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公开(公告)号：US4318974A
公开(公告)日：1982-03-09
申请号：US194484
申请日：1980-10-06
CPC分类号： G03G9/08757
摘要： Disclosed is an improved toner composition comprised of a colorant and a copolycarbonate resin, which toner has an intrinsic viscosity of from about 0.10 to about 0.6 dl/gr. (deciliters per gram) a melt flow temperature (T.sub.f) of from about 70.degree. C. to about 125.degree. C., a flash fusing energy of from about 3 J/in..sup.2 to about 8 J/in..sup.2, (Joules per inch squared), and a glass transition temperature of from about 50.degree. C. to about 65.degree. C.
摘要翻译： 公开了一种由着色剂和共聚碳酸酯树脂组成的改进的调色剂组合物，该调色剂的特性粘度为约0.10至约0.6dl / gr。 （每分钟分解）熔体流动温度（Tf）为约70℃至约125℃，闪光熔化能为约3J / in.2至约8J / in.2（焦耳 每英寸平方），玻璃化转变温度为约50℃至约65℃。
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2.发明授权
公开(公告)号：US4920023A
公开(公告)日：1990-04-24
申请号：US201657
申请日：1988-06-02
申请人： Ronald J. Koch , John F. Knapp , Robert J. Gruber
发明人： Ronald J. Koch , John F. Knapp , Robert J. Gruber
CPC分类号： G03G9/09791 , G03G9/09708 , G03G9/1138
摘要： A process for the preparation of stable developer compositions, which comprises treating coated carrier particles with metal salts, or metal salts of fatty acids, and thereafter admixing these particles with a colored toner composition containing metal salts or metal salts of fatty acids, and comprised of resin particles and colored pigment particles, and wherein the salts are present in an amount of from about 0.01 to about 1 percent by weight.
摘要翻译： 一种制备稳定的显影剂组合物的方法，其包括用金属盐或脂肪酸的金属盐处理涂覆的载体颗粒，然后将这些颗粒与含有金属盐或脂肪酸金属盐的着色调色剂组合物混合，并由 树脂颗粒和着色颜料颗粒，其中盐的含量为约0.01至约1重量％。
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3.发明授权
公开(公告)号：US4695524A
公开(公告)日：1987-09-22
申请号：US865327
申请日：1986-05-21
CPC分类号： G03G13/08 , G03G9/083 , G03G9/1139
摘要： Disclosed is a process for generating consistent high quality images comprised of (1) providing a xerographic imaging or printing apparatus; (2) adding thereto a stable two component developer composition comprised of toner composition with an average particle diameter of from about 6 to about 10 microns with resin particles, first pigment particles, second magnetite pigment particles, which are present in a greater amount than the first pigment particles, and blended flow additive particles; and carrier particles consisting of a ferrite core, or a steel core, and a coating thereover selected from the group consisting of terpolymers of styrene, methacrylate, and triethoxysilane; and polymethacrylate, which coating has incorporated therein conductive particles; (3) forming electrostatic latent images or magnetic images in the apparatus; and (4) developing the images formed.
