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公开(公告)号：US5275750A
公开(公告)日：1994-01-04
申请号：US916963
申请日：1992-07-20
IPC分类号： C08F290/06 , G02F1/15 , H01B1/12 , H01G9/02 , H01G9/025 , H01M10/052 , H01M10/0565
CPC分类号： H01G9/025 , C08F290/062 , H01B1/122 , H01M10/052 , H01M10/0565 , G02F1/1525
摘要： A method of manufacturing a solid polymer electrolyte which comprises polymerizing an ester polymethoxyoxyalkylene, a diester polyoxyalkylene, an oxycompound having a double bond, and an inorganic salt, and the solid polymer electrolyte thus obtained. The electrolyte is suitable for application in electrochemical devices such as primary or secondary battery, condenser or electrochromic display.
摘要翻译： 一种固体高分子电解质的制造方法，其特征在于，聚酯化聚甲氧基氧化烯，二酯聚氧化烯，具有双键的氧化合物和无机盐，以及由此得到的固体高分子电解质。 电解质适用于电化学装置，如一次或二次电池，冷凝器或电致变色显示。
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公开(公告)号：US5324599A
公开(公告)日：1994-06-28
申请号：US826000
申请日：1992-01-27
申请人： Noboru Oyama , Katsuhiko Naoi , Tadashi Sotomura , Hiroshi Uemachi , Yoshiko Sato , Teruhisa Kanbara , Kenichi Takeyama
发明人： Noboru Oyama , Katsuhiko Naoi , Tadashi Sotomura , Hiroshi Uemachi , Yoshiko Sato , Teruhisa Kanbara , Kenichi Takeyama
IPC分类号： H01M4/60 , H01M10/052 , H01M10/0565 , H01M6/18
CPC分类号： H01M10/052 , H01M10/0565 , H01M4/60
摘要： The present invention provides an electrode material comprising a combination of a compound having a disulfide group and a conductive polymer, or a conductive polymer having a disulfide group, wherein an S-S bond of the disulfide group is cleaved by the electrolytic reduction to form a sulfur-metal ion bond or a sulfur-proton bond, and the sulfur-metal ion bond or the sulfur-proton bond re-forms an S-S bond by the electrolytic oxidation. The present invention also provides a lithium rechargeable battery comprising a cathode, a solid electrolyte, and an anode, wherein the cathode is made of a composition containing as its main components lithium thiolate having a sulfur-lithium ion bond capable of forming a disulfide bond by the electrolytic oxidation and a .pi. electron conjugated conductive polymer; or a composition containing as its main component a .pi. electron conjugated conductive polymer having a sulfur-lithium ion bond capable of forming a disulfide bond by electrolytic oxidation; the solid electrolyte is a composition containing a salt containing lithium, or a polymer containing the salt; and the anode is made of a composition containing as its main components aluminium or an alloy containing aluminium, and carbon.
摘要翻译： 本发明提供了包含具有二硫化物的化合物和导电性聚合物的组合的电极材料或具有二硫键的导电性聚合物，其中通过电解还原将二硫键的SS键切割，形成硫 - 金属离子键或硫质子键，硫金属离子键或硫质子键通过电解氧化而重新形成SS键。 本发明还提供一种锂可再充电电池，其包含阴极，固体电解质和阳极，其中阴极由含有能够形成二硫键的硫 - 锂离子键的硫醇锂的组成的组合物制成 电解氧化和π电子共轭导电聚合物; 或含有通过电解氧化形成二硫键的具有硫 - 锂离子键的π电子共轭导电聚合物作为其主要成分的组合物; 固体电解质是含有含锂的盐或含有该盐的聚合物的组合物; 并且阳极由含有铝或含有铝的合金和碳的主要成分的组合物制成。
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公开(公告)号：US5348819A
公开(公告)日：1994-09-20
申请号：US55858
申请日：1993-04-30
摘要： A reversible electrode of the present invention is provided, which includes an organic sulfur aromatic compound represented by the formula R(SX).sub.y (where R is an aromatic group, S is sulfur, X is a metal atom or hydrogen, and y is an integer of 2 or more) as a component so as to utilize the reversible electrochemical oxidation-reduction of sulfur atoms of the organic sulfur aromatic compound for an electrode reaction. Moreover, according to the present invention, a method for producing the reversible electrode is provided.
