摘要:
A clad glass composition that is excellent in devitrification resistance and that prevents the whole mother glass rod from devitrifying by preventing a core glass composition from devitrifying in forming a mother glass rod using a concentric crucible drawing method, is provided. The clad glass composition forms a clad of a mother glass rod for a gradient-index rod lens having a core/clad structure.
摘要:
A gradient-index rod lens is provided that is excellent in yield. The gradient-index rod lens has a core/clad structure and is obtained by providing a mother glass rod, which includes a core glass mother composition and a clad glass mother composition, with a refractive index distribution through ion exchange. The clad and the core each contains an alkali metal oxide but are substantially free from lead. The clad and the core each contains an alkali metal oxide and has a basic composition including components other than the alkali metal oxide, but they are different from each other in the basic composition. The clad glass mother composition has a higher thermal expansion coefficient and glass-transition temperature than those of the core glass mother composition. The difference of the thermal expansion coefficient between the clad glass mother composition and the core glass mother composition is larger than 2×10−7/° C. but smaller than 20×10−7/° C.
摘要:
The present invention provides a clad glass composition that is excellent in devitrification resistance and that prevents the whole mother glass rod from devitrifying by preventing a core glass composition from devitrifying in forming a mother glass rod using a concentric crucible drawing method. The clad glass composition forms a clad of a mother glass rod for a gradient-index rod lens having a core/clad structure. The clad glass composition includes the following components, indicated by mol %: 45 to 65% SiO2; 0.5 to 10% TiO2; 0 to 15% B2O3; 0 to 7% Al2O3; 0.1 to 10% Bi2O3; 0 to 5% Li2O; 5 to 30% Na2O; 0 to 10% K2O; 0 to 15% MgO; 0 to 10% CaO; 0 to 10% SrO; 0.5 to 10% BaO; 0 to 10% Cs2O; 0 to 10% ZnO; 0 to 7% Y2O3; 0 to 7% Nb2O5; 0 to 7% In2O3; 0 to 7% La2O3; 0 to 10% Ta2O5; 0 to 7% ZrO2; and 0 to 1% Sb2O3, where the total of Li2O+Na2O+K2O is in the range of 5 to 35 mol %, the total of MgO+CaO+SrO+BaO is in the range of 2 to 20 mol %, the total of Li2O+Na2O+K2O+MgO+CaO+SrO+BaO is in the range of 7 to 50 mol %, and the total of Cs2O+ZnO+Y2O3+Nb2O5+In2O3+La2O3+ZrO2+Ta2O5 is in the range of 0 to 15 mol %. In the clad glass composition, at least two molar ratios selected from the group consisting of: MgO/(MgO+CaO+SrO+BaO); CaO/(MgO+CaO+SrO+BaO); SrO/(MgO+CaO+SrO+BaO); and BaO/(MgO+CaO+SrO+BaO) are at least 0.1. The clad glass composition is substantially free from lead and has a refractive index in the range of 1.56 to 1.68.
摘要翻译:本发明提供一种耐失透性优异的包覆玻璃组合物,通过使用同心坩埚拉伸法,通过防止芯玻璃组合物在形成母玻璃棒时失透而防止整个母玻璃棒脱光。 复合玻璃组合物形成具有芯/包层结构的梯度折射率棒状透镜的母玻璃棒的包层。 复合玻璃组合物包含以摩尔%表示的以下组分:45-65%SiO 2; 0.5〜10%TiO2; 0〜15%B2O3; 0〜7%Al2O3; 0.1〜10%Bi2O3; 0〜5%Li2O; 5〜30%Na2O; 0〜10%K2O; 0〜15%MgO; 0〜10%CaO; 0〜10%SrO; 0.5〜10%BaO; 0〜10%Cs2O; 0〜10%的ZnO; 0〜7%Y2O3; 0〜7%Nb2O5; 0〜7%In2O3; 0〜7%La2O3; 0〜10%Ta2O5; 0〜7%ZrO2; 和0〜1%的Sb2O3,其中Li2O + Na2O + K2O的合计为5〜35摩尔%,MgO + CaO + SrO + BaO的合计为2〜20摩尔%,总计 的Li 2 O + Na 2 O + K 2 O + MgO + CaO + SrO + BaO在7〜50摩尔%的范围内,Cs 2 O + ZnO + Y 2 O 3 + Nb 2 O 5 + In 2 O 3 + La 2 O 3 + ZrO 2 + Ta 2 O 5的合计为0 至15摩尔%。 在包覆玻璃组合物中,选自MgO /(MgO + CaO + SrO + BaO)中的至少两种摩尔比。 CaO /(MgO + CaO + SrO + BaO); SrO /(MgO + CaO + SrO + BaO); 和BaO /(MgO + CaO + SrO + BaO)为0.1以上。 包覆玻璃组合物基本上不含铅,折射率在1.56-1.68的范围内。
摘要:
A gradient-index rod lens is provided that is excellent in yield. The gradient-index rod lens has a core/clad structure and is obtained by providing a mother glass rod, which includes a core glass mother composition and a clad glass mother composition, with a refractive index distribution through ion exchange. The clad and the core each contains an alkali metal oxide but are substantially free from lead. The clad and the core each contains an alkali metal oxide and has a basic composition including components other than the alkali metal oxide, but they are different from each other in the basic composition. The clad glass mother composition has a higher thermal expansion coefficient and glass-transition temperature than those of the core glass mother composition. The difference of the thermal expansion coefficient between the clad glass mother composition and the core glass mother composition is larger than 2×10−7/° C. but smaller than 20×10−7/° C.