摘要翻译： 公开了一种用于产生一致的高质量图像的方法，包括（1）提供静电复印成像或打印装置; （2）向树脂颗粒，第一颜料颗粒，第二磁铁矿颜料颗粒中以比例大于约6至约10微米的较大量存在的调色剂组合物加入稳定的双组分显影剂组合物 第一颜料颗粒和混合流动添加剂颗粒; 以及由铁氧体磁芯或钢芯组成的载体颗粒和选自苯乙烯，甲基丙烯酸酯和三乙氧基硅烷的三元共聚物的涂层; 和聚甲基丙烯酸酯，该涂层已经结合有导电颗粒; （3）在设备中形成静电潜像或磁图像; 和（4）形成形成的图像。
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公开(公告)号：US4517268A
公开(公告)日：1985-05-14
申请号：US531520
申请日：1983-09-12
申请人： Robert J. Gruber , John F. Knapp , Steven B. Bolte
发明人： Robert J. Gruber , John F. Knapp , Steven B. Bolte
CPC分类号： H01F41/16 , G03G9/08 , G03G9/083 , G03G9/0833 , G03G9/08711
摘要： Disclosed is an improved, simple, economical process for generating documents, such as personal checks, suitable for magnetic image character recognition, which process comprises generating such documents with conventional xerographic methods in a high speed electronic laser printing device, and wherein there is selected as the developer composition a magnetic toner containing from about 20 percent by weight to about 70 percent by weight of magnetite particles, and from about 30 percent by weight to about 80 percent by weight of toner resin particles of styrene copolymers, such as a styrene butadiene copolymer, a styrene n-butylmethacrylate copolymer, or polyesters, and wherein the carrier particles are comprised of ferrite cores, coated with various polymeric resinous compositions. There can also be included in the developer composition various additives such as collodial silica particles, and charge enhancing additives, and further conductive carbon black or insulating carbon black particles can be incorporated into the carrier polymeric resinous coating.
摘要翻译： 公开了一种改进的，简单的，经济的用于生成适合于磁图像字符识别的诸如个人检查的文档的过程，该方法包括在高速电子激光打印装置中用常规静电印刷方法生成这样的文档，并且其中选择为 显影剂组合物含有约20重量％至约70重量％的磁铁矿颗粒的磁性调色剂和约30重量％至约80重量％的苯乙烯共聚物如苯乙烯丁二烯共聚物的调色剂树脂颗粒 ，苯乙烯正丁基甲基丙烯酸酯共聚物或聚酯，并且其中载体颗粒由铁氧体磁芯组成，涂覆有各种聚合物树脂组合物。 还可以在显影剂组合物中包括诸如胶体二氧化硅颗粒和电荷增强添加剂的各种添加剂，并且可以在载体聚合物树脂涂料中引入另外的导电炭黑或绝缘炭黑颗粒。
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公开(公告)号：US4737434A
公开(公告)日：1988-04-12
申请号：US846668
申请日：1986-03-31
申请人： Robert J. Gruber , John F. Knapp
发明人： Robert J. Gruber , John F. Knapp
CPC分类号： G03G13/013 , G03G9/08
摘要： A process for generating consistent high quality colored images for extended periods consisting essentially of (1) providing a xerographic imaging or printing apparatus; (2) adding thereto a stable two-component developer composition comprised of first polymer particles, second polymer particles, and blended flow additive particles and carrier particles; (3) forming electrostatic latent images in the apparatus; and (4) developing the images formed wherein the developer composition retains its triboelectric properties of from about 20 to about 40 microcoulombs per gram for over 500,000 imaging cycles, subject to the provision that the second polymer particles are of a different composition than the first polymer particles.
摘要翻译： 一种用于长时间生成一致的高质量彩色图像的过程，其基本上由（1）提供静电复印成像或打印装置; （2）向其中加入由第一聚合物颗粒，第二聚合物颗粒和混合流动添加剂颗粒和载体颗粒组成的稳定的双组分显影剂组合物; （3）在设备中形成静电潜像; 和（4）显影所形成的图像，其中显影剂组合物保持其约20至约40微克/克的摩擦电性能超过500,000次成像循环，条件是第二聚合物颗粒的组成不同于第一聚合物 粒子。
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公开(公告)号：US4563086A
公开(公告)日：1986-01-07
申请号：US663610
申请日：1984-10-22
申请人： John F. Knapp , Robert J. Gruber , Steven B. Bolte
发明人： John F. Knapp , Robert J. Gruber , Steven B. Bolte
CPC分类号： G03G15/5062 , G03G2215/0013
摘要： An electrophotographic printing machine in which a magnetic toner image is transferred to a copy sheet from a photoconductive member and fused thereto. The toner image fused to the copy sheet is magnetized and the intensity of the magnetic field generated by the toner image detected to provide a continuous indication of the quality of the toner image fused to the copy sheet.