摘要翻译： 提供本发明的可逆电极，其包括由式R（SX）y表示的有机硫芳族化合物（其中R是芳族基团，S是硫，X是金属原子或氢，y是 2以上的整数）作为成分，以利用有机硫磺芳族化合物的硫原子的可逆电化学氧化还原进行电极反应。 此外，根据本发明，提供了制造可逆电极的方法。
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公开(公告)号：US5413882A
公开(公告)日：1995-05-09
申请号：US950476
申请日：1992-09-24
摘要： A reversible electrode is provided comprising mainly organic disulfide compounds and having applications in such electrochemical devices as batteries, electrochromic displays, sensors, memories, etc. Large current charge/discharge is realized at room temperature with charge/discharge characteristics of excellent reversibility. Its structure is a composition combining organic disulfide compounds with disulfide bonding and conducting polymers. In other words, conducting polymers after being subjected to an electrolysis are put together with organic disulfide compounds. Thus, due to the effect of composition with conducting polymers, the oxidation/reduction reactions of organic disulfide compounds are accelerated and a reversible electrode characterized by utilization of a high energy density of organic disulfide compounds and the possibility of a large current charge/discharge is realized.
摘要翻译： 提供主要包含有机二硫化物的可逆电极，并且可用于诸如电池，电致变色显示器，传感器，存储器等的电化学装置中。在室温下实现大电流充电/放电，具有极好的可逆性的充电/放电特性。 其结构是结合有机二硫化物与二硫键和导电聚合物的组合物。 换句话说，进行电解后的导电聚合物与有机二硫化物组合在一起。 因此，由于组成与导电聚合物的作用，有机二硫化物化合物的氧化/还原反应加快，特征在于利用有机二硫化物的高能量密度和大电流充电/放电的可能性的可逆电极是 实现了
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公开(公告)号：US5370947A
公开(公告)日：1994-12-06
申请号：US56052
申请日：1993-04-30
摘要： A reversible electrode of the present invention includes, as a main component thereof, a thiourea compound represented by the following formula (I): ##STR1## (where R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently selected from the group consisting of hydrogen, halogen, a hydroxyl group, a cyano group, a carboxyl group, an amino group, an aryl group, an allyl group, an alkyl group, an alkoxy group, a group containing a mercapto group, a group containing a phenyl group, a group having a hetero ring containing O, and a group having a hetero ring containing N) or a polymer having the thiourea compound as its main polymer unit; the reversible electrode utilizing reversible electrochemical oxidation-reduction of sulfur atoms of the thiourea compound or the polymer.
摘要翻译： 本发明的可逆电极作为其主要成分，含有下述式（I）所示的硫脲化合物：从氢，卤素，羟基，氰基，羧基， 氨基，芳基，烯丙基，烷基，烷氧基，含巯基的基团，含有苯基的基团，含有O的杂环的基团和具有杂环的基团 含有N）或具有硫脲化合物作为其主要聚合物单元的聚合物; 利用硫脲化合物或聚合物的硫原子的可逆电化学氧化还原的可逆电极。
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公开(公告)号：US5388026A
公开(公告)日：1995-02-07
申请号：US171766
申请日：1993-12-22
CPC分类号： H01G9/025
摘要： An electrolyte of electrolytic capacitor comprises at least one ammonium salt and at least one polyether polyol having a skeletal structure represented by the formula: ##STR1## where, each of Rs independently represents a hydrogen atom, an optionally substituted isocyanate residue or acrylic residue which may be the same as or different from one another; m.sub.1, m.sub.2, m.sub.3, n.sub.1, n.sub.2 and n.sub.3 each represent a positive integer, and the ends of the isocyanate residues or the acrylic residues are 3-dimensionally linked.
摘要翻译： 电解电容器的电解质包含至少一种铵盐和至少一种具有由下式表示的骨架结构的聚醚多元醇：其中，各自各自独立地表示氢原子，任选取代的异氰酸酯残基或丙烯酸残基， 彼此相同或不同; m1，m2，m3，n1，n2和n3各自表示正整数，异氰酸酯残基或丙烯酸残基的末端是三维连接的。
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公开(公告)号：US5571292A
公开(公告)日：1996-11-05
申请号：US590758
申请日：1996-01-24
CPC分类号： H01M4/364 , H01M4/36 , H01M4/60 , H01M10/345 , H01M2004/028 , H01M2300/0025 , H01M4/485 , Y10T29/49115
摘要： A method is disclosed for producing a composite electrode which can be configured in a battery. The method comprises steps of (1) preparing a solution of an organic disulfide compound in 2-pyrrolidone or its derivative, (2) adding polyaniline to the solution to dissolve, thereby obtaining a homogeneous liquid, and then (3) removing at least a part of the 2-pyrrolidone or its derivative from the homogeneous liquid to obtain a solid product wherein the organic disulfide compound and the polyaniline are homogeneously mixed.
