摘要:
Thermoplastic polycarbonate/graft polymer moulding compositions containingA) 5 to 95 parts by weight of an aromatic polycarbonate,B) 1 to 50 parts by weight of at least one thermoplastic homopolymer, copolymer or terpolymer of styrene, .alpha.-methylstyrene, acrylonitrile, N-substituted maleimide or mixtures thereof,C) 1 to 50 parts by weight of at least one graft polymer ofC.1) 5 to 90 parts by weight of styrene, .alpha.-methylstyrene, acrylonitrile, N-substituted maleimide or mixtures thereof, onC.2) 95 to 10 parts by weight of a rubber with a glass transition temperature .ltoreq.0.degree. C. andD) 1 to 25 parts by weight (per 100 parts by weight A+B+C) of at least one additive selected from flame retardants, lubricants, antistatic agent, mould release agents or mixtures thereof,characterised in that the component B) is produced by bulk, solution or suspension polymerisation and has an oligomer content .ltoreq.1 wt. %, component C) is produced by emulsion polymerisation and the total oligomer content of the moulding compositions is .ltoreq.0.6 wt. %.
摘要翻译:含有A)5-95重量份的芳族聚碳酸酯的热塑性聚碳酸酯/接枝聚合物模塑组合物,B)1至50重量份的至少一种苯乙烯,α-甲基苯乙烯,丙烯腈,N-甲基苯乙烯的共聚物或三元共聚物, 取代的马来酰亚胺或其混合物,C)1至50重量份的至少一种C.1的接枝聚合物)C至5重量份的苯乙烯,α-甲基苯乙烯,丙烯腈,N-取代的马来酰亚胺或其混合物,在C .2)95至10重量份的玻璃化转变温度为0℃的橡胶和D)1至25重量份(每100重量份A + B + C)至少一种添加剂 选自阻燃剂,润滑剂,抗静电剂,脱模剂或其混合物,其特征在于组分B)通过本体,溶液或悬浮液聚合制备,并且具有低聚物含量为1重量%。 %,组分C)通过乳液聚合制备,并且模塑组合物的总低聚物含量为0.6重量%。 %。
摘要:
The present invention relates to thermoplastic graft polymer moulding compositions for high-gloss applications, which exhibit a reduced tendency of the additives to exude out of the thermoplastic composition during processing, and which exhibit reduced deposit build-up in the mould.
摘要:
Thermoplastic moulding compositions containingA. a thermoplastic polymer andB. 0.1 to 50% by weight, with respect to A, of an inorganic substance with an average particle diameter of 0.1 to 100 nm,and the use of superfine inorganic substances as defined by B for increasing the X-ray contrast of thermoplastic moulding compositions comprising A and B.
摘要:
A thermoplastic, flame-retardant moulding composition having improved mechanical properties is disclosed. The composition contains 40 to 99 parts by weight of a thermoplastic polycarbonate or polyester carbonate, 0.5 to 60 parts by weight of a graft polymer, 0 to 45 parts by weight of a thermoplastic vinyl copolymer, 0.5 to 20 parts by weight of a mixture of at least one mono- and at least one oligo-phosphorus conforming to the general formula and 0.05 to 5 parts by weight of a fluorinated polyolefine.
摘要:
Thermoplastic moulding materials containing A. 15 to 80 parts by weight of a thermoplastic polycarbonate or polyester carbonate, and B. 4 to 40 parts by weight of a graft polymer of B.1 20 to 60 weight % of one or more monomers on B.2 40 to 80 weight % of one or more graft bases having glass transition temperatures
摘要:
Thermoplastic moulding compositions comprising A) 1 to 60 parts by weight of at least one particulate graft rubber polymer of the ABS type which is produced by emulsion polymerisation, in which at least 50% of the graft rubber particles (number) have a structure detectable via transmission electron microscopy photographs in which the individual particles contain irregular cellular inclusions of resin-forming polymer and the surface of the particles has an irregular jagged structure such that 5 to 30 of such peaks are present per depicted particle, which particles differ from an idealised round particle (having a diameter d) by a diameter d+d/x, where x=3 to 15, B) 40 to 99 parts by weight of at least one particulate graft rubber polymer of the ABS type which is produced by solution or bulk polymerisation and which has the morphology which is characteristic of bulk types of ABS, and optionally C) 0 to 200 parts by weight of at least one thermoplastic, rubber-free resin.
摘要翻译:包含A)1至60重量份的至少一种由乳液聚合制备的至少一种ABS型颗粒接枝橡胶聚合物,其中至少50%的接枝橡胶颗粒(数量)具有可检测的结构 透射电子显微镜照片,其中单个颗粒含有形成树脂的聚合物的不规则细胞夹杂物,并且颗粒表面具有不规则的锯齿状结构,使得每个所述颗粒存在5至30个这样的峰,该颗粒与理想化圆 颗粒(直径d)直径d + d / x,其中x = 3至15,B)40至99重量份的由溶液或体积产生的ABS型的至少一种颗粒接枝橡胶聚合物 聚合并且其具有ABS的主体类型特征的形态,并且任选地C)0至200重量份的至少一种热塑性橡胶树脂。
摘要:
ABS polymer compositions consisting ofA) 5 to 80 parts by weight of at least one ABS polymer prepared by mass polymerization or solution polymerization, having rubber particles with an average particle diameter of from 800 to 15,000 nm and a rubber content of from 1 to 20% by weight,B) 1 to 50 parts by weight of at least one ABS polymer prepared by emulsion polymerization, having an average particle diameter of from 50 to 500 nm and a rubber content of from 20 to 80% by weight,C) 0 to 70 parts by weight of at least one thermoplastic vinyl resin prepared by radical polymerization of at least two monomer components selected from styrene, .alpha.-methylstyrene, methyl methacrylate, acrylonitrile, N-phenylmaleimide andD) 0.5 to 10 parts by weight of at least one polybutadiene prepared by emulsion polymerization, having an average particle diameter d.sub.50 in the latex form of from 80 to 500 nm and a gel content of from 10 to 95% by weight.
摘要:
The invention relates to thermoplastic molding compounds containing(1.) thermoplastic aromatic polycarbonates and/or thermoplastic aromatic polyesters,(2.) graft polymers and, optionally,(2.a) thermoplastic copolymers,which are characterized in that they additionally contain aliphatic polycarbonates having weight average molecular weights Mw (as measured by ultracentrifugation or light scattering) in the range from 15,000 to 500,000.
摘要:
A thermoplastic molding composition having improved mechanical properties is disclosed. The composition contains (A) aromatic polycarbonate and/or polyester carbonate (B) at least one graft rubber, obtained by emulsion polymerization of styrene and acrylonitrile in the presence of at least two rubber latices of type (B1) and (B2) where (B1) has a particle diameter d50 of ≦350 nm, a particle size distribution range of 30 nm to 100 nm, and a gel content of 70 wt. %, and (B2) has a particle diameter of ≧350 nm, a particle size distribution range of 50 nm to 500 nm, and a gel content of ≧70 wt. %, and the difference in the average particle diameter of B1 and B2 is ≧50 nm, (C) an optional copolymer of styrene and or acrylonitrile and for methyl methacrylate and/or N-substituted maleinimide, and optionally (D) flame retardant as well as optionally conventional additives.