摘要翻译： 一种电子照相印刷机，其中磁性调色剂图像从感光体转印到复印纸上并熔合。 与复印纸熔合的调色剂图像被磁化，并且检测由调色剂图像产生的磁场的强度，以提供与复印纸融合的调色剂图像的质量的连续指示。
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7.发明授权Process for preventing deposition of toner particles in an imaging apparatus 失效用于防止调色剂颗粒沉积在成像装置中的方法
公开(公告)号：US4520092A
公开(公告)日：1985-05-28
申请号：US566754
申请日：1983-12-27
申请人： John F. Knapp , Robert J. Gruber
发明人： John F. Knapp , Robert J. Gruber
CPC分类号： G03G9/08
摘要： A process for obtaining smudge resistant images and for preventing the deposition of unwanted toner particles in an imaging apparatus which comprises(a) providing a xerographic imaging apparatus,(b) adding an improved two component contamination free developer composition to said apparatus, which composition consists essentially of from about 50 percent to about 80 percent by weight of a resin comprised of the polymeric esterification product of a dicarboxylic acid and a diol comprising a diphenol of the following formula ##STR1## wherein R is selected from substituted and unsubstituted alkylene radicals having from about 2 to about 12 carbon atoms, alkylidene radicals having from 1 to 12 carbon atoms and cycloalkylidene radicals having from 3 to 12 carbon atoms; R' and R" are selected from substituted and unsubstituted alkylene radicals having from 2 to 12 carbon atoms, alkylene arylene radicals having from 8 to 12 carbon atoms and arylene radicals; X and X'; are selected from hydrogen or any alkyl radical having from 1 to 4 carbon atoms; and each n is a number of from 0 (zero) to 4, about 20 percent to about 50 percent by weight of magnetite and a carrier material consisting of a steel core coated with a polymethyl methacrylate resin or a polyvinylidene fluoride resin,(c) forming electrostatic latent images in the imaging apparatus, and(d) developing the images formed.
摘要翻译： 一种用于获得防污染图像并防止在成像设备中沉积不需要的调色剂颗粒的方法，其包括（a）提供静电复印成像设备，（b）将改进的两组分无污染的显影剂组合物添加到所述设备中， 基本上为约50重量％至约80重量％的由二羧酸和二醇的聚合酯化产物组成的树脂，其包含下式的二酚其中R选自取代和未取代的亚烷基， 约2至约12个碳原子，具有1至12个碳原子的亚烷基和具有3至12个碳原子的亚环烷基; R'和R“选自具有2至12个碳原子的取代和未取代的亚烷基，具有8至12个碳原子的亚烷基亚芳基和亚芳基; X和X'; 选自氢或任何具有1至4个碳原子的烷基; 并且每个n是0〜0〜4，约20〜50重量％的磁铁矿和由涂覆有聚甲基丙烯酸甲酯树脂或聚偏二氟乙烯树脂的钢芯组成的载体材料，（c） 在成像设备中形成静电潜像，以及（d）显影形成的图像。
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公开(公告)号：US4487825A
公开(公告)日：1984-12-11
申请号：US227003
申请日：1981-01-22
申请人： Robert J. Gruber , John F. Knapp
发明人： Robert J. Gruber , John F. Knapp
CPC分类号： G03G9/08708 , G03G9/08722 , Y10S430/104
摘要： This invention relates to a conductive single component magnetic dry toner comprised of resins selected from polystyrene allyl alcohol copolymers, and epoxy resins, a magnetic material such as magnetite, and a conductive carbon black which is adhered and/or embedded on the surface of the copolymer or epoxy resin-magnetic material mixture. Such toner compositions, which have excellent conductivity, superior flow properties and low melt fusing temperatures, 95.degree. C.-130.degree. C., are useful for causing the development of images in commercial printers and recorders such as the Versatec printers.