摘要:
The present invention provides a clad glass composition that is excellent in devitrification resistance and that prevents the whole mother glass rod from devitrifying by preventing a core glass composition from devitrifying in forming a mother glass rod using a concentric crucible drawing method. The clad glass composition forms a clad of a mother glass rod for a gradient-index rod lens having a core/clad structure. The clad glass composition includes the following components, indicated by mol %: 45 to 65% SiO2; 0.5 to 10% TiO2; 0 to 15% B2O3; 0 to 7% Al2O3; 0.1 to 10% Bi2O3; 0 to 5% Li2O; 5 to 30% Na2O; 0 to 10% K2O; 0 to 15% MgO; 0 to 10% CaO; 0 to 10% SrO; 0.5 to 10% BaO; 0 to 10% Cs2O; 0 to 10% ZnO; 0 to 7% Y2O3; 0 to 7% Nb2O5; 0 to 7% In2O3; 0 to 7% La2O3; 0 to 10% Ta2O5; 0 to 7% ZrO2; and 0 to 1% Sb2O3, where the total of Li2O+Na2O+K2O is in the range of 5 to 35 mol %, the total of MgO+CaO+SrO+BaO is in the range of 2 to 20 mol %, the total of Li2O+Na2O+K2O+MgO+CaO+SrO+BaO is in the range of 7 to 50 mol %, and the total of Cs2O+ZnO+Y2O3+Nb2O5+In2O3+La2O3+ZrO2+Ta2O5 is in the range of 0 to 15 mol %. In the clad glass composition, at least two molar ratios selected from the group consisting of MgO/(MgO+CaO+SrO+BaO); CaO/(MgO+CaO+SrO+BaO); SrO/(MgO+CaO+SrO+BaO); and BaO/(MgO+CaO+SrO+BaO) are at least 0.1. The clad glass composition is substantially free from lead and has a refractive index in the range of 1.56 to 1.68.
摘要:
It is an object of the present invention to provide a clad glass composition for graded-index rod lens for covering, during manufacturing, a preform glass composition lens of a graded-index rod lens that does not include PbO, in which the composition substantially does not include PbO, and expressed in mol % includes SiO2: 45 to 65, Na2O: 3 to 30, K2O: 0 to 10, MgO: 0 to 15, BaO: 0 to 20, where Na2O+K2O: 3 to 35 and MgO+BaO: 0 to 25, and furthermore includes B2O3: 0 to 15, ZnO: 0 to 10, TiO2: 0 to 10, Y2O3: 0 to 7, ZrO2: 0 to 7, Nb2O5: 0 to 7, In2O3: 0 to 7, La2O3: 0 to 7, Ta2O5: 0 to 10, where B2O3+ZnO+TiO2+Y2O3+ZrO2+Nb2O5+In2O3+La2to 20, and a content of at least one of TiO2 and La2O3 is substantially 0 mol %.
摘要翻译:本发明的目的是提供一种用于渐变折射率棒状透镜的包覆玻璃组合物,用于在制造期间覆盖不包括PbO的渐变折射率棒状透镜的预成型玻璃组合物透镜,其中组成基本上 不包括PbO,以摩尔%表示,包括SiO 2:45至65,Na 2 O 3至30,K 2 O: 0〜10,MgO:0〜15,BaO:0〜20,其中Na 2 O + K 2 O 3〜35,MgO + BaO:0〜25 ,还包括B 2 O 3:0至15,ZnO:0至10,TiO 2:0至10,Y :0至7,在<2> O> 3中:0至7,La 2 O 3:0 至7,Ta 2 O 5:0至10,其中B 2 O 3 + ZnO + TiO 2 2 + 2 + 2 + 3 + 3 + 2 + 2 + 2 + 2 + 5 + 2&lt; 2&gt;&lt; 3&lt; 3&gt; +&lt; 2&gt; 2&gt;〜20, TiO 2和La 2 O 3 3中的至少一个基本上为0mol%。