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公开(公告)号：US5391690A
公开(公告)日：1995-02-21
申请号：US70733
申请日：1993-06-02
申请人： Tatsuya Kanno , Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Yoshihiro Iguchi , Takaaki Kuwana , Toshihiro Matsumoto
发明人： Tatsuya Kanno , Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Yoshihiro Iguchi , Takaaki Kuwana , Toshihiro Matsumoto
CPC分类号： C08G64/307 , C08G63/64 , C08K5/524
摘要： A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
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2.发明授权Process for producing (co)polycarbonate with transesterification catalyst and compound 失效用酯交换催化剂和化合物生产（共）聚碳酸酯的方法
公开(公告)号：US5278279A
公开(公告)日：1994-01-11
申请号：US940310
申请日：1992-08-31
申请人： Tatsuya Kanno , Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Yoshihiro Iguchi , Takaaki Kuwana , Toshihiro Matsumoto
发明人： Tatsuya Kanno , Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Yoshihiro Iguchi , Takaaki Kuwana , Toshihiro Matsumoto
CPC分类号： C08G64/307 , C08G63/64 , C08K5/524
摘要： A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
摘要翻译： 通过使二羟基化合物与二羧酸的二酯和/或二碳酸的二酯反应，生成具有高分子量和（色），热稳定性和机械性能的（共）聚碳酸酯或（共）聚酯碳酸酯的方法 存在酯交换催化剂，其中至少部分反应过程在指定的有机磷化合物的存在下进行，或在指定的有机磷化合物和受阻酚化合物的存在下进行。 包含（共）聚碳酸酯和/或（共）聚酯碳酸酯和特定的有机磷化合物或特定有机磷化合物的（共）聚碳酸酯或（共）聚酯 - 碳酸酯组合物，其具有优异的色调，热稳定性和机械性能 磷化合物和受阻酚化合物。
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3.发明授权Process for producing (co)polycarbonate and (co)polycarbonate composition 失效制备（共）聚碳酸酯和（共）聚碳酸酯组合物的方法
公开(公告)号：US5387628A
公开(公告)日：1995-02-07
申请号：US119368
申请日：1993-09-09
申请人： Tatsuya Kanno , Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Yoshihiro Iguchi , Takaaki Kuwana , Toshihiro Matsumoto
发明人： Tatsuya Kanno , Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Yoshihiro Iguchi , Takaaki Kuwana , Toshihiro Matsumoto
IPC分类号： C08G63/64 , C08G64/00 , C08G64/20 , C08G64/30 , C08K3/00 , C08K5/51 , C08K5/524 , C08L69/00 , C08K5/15
CPC分类号： C08G64/307 , C08G63/64 , C08K5/524
摘要： A process for producing a (co)polycarbonate or a (co)polyestercarbonate having a high molecular weight and excellent hue, heat stability and mechanical properties by reacting a dihydroxyl compound with a diester of carbonic acid and/or a diester of dicarbonic acid in the presence of a transesterification catalyst, wherein at least part of the reaction process is conducted in the presence of a specified organic phosphorus compound, or, in the presence of a specified organic phosphorus compound and a hindered phenol compound. A (co)polycarbonate or (co)polyester-carbonate composition having excellent hue, heat stability and mechanical properties, comprising a (co)polycarbonate and/or a (co)polyestercarbonate and, a specified organic phosphorus compound, or, a specified organic phosphorus compound and a hindered phenol compound.
摘要翻译： 通过使二羟基化合物与二羧酸的二酯和/或二碳酸的二酯反应，生成具有高分子量和（色），热稳定性和机械性能的（共）聚碳酸酯或（共）聚酯碳酸酯的方法 存在酯交换催化剂，其中至少部分反应过程在指定的有机磷化合物的存在下进行，或在指定的有机磷化合物和受阻酚化合物的存在下进行。 包含（共）聚碳酸酯和/或（共）聚酯碳酸酯和特定的有机磷化合物或特定有机磷化合物的（共）聚碳酸酯或（共）聚酯 - 碳酸酯组合物，其具有优异的色调，热稳定性和机械性能 磷化合物和受阻酚化合物。
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公开(公告)号：US5489665A
公开(公告)日：1996-02-06
申请号：US327329
申请日：1994-10-21
申请人： Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Tatsuya Kanno , Takaaki Kuwana , Yoshimichi Okano
发明人： Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Tatsuya Kanno , Takaaki Kuwana , Yoshimichi Okano
CPC分类号： C08G64/307
摘要： A polycarbonate is produced by transesterification from a dihydroxy compound such as 2,2-bis(4-hydroxyphenyl)propane and a diester of carbonic acid such as bisphenyl carbonate in the presence of a substance which contains iron in an amount of 50% by weight or less and contacts the reactants. Alternatively, a polycarbonate is produced by transesterification from a dihydroxy compound and a diester of carbonic acid in a reactor made of stainless steel and treated by electropolishing or acid pickling or buffed on a surface part thereof which contacts the reactants. As the transesterification catalyst, (a) a nitrogen-containing, electron-donating compound and (b) a nitrogen-containing, electron-donating compound and an alkali metal compound or an alkaline earth metal compound are preferably used.