摘要翻译： 公开了一种用于制造可配置在电池中的复合电极的方法。 该方法包括以下步骤：（1）制备有机二硫化物在2-吡咯烷酮或其衍生物中的溶液，（2）将聚苯胺加入到溶液中以溶解，从而得到均匀的液体，然后（3）至少除去 来自均相液体的部分2-吡咯烷酮或其衍生物，得到固体产物，其中有机二硫化物化合物和聚苯胺均匀混合。
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公开(公告)号：US5518841A
公开(公告)日：1996-05-21
申请号：US190931
申请日：1994-02-03
CPC分类号： H01M4/364 , H01M4/36 , H01M4/60 , H01M10/345 , H01M2004/028 , H01M2300/0025 , H01M4/485 , Y10T29/49115
摘要： A composite cathode for a battery is disclosed. In addition, a method is disclosed for producing said composite cathode which can be configured in a battery. The method comprises steps or (1) preparing a solution or an organic disulfide compound in 2-pyrrolidone or its derivative, (2) adding polyaniline to the solution to dissolve, thereby obtaining a homogeneous liquid, and then (3) removing at least a part of the 2-pyrrolidone or its derivative from the homogeneous liquid to obtain a solid product wherein the organic disulfide compound and the polyaniline are homogeneously mixed.
摘要翻译： 公开了一种用于电池的复合阴极。 此外，公开了一种用于制造可配置在电池中的复合阴极的方法。 该方法包括以下步骤：（1）在2-吡咯烷酮或其衍生物中制备溶液或有机二硫化物，（2）将聚苯胺加入溶液中溶解，从而得到均匀的液体，然后（3）至少除去 来自均相液体的部分2-吡咯烷酮或其衍生物，得到固体产物，其中有机二硫化物化合物和聚苯胺均匀混合。
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公开(公告)号：US5413883A
公开(公告)日：1995-05-09
申请号：US146401
申请日：1993-11-01
CPC分类号： H01M4/60
摘要： A reversible electrochemical electrode applicable for a battery, sensor, memory or display device is made by ion-implanting a conductive solid polymer such as polyaniline with ions of alkaline or alkaline earth metal. A wide variety of selections and combinations of materials of the conductive solid polymer and ion is possible. In addition, n-type doping is possible.
摘要翻译： 用于电池，传感器，存储器或显示装置的可逆电化学电极通过离子注入诸如聚苯胺的导电固体聚合物与碱金属或碱土金属的离子来制备。 导电固体聚合物和离子的各种选择和材料的组合是可能的。 此外，可以进行n型掺杂。
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公开(公告)号：US4789610A
公开(公告)日：1988-12-06
申请号：US95146
申请日：1987-09-11
IPC分类号： H01M4/136 , H01M4/58 , H01M10/054 , H01M10/0562 , H01M6/18
CPC分类号： H01M10/0562 , H01M4/581
摘要： A solid-electrolyte secondary cell comprising a positive and a negative electrode composed of a copper chevrel compound (Cu.sub.x Mo.sub.6 S.sub.8), and copper ion conductive solid electrolyte is provided. This secondary cell is capable of charging with a current as high as about 1 mA/cm.sup.2, can stand high temperatures of up to 100.degree. C. and maintains its initial performance even after long-time charging and discharging. A cell small in voltage drop during dicharge is also provided by using a heat treated mixture of a copper chevrel compound and a copper ion conductive solid electrolyte represented by the formula K.sub.q Rb.sub.1-q Cu.sub.4 I.sub.2-p Cl.sub.3+3 (0.ltoreq.q.ltoreq.0.5, 0.25.ltoreq.p.ltoreq.1.0) for both positive and negative electrodes.
摘要翻译： 提供了由铜螯合物（CuxMo6S8）和铜离子导电性固体电解质构成的正极和负极的固体电解质二次电池。 该二次电池能够以高达约1mA / cm 2的电流充电，可以承受高达100℃的高温，并且即使在长时间充电和放电之后也保持其初始性能。 通过使用铜螯合物和由KqRb1-qCu4I2-pCl3 + 3（0≤q≤0.5）表示的铜离子导电固体电解质的热处理混合物，也提供了在二次加注期间电压降小的电池 ，0.25
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