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    Additives for property modification in ceramic composite bodies
    1.
    发明授权
    Additives for property modification in ceramic composite bodies 失效
    陶瓷复合材料的改性添加剂

    公开(公告)号：US5403790A

    公开(公告)日：1995-04-04

    申请号：US960407

    申请日：1993-01-11

    申请人： Terry D. Claar ,  Gerhard H. Schiroky ,  Kevin P. Pochopien ,  Vilupanur A. Ravi ,  James C. Wang ,  Ratnesh K. Dwivedi

    发明人： Terry D. Claar ,  Gerhard H. Schiroky ,  Kevin P. Pochopien ,  Vilupanur A. Ravi ,  James C. Wang ,  Ratnesh K. Dwivedi

    IPC分类号： C04B35/56 ,  C04B35/58 ,  C04B35/65 ,  C04B41/50 ,  C04B41/87 ,  C22C29/00 ,  C22C29/06 ,  B22F3/26

    CPC分类号： C04B35/563 ,  C04B35/5622 ,  C04B35/58078 ,  C04B35/65 ,  C04B35/652 ,  C04B41/5062 ,  C04B41/87 ,  C22C29/00 ,  C22C29/06 ,  C22C29/062

    摘要： This invention relates generally to a novel method of manufacturing a composite body. More particularly, the present invention relates to a method for modifying the resultant properties of a composite body, by, for example, minimizing the amount of porosity present in the composite body. Moreover, additives, whether used alone or in combination, (1) can be admixed with the permeable mass, (2) can be mixed or alloyed with the parent metal, (3) can be placed at an interface between the parent metal and the preform or mass of filler material, (4) or any combination of the aforementioned methods, to modify properties of the resultant composite body. Particularly, additives such as VC, NbC, WC, W.sub.2 B.sub.5, TaC, ZrC, ZrB.sub.2, SiB.sub.6, SiC, MgO, Al.sub.2 O.sub.3, ZrO.sub.2, CeO.sub.2, Y.sub.2 O.sub.3, La.sub.2 O.sub.3, MgAl.sub.2 O.sub.4, HfO.sub.2, ZrSiO.sub.4, Yb.sub.2 O.sub.3 and Mo.sub.2 B.sub.5 can be combined with the permeable mass in an amount of about 5-50 percent by weight, prior to reactively infiltrating the permeable mass. Moreover, an additive may also include substantially pure elemental metals (e.g., Nb, Ti, Hf, V, Ta, Cr, Mo, Al, Cr, Si, Co and W) which may be provided by any of the methods discussed above herein.

    摘要翻译： PCT No.PCT / US91 / 04951 Sec。 371日期：1993年1月11日 102（e）日期1993年1月11日PCT PCT 1991年7月12日PCT公布。 公开号WO92 / 00933 日本1992年1月23日。本发明一般涉及一种制造复合体的新方法。 更具体地说，本发明涉及通过例如最小化复合体中存在的孔隙率来改变复合体的合成性能的方法。 此外，无论单独使用还是组合使用，添加剂（1）均可与可渗透物质混合，（2）可与母体金属混合或合金化，（3）可置于母体金属与母体金属之间的界面处 填充材料的预制件或质量，（4）或上述方法的任何组合，以改变所得复合材料的性能。 特别地，可以将诸如VC，NbC，WC，W2B5，TaC，ZrC，ZrB2，SiB6，SiC，MgO，Al2O3，ZrO2，CeO2，Y2O3，La2O3，MgAl2O4，HfO2，ZrSiO4，Yb2O3和Mo2B5的添加剂与渗透性 在反应性渗透可渗透物质之前，其质量为约5-50重量％。 此外，添加剂还可以包括可以通过上述任何方法提供的基本上纯的元素金属（例如，Nb，Ti，Hf，V，Ta，Cr，Mo，Al，Cr，Si，Co和W） 。

    Method of producing and modifying the properties of ceramic composite bodies
    2.
    发明授权
    Method of producing and modifying the properties of ceramic composite bodies 失效
    制造和改性陶瓷复合材料性能的方法