摘要翻译： 聚碳酸酯通过二羟基化合物如2,2-双（4-羟基苯基）丙烷和碳酸二酯如碳酸二苯酯的二酯化合物在含有50重量％的铁的物质的存在下进行酯交换 或更少并接触反应物。 或者，通过在由不锈钢制成的反应器中由二羟基化合物和碳酸二酯进行酯交换并通过电解抛光或酸洗或在其与反应物接触的表面部分上抛光来制备聚碳酸酯。 作为酯交换催化剂，优选使用（a）含氮供电子化合物和（b）含氮的给电子化合物和碱金属化合物或碱土金属化合物。
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公开(公告)号：US5432250A
公开(公告)日：1995-07-11
申请号：US978209
申请日：1992-11-18
CPC分类号： C08G64/30 , C08G64/307
摘要： In a process for producing a polycarbonate by subjecting a dihydroxy compound and a diester of carbonic acid to melt polycondensation through transesterification, after a polycarbonate prepolymer is prepared in the first-stage reaction, polycondensation is conducted as the second-stage reaction at a residence time in the range of from 15 to less than 60 min or through the use of at least one paddle-type self-cleaning twin-screw extruder.This process enables a colorless, transparent polycarbonate having a high molecular weight to be produced at a high efficiency on an industrial scale.
摘要翻译： 在通过使二羟基化合物和碳酸二酯通过酯交换进行熔融缩聚来制造聚碳酸酯的方法中，在第一阶段反应中制备聚碳酸酯预聚物之后，在停留时间进行缩聚作为第二阶段反应 在15至小于60分钟的范围内，或通过使用至少一个桨式自清洁双螺杆挤出机。 该方法能够以高效率在工业规模上生产具有高分子量的无色透明聚碳酸酯。
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公开(公告)号：US5548041A
公开(公告)日：1996-08-20
申请号：US521071
申请日：1995-08-29
申请人： Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Tatsuya Kanno , Takaaki Kuwana , Yoshimichi Okano
发明人： Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Tatsuya Kanno , Takaaki Kuwana , Yoshimichi Okano
CPC分类号： C08G64/307
摘要： A polycarbonate is produced by transesterification from a dihydroxy compound such as 2,2-bis(4-hydroxyphenyl)propane and a diester of carbonic acid such as bisphenyl carbonate in a reactor made of stainless steel and treated by electropolishing or acid pickling or buffed on a surface part thereof which contacts the reactants. As the transesterification catalyst, (a) a nitrogen-containing, electron-donating compound and (b) a nitrogen-containing, electron-donating compound and an alkali metal compound or an alkaline earth metal compound are preferably used.
摘要翻译： 聚碳酸酯通过在不锈钢制反应器中由二羟基化合物如2,2-双（4-羟基苯基）丙烷和碳酸二碳酸酯如碳酸二苯酯进行酯交换反应生产，并通过电解抛光或酸洗处理或抛光 其表面部分与反应物接触。 作为酯交换催化剂，优选使用（a）含氮供电子化合物和（b）含氮的给电子化合物和碱金属化合物或碱土金属化合物。
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公开(公告)号：US5468836A
公开(公告)日：1995-11-21
申请号：US119065
申请日：1993-09-13
申请人： Yoshimichi Okano , Tatsuya Kanno , Tsutomu Yamato , Yasuhiro Oshino , Michiyo Tanigawa , Takaaki Kuwana , Yutaka Fukuda
发明人： Yoshimichi Okano , Tatsuya Kanno , Tsutomu Yamato , Yasuhiro Oshino , Michiyo Tanigawa , Takaaki Kuwana , Yutaka Fukuda
CPC分类号： C08G64/14 , C08G64/30 , C08G64/307
摘要： A polycarbonate which is not discolored and is substantially free from chlorine ions causative of discoloration, has a branching parameter G of 0.1 to 1.0 and, terminal hydroxyl groups of 20 mole % or below based on all the terminal groups of the polycarbonate, and/or, a chlorine ion concentration in the polycarbonate of 10 ppm or below, and/or, a total of an alkali metal ion concentration and an alkaline earth metal ion concentration in the polycarbonate of 1 ppm or below. A process for preparing the above polycarbonate by the melt transesterification process which comprises using a nitrogenous basic compound (a), and/or, a compound (b) containing an element selected from the group consisting of Groups IIb, IVb and Vb of the periodic table; or, a nitrogenous basic compound (a), and, a compound (c) containing an element selected from the group consisting of alkali metals and alkaline earth metals, as a transesterification catalyst.