摘要翻译： 本发明涉及由选自聚苯乙烯烯丙基醇共聚物和环氧树脂的树脂，磁铁矿等磁性材料和导电性炭黑组成的导电性单组分磁性干燥调色剂，该导电性炭黑被粘合和/或嵌入在共聚物的表面上 或环氧树脂 - 磁性材料混合物。 具有优异的导电性，优异的流动性能和低熔点熔融温度（95℃-130℃）的这种调色剂组合物可用于在诸如Versatec打印机的商业打印机和记录仪中形成图像。
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9.发明授权Conductive single component magnetic toner for use in electronic printing devices 失效用于电子印刷装置的导电单组分磁性调色剂
公开(公告)号：US4451837A
公开(公告)日：1984-05-29
申请号：US383662
申请日：1982-06-01
申请人： Robert J. Gruber , John F. Knapp
发明人： Robert J. Gruber , John F. Knapp
CPC分类号： G03G9/08755 , G03G9/0825
摘要： An improved conductive single component magnetic dry toner composition for use in developing images in electronic printing systems of a conductivity of from 10.sup.-6 to 10.sup.-8 (ohms/cm).sup.-1, and a fusing temperature of from about 95 degrees Centigrade to about 130 degrees Centigrade, and comprised of a magnetic material present in an amount of from about 40 percent by weight to about 80 percent by weight, and from about 20 percent by weight to about 60 percent by weight of a polyester resin, comprised of the polymeric esterification product of a dicarboxylic acid and a diol comprising a diphenol of the formula: ##STR1## wherein R is selected from substituted and unsubstituted alkylene radicals containing from about 2 to about 12 carbon atoms, alkylidene radicals containing from 1 to about 12 carbon atoms, and cycloclkylidene radicals containing from about 3 to about 12 carbon atoms; R' and R" are selected from substituted and unsubstituted alkylene radicals containing from about 2 to about 12 carbon atoms, alkylene arylene radicals containing from about 8 to about 12 carbon atoms and arylene radicals; X and X' are selected from hydrogen or alkyl radicals containing from 1 to about 4 carbon atoms; and each n is a number of from 0 (zero) to 4, a conductive carbon black present in an amount of from about 0.5 percent to about 4 percent, which carbon black is adhered to or embedded in the surface of the polyester magnetic mixture.
摘要翻译： 一种改进的导电单组分磁性干粉调色剂组合物，用于在电子印刷系统中显影，电导率为10-6至10-8（欧姆/厘米）-1，熔点温度为约95摄氏度至约 130摄氏度，由含有约40重量％至约80重量％，约20重量％至约60重量％的聚酯树脂的量的磁性材料组成，该聚酯树脂由聚合物 二羧酸和二醇的酯化产物，其包含下式的二酚：其中R选自含有约2至约12个碳原子的取代和未取代的亚烷基，含有1至约12个碳原子的亚烷基， 和含有约3至约12个碳原子的亚环烷基; R'和R“选自含有约2至约12个碳原子的取代和未取代的亚烷基，含有约8至约12个碳原子的亚烷基亚芳基和亚芳基; X和X'选自氢或含有1至约4个碳原子的烷基; 并且每个n为0（零）至4的数量，以约0.5％至约4％的量存在的导电炭黑，该炭黑粘附或嵌入聚酯磁性混合物的表面。
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公开(公告)号：US4296192A
公开(公告)日：1981-10-20
申请号：US54203
申请日：1979-07-02
CPC分类号： C08G59/62 , C08G59/621 , C08L71/00 , C08L71/02 , G03G9/08759 , C08G2650/56 , Y10S430/105
摘要： An electrostatographic toner composition including a colorant and polyether polymer of a dihydric phenol and an alkylene ether glycol.
摘要翻译： 一种包含二元酚和亚烷基醚二醇的着色剂和聚醚聚合物的静电色调调色剂组合物。
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