    公开(公告)号：US5066622A

    公开(公告)日：1991-11-19

    申请号：US554100

    申请日：1990-07-13

    申请人： Terry D. Claar ,  Gerhard H. Schiroky ,  Kevin P. Pochopien

    发明人： Terry D. Claar ,  Gerhard H. Schiroky ,  Kevin P. Pochopien

    IPC分类号： C04B35/65 ,  C04B41/50 ,  C04B41/87 ,  C22C29/00 ,  C22C29/06

    CPC分类号： C04B41/87 ,  C04B35/652 ,  C04B41/5062 ,  C22C29/00 ,  C22C29/06 ,  C22C29/062

    摘要： This invention relates generally to a novel method of manufacturing a composite body. More particularly, the present invention relates to a method for modifying the resultant properties of a composite body, by, for example, minimizing the amount of porosity present in the composite body. Additives such as TaC, ZrC, ZrB.sub.2, VC, NbC, WC, W.sub.2 B.sub.5 and/or MoO.sub.2 B.sub.5 can be combined with a boron carbide material which is thereafter reactively infiltrated by a parent metal. The composite body comprises one or more boron-containing compounds (e.g., a boride or a boride and a carbide) which is made by the reactive infiltration of molten parent metal into the boron carbide mass. Particular emphasis is placed upon modifying the properties of a ZrB.sub.2 -ZrC-Zr composite body. However, the methods disclosed in the application are believed to be generic to a number of parent metals and preform materials.

    摘要翻译： 本发明一般涉及复合体的新型制造方法。 更具体地说，本发明涉及通过例如最小化复合体中存在的孔隙率来改变复合体的合成性能的方法。 添加剂如TaC，ZrC，ZrB2，VC，NbC，WC，W2B5和/或MoO2B5可与碳化硼材料组合，然后碳化硼材料随后由母体金属反应渗透。 复合体包含一种或多种通过熔融母体金属反应性浸渗到碳化硼块中制成的含硼化合物（例如硼化物或硼化物和碳化物）。 特别强调改性ZrB2-ZrC-Zr复合体的性能。 然而，本申请中公开的方法被认为是对许多母体金属和预成型材料的通用。

    Method of modifying ceramic composite bodies by a post-treatment process and articles produced thereby
    4.
    发明授权
    Method of modifying ceramic composite bodies by a post-treatment process and articles produced thereby 失效
    通过后处理工艺改变陶瓷复合体的方法和由此制备的制品

    公开(公告)号：US5162098A

    公开(公告)日：1992-11-10

    申请号：US700349

    申请日：1991-05-07

    申请人： Terry D. Claar ,  Gerhard H. Schiroky ,  William B. Johnson

    发明人： Terry D. Claar ,  Gerhard H. Schiroky ,  William B. Johnson

    IPC分类号： C04B35/65 ,  C04B41/50 ,  C04B41/87 ,  C22C29/00

    CPC分类号： C04B41/5062 ,  C04B35/652 ,  C04B41/87 ,  C22C29/00

    摘要： This invention relates generally to a novel method of manufacturing a composite body, such as a ZrB.sub.2 -ZrC-Zr (optional) composite body, by utilizing a post-treatment process and to the novel products made thereby. More particularly, the invention relates to a method of modifying a composite body comprising one or more boron-containing compounds (e.g., a boride or a boride and a carbide) which has been made by the reactive infiltration of a molten parent metal into a bed or mass containing boron carbide, and optionally one or more inert fillers, to form the body.

    摘要翻译： 本发明一般涉及通过利用后处理工艺制造复合体，例如ZrB 2 -ZrC-Zr（任选的）复合体的新方法和由此制备的新产品。 更具体地说，本发明涉及一种修饰包括一种或多种含硼化合物（例如，硼化物或硼化物和碳化物）的复合体的方法，其通过将熔融母体金属的反应性渗入床形成 或含有碳化硼的物质，以及任选的一种或多种惰性填料以形成体。

    Method of producing ceramic composite bodies
    6.
    发明授权
    Method of producing ceramic composite bodies 失效
    生产陶瓷复合体的方法

    公开(公告)号：US5372178A

    公开(公告)日：1994-12-13

    申请号：US823009

    申请日：1992-01-15

    申请人： Terry D. Claar ,  Gerhard H. Schiroky ,  Donald P. Ripa ,  William B. Johnson

    发明人： Terry D. Claar ,  Gerhard H. Schiroky ,  Donald P. Ripa ,  William B. Johnson

    IPC分类号： C04B35/56 ,  C04B35/58 ,  C04B35/65 ,  B22D19/00

    CPC分类号： C04B35/65 ,  C04B35/56 ,  C04B35/5622 ,  C04B35/5805 ,  C04B35/58071 ,  C04B35/58078 ,  C04B35/652

    摘要： This invention relates generally to a novel method of preparing self-supporting bodies, and novel products made thereby. In its more specific aspects, this invention relates to a method for producing self-supporting bodies comprising one or more boron-containing compounds (e.g., a boride or a boride and a carbide, etc.) by reactive infiltration of molten parent metal into a preform comprising boron carbide or a boron donor material combined with a carbon donor material and, optionally, one or more inert fillers, to form the body. Specifically, a boron carbide material or combination of a boron donor material and a carbon donor material, and in either case, optionally, one or more inert fillers, are sedimentation cast, spray coated, tapped, slip cast, pressed, etc., onto or into a body and into a particular desired shape.