摘要翻译： PCT No.PCT / JP93 / 00104 Sec。 371日期1993年9月13日 102（e）1993年9月13日PCT 1993年1月28日PCT PCT。 公开号WO93 / 15129 日期为1993年8月5日。不变色并且基本上不含有由于变色引起的氯离子的聚碳酸酯，具有0.1至1.0的支化参数G和基于所有末端基团的20摩尔％或更低的末端羟基 的聚碳酸酯和/或聚碳酸酯中的氯离子浓度为10ppm以下，和/或聚碳酸酯中的碱金属离子浓度和碱土金属离子浓度的总和为1ppm以下。 一种通过熔融酯交换方法制备上述聚碳酸酯的方法，其包括使用含氮碱性化合物（a）和/或含有选自周期表中第IIb，IVb和Vb族的元素的化合物（b） 表; 或含氮碱性化合物（a）和含有选自碱金属和碱土金属的元素的化合物（c）作为酯交换催化剂。
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公开(公告)号：US5610262A
公开(公告)日：1997-03-11
申请号：US418510
申请日：1995-04-07
CPC分类号： C08G64/30 , C08G64/307
摘要： In a process for producing a polycarbonate by subjecting a dihydroxy compound and a diester of carbonic acid to melt polycondensation through transesterification, after a polycarbonate prepolymer is prepared in the first-stage reaction, polycondensation is conducted as the second-stage reaction in a residence time in the range of from 15 to less than 60 min or through the use of at least one paddle-type self-cleaning twin-screw extruderThis process enables a colorless, transparent polycarbonate having a high molecular weight to be produced at a high efficiency on an industrial scale.
摘要翻译： 在通过使二羟基化合物和碳酸二酯通过酯交换进行熔融缩聚来制造聚碳酸酯的方法中，在第一阶段反应中制备聚碳酸酯预聚物之后，在停留时间作为第二阶段反应进行缩聚 在15至小于60分钟的范围内，或通过使用至少一个桨式自清洁双螺杆挤出机。该方法使得能够以高效率生产具有高分子量的无色透明聚碳酸酯 工业规模。
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公开(公告)号：US5434227A
公开(公告)日：1995-07-18
申请号：US851806
申请日：1992-03-16
申请人： Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Tatsuya Kanno , Takaaki Kuwana , Yoshimichi Okano
发明人： Tsutomu Yamato , Yasuhiro Oshino , Yutaka Fukuda , Tatsuya Kanno , Takaaki Kuwana , Yoshimichi Okano
CPC分类号： C08G64/307
摘要： A polycarbonate is produced by transesterification from a dihydroxy compound such as 2,2-bis(4-hydroxyphenyl)propane and a diester of carbonic acid such as bisphenyl carbonate in the presence of a substance containing iron in an amount of 50% by weight or less to contact the reactants. Also, a polycarbonate is produced by transesterification from a dihydroxy compound and a diester of carbonic acid in a reactor made of stainless steel and treated by electropolishing or acid pickling or buffed on a surface part thereof to contact the reactants. As the transesterification catalyst, (a) a nitrogen-containing, electron-donating compound and (b) a nitrogen-containing, electron-donating compound and an alkali metal compound or an alkaline earth metal compound are preferably used.
摘要翻译： 聚碳酸酯通过二羟基化合物如2,2-双（4-羟基苯基）丙烷和碳酸二酯如碳酸二苯酯在含铁量为50重量％的物质存在下进行酯交换反应制备，或 少接触反应物。 另外，在由不锈钢制成的反应器中由二羟基化合物和碳酸二酯进行酯交换反应生成聚碳酸酯，并通过电解抛光或酸洗或在其表面部分进行抛光以与反应物接触。 作为酯交换催化剂，优选使用（a）含氮供电子化合物和（b）含氮的给电子化合物和碱金属化合物或碱土金属化合物。
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公开(公告)号：US5418314A
公开(公告)日：1995-05-23
申请号：US946335
申请日：1992-11-02
CPC分类号： C08G64/307 , C08G64/30
摘要： In a process for producing a polycarbonate by subjecting a dihydroxy compound and a diester of carbonic acid to melt polycondensation through transesterification, after a polycarbonate prepolymer is prepared in the first-stage reaction, polycondensation is conducted as the second-stage reaction at a residence time in the range of from 15 to less than 60 min or through the use of at least one paddle-type self-cleaning twin-screw extruder.This process enables a colorless, transparent polycarbonate having a high molecular weight to be produced at a high efficiency on an industrial scale.
摘要翻译： PCT No.PCT / JP92 / 00231 Sec。 371日期：1992年11月2日 102（e）日期1992年11月2日PCT提交1992年2月28日PCT公布。 出版物WO92 / 16577 日本10月1日，1992。在通过使二羟基化合物和碳酸二酯通过酯交换进行熔融缩聚制备聚碳酸酯的方法中，在第一步反应中制备聚碳酸酯预聚物之后，进行缩聚作为第二步 在15至60分钟范围内的停留时间或通过使用至少一个桨式自清洁双螺杆挤出机的阶段反应。 该方法能够以高效率在工业规模上生产具有高分子量的无色透明聚碳酸酯。
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