , Y10S430/159 , Y10S430/16
摘要： A photographic recording material. On a support are provided a silver emulsion halide layer and a photographic layer. The photographic layer contains an indole compound represented by the general formula (I): ##STR1## wherein PUG represents a photographically useful group, Ball represents an organic group which has enough molecular weight and/or disposition to render the compound non-diffusible during processing of the photographic recording material with an alkaline medium and wherein the Ball contains a nitrogen atom which is directly attached to the 5th or 6th position of the indole ring. R.sub.1 represents a halogen atom or a monovalent organic group. R.sub.2 represents a hydrogen atom or a low molecular group attached, through a carbon atom, to the 2nd position of the indole ring. "m" represents an integer of zero to 3.
摘要翻译： 摄影材料。 在载体上提供银乳剂卤化物层和照相层。 照相层包含由通式（I）表示的吲哚化合物：其中PUG表示摄影有用的基团，Ball表示具有足够分子量和/或配置以在处理期间使化合物不扩散的有机基团 的照相记录材料，并且其中Ball包含直接连接到吲哚环的第5或第6位置的氮原子。 R1表示卤素原子或一价有机基团。 R2表示通过碳原子连接到吲哚环的第二位置的氢原子或低分子基团。 “m”表示0〜3的整数。
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6.发明授权
公开(公告)号：US4631251A
公开(公告)日：1986-12-23
申请号：US771000
申请日：1985-08-30
CPC分类号： G03C1/49854 , G03C8/4033
摘要： In a heat-developable color photo-sensitive material comprising a support bearing thereon a photographic component layer containing at least a photo-sensitive silver halide, a reducing agent, a binder and a dye-providing material; said heat-developable photo-sensitive material characterized in that at least one of said dye-providing materials is a polymer having a repetition unit being derived from a monomer Formula [I] below: ##STR1## wherein , Q represents an ethylene unsaturated group or a group having an ethylene unsaturated group; Z represents a group of atoms required for forming a nitrogen-containing heterocyclic residual group in which a polymerizable ethylene unsaturated bonding may also be incorporated into the heterocyclic ring, together with a nitrogen atom; R.sub.1 represents an alkyl, aryl, alkylamino, anilino, acylamino or ureido group; Ar represents an aryl group or a heterocyclic residual group; and n is an integer of zero or one.
摘要翻译： 在一种可热显影的彩色感光材料中，其中包含至少含有感光卤化银，还原剂，粘合剂和染料提供材料的照相组分层的支持体; 所述可热显影的感光材料的特征在于，所述提供染料的材料中的至少一种是具有源自下列单体式[I]的重复单元的聚合物：其中Q表示 乙烯不饱和基团或具有乙烯不饱和基团的基团; Z表示形成含氮杂环残基所需的原子团，其中也可以将杂化环中的可聚合的乙烯不饱和键与氮原子一起引入; R 1表示烷基，芳基，烷基氨基，苯胺基，酰氨基或脲基; Ar表示芳基或杂环残基; n为0或1的整数。
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