    摘要翻译： 本发明一般涉及一种制备自支撑体的新方法，以及由此制成的新颖产品。 在其更具体的方面，本发明涉及一种通过将熔融母体金属反应性渗透到一种或多种含硼化合物（例如硼化物或硼化物和碳化物等）中来制备包含一种或多种含硼化合物的自支撑体的方法， 包括碳化硼或与碳供体材料组合的硼供体材料和任选的一种或多种惰性填料以形成所述体。 具体地说，碳化硼材料或硼供体材料和碳供体材料的组合，并且在任一情况下，任选地一种或多种惰性填料是沉淀铸造，喷涂，轻敲，滑模，压制等，到 或进入身体并且变成特定期望的形状。

    Method of producing ceramic composite bodies
    7.
    发明授权
    Method of producing ceramic composite bodies 失效
    生产陶瓷复合体的方法

    公开(公告)号：US5299621A

    公开(公告)日：1994-04-05

    申请号：US762163

    申请日：1991-09-19

    申请人： Terry D. Claar ,  Gerhard H. Schiroky ,  Donald P. Ripa ,  William B. Johnson

    发明人： Terry D. Claar ,  Gerhard H. Schiroky ,  Donald P. Ripa ,  William B. Johnson

    IPC分类号： C04B35/563 ,  C04B35/56 ,  C04B35/58 ,  C04B35/65 ,  C22C1/10 ,  B22D19/00

    CPC分类号： C04B35/563 ,  C04B35/5622 ,  C04B35/58071 ,  C04B35/58078 ,  C04B35/65 ,  C04B35/652

    摘要： This invention relates generally to a novel method of preparing self-supporting bodies, and novel products made thereby. In its more specific aspects, this invention relates to a method for producing self-supporting bodies comprising one or more boron-containing compounds, e.g., a boride or a boride and a carbide, by reactive infiltration of molten parent metal into a preform comprising boron carbide or a boron donor material combined with a carbon donor material and, optionally, one or more inert fillers, to form the body. Specifically, a boron carbide material or combination of a boron donor material and a carbon donor material, and in either case, optionally, one or more inert fillers, are sedimentation cast, slip cast or pressed onto or into a body and into a particular desired shape.

    摘要翻译： 本发明一般涉及一种制备自支撑体的新方法，以及由此制成的新颖产品。 在其更具体的方面，本发明涉及通过将熔融母体金属反应性渗入包含硼的预成型体中来生产包含一种或多种含硼化合物（例如硼化物或硼化物）和碳化物的自支撑体的方法 碳化物或硼供体材料与碳供体材料和任选的一种或多种惰性填料组合以形成体。 具体地说，碳化硼材料或硼供体材料和碳供体材料的组合，并且在任一种情况下，任选地，一种或多种惰性填料中，是沉淀铸造，滑模浇注或压入或进入体内并进入特定期望的 形状。

    Method of modifying ceramic composite bodies by a post-treatment process and articles produced thereby
    8.
    发明授权
    Method of modifying ceramic composite bodies by a post-treatment process and articles produced thereby 失效
    通过后处理工艺改变陶瓷复合体的方法和由此制备的制品

    公开(公告)号：US5298051A

    公开(公告)日：1994-03-29

    申请号：US973449

    申请日：1992-11-09

    申请人： Terry D. Claar ,  Gerhard H. Schiroky ,  William B. Johnson

    发明人： Terry D. Claar ,  Gerhard H. Schiroky ,  William B. Johnson

    IPC分类号： C04B35/65 ,  C04B41/50 ,  C04B41/87 ,  C22C29/00 ,  C22C29/04

    CPC分类号： C04B41/009 ,  C04B35/652 ,  C04B41/5062 ,  C04B41/87 ,  C22C29/00

    摘要： This invention relates generally to a novel method of manufacturing a composite body, such as a ZrB.sub.2 -ZrC-Zr (optional) composite body, by utilizing a post-treatment process and to the novel products made thereby. More particularly, the invention relates to a method of modifying a composite body comprising one or more boron-containing compounds (e.g., a boride or a boride and a carbide) which has been made by the reactive infiltration of a molten parent metal into a bed or mass containing boron carbide, and optionally one or more inert fillers, to form the body.

    摘要翻译： 本发明一般涉及通过利用后处理工艺制造复合体，例如ZrB 2 -ZrC-Zr（任选的）复合体的新方法和由此制备的新颖产品。 更具体地说，本发明涉及一种修饰包括一种或多种含硼化合物（例如，硼化物或硼化物和碳化物）的复合体的方法，其通过将熔融母体金属的反应性渗入床形成 或含有碳化硼的物质，以及任选的一种或多种惰性填料以形成体。