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1.发明授权
公开(公告)号：US4663396A
公开(公告)日：1987-05-05
申请号：US702434
申请日：1985-02-19
CPC分类号： C08F8/38
摘要： A method for producing chlorosulfonated polyethylene with controlled addition of the amount of sulfur added to the polyethylene. Polyethylene dissolved in halogenated hydrocarbon is reacted with sulfuryl chloride in the presence of a catalyst of a radical generating agent in a binary phase system. The addition amount of sulfur is controlled by adding an amine compound to the reaction in an amount within the range where the following formula is applicable:log.sub.10 S=.alpha..multidot.log.sub.10 A+.beta. (1)whereinS: reaction yield (%) of sulfur of sulfuryl chlorideA: concentration (mol/liter) of amine compound in halogenated hydrocarbon solvent.alpha.,.beta.: constants such that1.0
摘要翻译： 一种生产氯磺化聚乙烯的方法，可控制加入加到聚乙烯中的硫的量。 在二元相体系中，在自由基生成剂的催化剂存在下，将溶解在卤代烃中的聚乙烯与磺酰氯反应。 硫的添加量通过向反应中加入胺化合物控制，其量可以在以下公式适用的范围内：log 10 S =αxlog 10 A +β（1）其中S：磺酰氯A的硫的反应收率（％） ：胺化合物在卤代烃溶剂中的浓度（mol /升）α，β：常数，使得1.0 <3.0 4.0 <α.12.0。
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公开(公告)号：US4871815A
公开(公告)日：1989-10-03
申请号：US305261
申请日：1989-02-02
CPC分类号： C08F8/38
摘要： An excellent cold-proof chlorosulfonated polyethylene and a method of manufacturing the same featured in that a polyethylene is once dissolved in a solvent by heating up them over a dissolution temperature of the polyethylene, then cooled and thus obtained homogeneous solution of the polyethylene is allowed to react with a sulfuryl chloride in the presence of a catalyst of a radical generating agent in the dissolution temperature region of the polyethylene or in a temperature region lower than the former one.
摘要翻译： 优异的耐冷氯磺化聚乙烯及其制造方法的特征在于，聚乙烯在聚乙烯的溶解温度下通过加热溶解而一次溶解在溶剂中，然后冷却，得到均匀的聚乙烯溶液 在聚乙烯的溶解温度区域或低于前者的温度区域中，在自由基产生剂的催化剂存在下，与磺酰氯反应。
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3.发明授权
公开(公告)号：US4544709A
公开(公告)日：1985-10-01
申请号：US578325
申请日：1984-02-13
CPC分类号： C08F8/38
摘要： Chlorosulfonated polyethylene having excellent properties as elastomer is produced by dissolving polyethylene in a mixed solvent of carbon tetrachloride and a halogenated aromatic compound such as, for example, chlorobenzene and reacting polyethylene with chlorine and sulfuryl chloride or with sulfuryl chloride.
摘要翻译： 通过将聚乙烯溶解在四氯化碳和卤代芳族化合物如氯苯和聚乙烯与氯和磺酰氯反应或与磺酰氯反应的混合溶剂中来制备作为弹性体具有优异性能的氯磺化聚乙烯。
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公开(公告)号：US4234704A
公开(公告)日：1980-11-18
申请号：US48382
申请日：1979-06-14
申请人： Yasuhiro Sakanaka , Mamoru Narui
发明人： Yasuhiro Sakanaka , Mamoru Narui
CPC分类号： C08F36/18 , C08L11/00 , C08L11/02 , C08L2205/02
摘要： A chloroprene polymer composition comprises a benzene soluble chloroprene polymer (A) and a gel chloroprene polymer (B) at a ratio ranging from 20:1 to 1:1, wherein the benzene soluble chloroprene polymer (A) is obtained by an aqueous emulsion polymerization of chloroprene or a mixture of chloroprene and a comonomer with 0.05 to 5.0 wt. % of a molecular weight regulator in which the polymerization in the presence of effective amount of the molecular weight regulator is carried out to reach a conversion of 40 to 60% and then, 40 to 70 wt. % of the molecular weight regulator incorporated at the initiation of the polymerization is incorporated and the polymerization is continued to give a conversion of higher than 80% and the gel chloroprene polymer (B) is obtained by an aqueous emulsion polymerization of chloroprene or a mixture of chloroprene and a polyfunctional monomer.
摘要翻译： 氯丁二烯聚合物组合物包含比例为20:1至1:1的苯可溶性氯丁二烯聚合物（A）和凝胶氯丁二烯聚合物（B），其中苯可溶性氯丁二烯聚合物（A）通过水乳液聚合 的氯丁二烯或氯丁二烯与共聚单体的混合物，其含量为0.05〜5.0wt。 ％的分子量调节剂，其中在有效量的分子量调节剂存在下进行聚合以达到40至60％，然后40至70重量％的转化率。 加入引入聚合的分子量调节剂的％，并继续聚合，得到高于80％的转化率，凝胶氯丁二烯聚合物（B）通过氯丁二烯的水乳液聚合或 氯丁二烯和多官能单体。
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