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    Chlorosulfonated propylene/olefin elastomers
    3.
    发明申请
    Chlorosulfonated propylene/olefin elastomers 失效
    氯磺化丙烯/烯烃弹性体

    公开(公告)号：US20080249249A1

    公开(公告)日：2008-10-09

    申请号：US12075525

    申请日：2008-03-12

    申请人： Avinash C. Gadkari

    发明人： Avinash C. Gadkari

    IPC分类号： C08L23/34

    CPC分类号： C08L23/34 ,  C08F8/38 ,  C08L2205/02 ,  C08F210/16 ,  C08L2666/04 ,  C08L2666/06

    摘要： Chlorosulfonated propylene/olefin elastomers containing 0.5-55 weight percent chlorine and 0.15 to 5 weight percent sulfur are prepared from metallocene catalyzed propylene/olefin copolymer base resins having a ratio of Mw/Mn less than 3.5 and a copolymerized propylene content of 70-98 weight percent.

    摘要翻译： 含有0.5-55重量％氯和0.15-5重量％硫的氯磺化丙烯/烯烃弹性体由Mw / Mn小于3.5的比例和70-98重量份的共聚丙烯含量的茂金属催化的丙烯/烯烃共聚物基础树脂 百分。

    Chlorinated and chlorosulfonated elastic substantially linear olefin polymers
    4.
    发明授权
    Chlorinated and chlorosulfonated elastic substantially linear olefin polymers 失效
    氯化氯磺化弹性基本线性烯烃聚合物

    公开(公告)号：US5565521A

    公开(公告)日：1996-10-15

    申请号：US450432

    申请日：1995-05-25

    申请人： Lawrence J. Effler, Jr. ,  George D. Wright ,  Mark T. Berard

    发明人： Lawrence J. Effler, Jr. ,  George D. Wright ,  Mark T. Berard

    IPC分类号： C08L27/06 ,  C08F8/20 ,  C08F8/38 ,  C08F10/02 ,  C08L23/28 ,  C08L27/24 ,  C08L67/00 ,  C08F8/00

    CPC分类号： C08F8/38 ,  C08F8/20 ,  C08L23/28

    摘要： Chlorinated and chlorosulfonated polyethylenes are produced by chlorinating substantially linear olefin polymers having a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63, a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation: M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63, a critical shear rate at onset of gross melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and M.sub.w /M.sub.n and at least about 0.01 long chain branches/1000 carbons and a molecular weight distribution from about 1.5 to about 2.5 and their method of manufacture are disclosed. The chlorosulfonated polyethylenes are produced by treating the chlorinated polyethylenes with a mixture of gaseous chlorine and sulfur dioxide.

    摘要翻译： 氯化和氯磺化的聚乙烯通过氯化基本上线性的烯烃聚合物来制备，所述烯烃聚合物的熔体流动比为I 10 / I 2≥5.63，分子量分布，Mw / Mn，由下式定义：Mw / Mn < I2）-4.63，总熔体断裂开始时的临界剪切速率比具有大约相同的I2和Mw / Mn的直链烯烃聚合物的表面熔融断裂开始时的临界剪切速率至少高50％，并且至少 约0.01个长支链/ 1000个碳，分子量分布约为1.5至约2.5，并且其制造方法被公开。 通过用氯气和二氧化硫的混合物处理氯化聚乙烯来制备氯磺化的聚乙烯。

    Process for the preparation of chlorinated polyolefin and chlorosulfonated polyolefin
    5.
    发明授权
    Process for the preparation of chlorinated polyolefin and chlorosulfonated polyolefin 失效

    公开(公告)号：US5378766A

    公开(公告)日：1995-01-03

    申请号：US156904

    申请日：1993-11-24

    申请人： Nobuyuki Ito ,  Katsushige Okayama ,  Toshinori Karasuda ,  Yasumichi Miyagawa

    发明人： Nobuyuki Ito ,  Katsushige Okayama ,  Toshinori Karasuda ,  Yasumichi Miyagawa

    IPC分类号： C08F8/20 ,  C08F8/38 ,  C08F8/00

    CPC分类号： C08F8/20 ,  C08F8/38

    摘要： A novel process for the preparation of a chlorinated polyolefin having excellent low temperature characteristics and brightness is provided which comprises allowing a polyolefin dissolved or suspended in a solvent to undergo chlorination reaction with chlorine gas or chlorinated sulfuryl in the presence of a radical initiator as a catalyst, characterized in that as said solvent there is used 1,1,2-trichloroethane and the temperature is controlled to 90.degree. C. or lower at the process for removing hydrogen chloride and/or sulfur dioxide by-produced during the reaction from the reaction system. A further process for the preparation of a chlorosulfonated polyolefin having excellent low temperature characteristics and brightness is provided which comprises allowing a polyolefin dissolved or suspended in a solvent to undergo chlorosulfonation reaction with chlorine and sulfur dioxide, chlorine and sulfuryl chloride, sulfuryl chloride alone, chlorine, sulfur dioxide and sulfuryl chloride or sulfuryl chloride and sulfur dioxide in the presence of a radical initiator as a catalyst, characterized in that as said solvent there is used 1,1,2-trichloroethane and the temperature is controlled to 90.degree. C. or lower at the process for removing hydrogen chloride and/or sulfur dioxide by-produced during the reaction from the reaction system.

    Method of making chlorosulfonated polyethylene
    6.
    发明授权
    Method of making chlorosulfonated polyethylene 失效
    制备氯磺化聚乙烯的方法

    公开(公告)号：US4871815A

    公开(公告)日：1989-10-03

    申请号：US305261

    申请日：1989-02-02

    申请人： Tatsushi Nakagawa ,  Mamoru Narui ,  Yasuhiro Sakanaka

    发明人： Tatsushi Nakagawa ,  Mamoru Narui ,  Yasuhiro Sakanaka

    IPC分类号： C08F8/00 ,  C08F8/38

    CPC分类号： C08F8/38

    摘要： An excellent cold-proof chlorosulfonated polyethylene and a method of manufacturing the same featured in that a polyethylene is once dissolved in a solvent by heating up them over a dissolution temperature of the polyethylene, then cooled and thus obtained homogeneous solution of the polyethylene is allowed to react with a sulfuryl chloride in the presence of a catalyst of a radical generating agent in the dissolution temperature region of the polyethylene or in a temperature region lower than the former one.

    摘要翻译： 优异的耐冷氯磺化聚乙烯及其制造方法的特征在于，聚乙烯在聚乙烯的溶解温度下通过加热溶解而一次溶解在溶剂中，然后冷却，得到均匀的聚乙烯溶液 在聚乙烯的溶解温度区域或低于前者的温度区域中，在自由基产生剂的催化剂存在下，与磺酰氯反应。