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公开(公告)号：US06922429B2
公开(公告)日：2005-07-26
申请号：US10812045
申请日：2004-03-29
摘要： A method and apparatus for removing BHP contaminants (alkali hydroxide and H2O2) from a recycled aqueous alkali chloride solution stream before the stream is fed to a chloralkali cell so that the contaminants do not impair the operation of a chloralkali cell. Unwanted alkali hydroxide within the recycled alkali chloride brine solution is reacted with chlorine gas and converted into an alkali chloride, which is useful in the operation of the chloralkali cell, and oxygen gas, which is outgassed from the system. Any H2O2 remaining in the recycled stream after elimination of the alkali hydroxide is reacted with chlorine to form HCl and oxygen gas. The HCl raises the pH of the brine solution, after which the pH may be adjusted by the addition of supplemental alkali hydroxide.
摘要翻译： 在将流送入氯碱池之前，从循环的氯化碱水溶液流中除去BHP污染物（碱金属氢氧化物和H 2 O 2 O 2）的方法和装置，使得 污染物不会损害氯碱电池的运行。 在循环的氯化碱盐水溶液中的不需要的碱性氢氧化物与氯气反应并转化成碱氯化物，其可用于氯碱电池的操作和从体系中脱气的氧气。 在碱性氢氧化物消除后残留在回收物流中的任何H 2 O 2 O 2 2与氯反应形成HCl和氧气。 HCl提高盐水溶液的pH值，之后可以通过加入碱性氢氧化碱调节pH值。
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公开(公告)号：US07195740B2
公开(公告)日：2007-03-27
申请号：US10812048
申请日：2004-03-29
摘要： A method and apparatus for removing BHP contaminants (alkali hydroxide and H2O2) from a recycled aqueous alkali chloride solution stream before the stream is fed to a chloralkali cell so that the contaminants do not impair the operation of a chloralkali cell. Unwanted alkali hydroxide within the recycled alkali chloride brine solution is reacted with chlorine gas and converted into an alkali chloride, which is useful in the operation of the chloralkali cell, and oxygen gas, which is outgassed from the system. Any H2O2 remaining in the recycled stream after elimination of the alkali hydroxide is reacted with chlorine to form HCl and oxygen gas. The HCl raises the pH of the brine solution, after which the pH may be adjusted by the addition of supplemental alkali hydroxide.
摘要翻译： 在将流送入氯碱池之前，从循环的氯化碱水溶液流中除去BHP污染物（碱金属氢氧化物和H 2 O 2 O 2）的方法和装置，使得 污染物不会损害氯碱电池的运行。 在循环的氯化碱盐水溶液中的不需要的碱性氢氧化物与氯气反应并转化成碱氯化物，其可用于氯碱电池的操作和从体系中脱气的氧气。 在碱性氢氧化物消除后残留在回收物流中的任何H 2 O 2 O 2 2与氯反应形成HCl和氧气。 HCl提高盐水溶液的pH值，之后可以通过加入碱性氢氧化碱调节pH值。
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公开(公告)号：US06763051B2
公开(公告)日：2004-07-13
申请号：US10151653
申请日：2002-05-20
IPC分类号： H01S3915
摘要： A method and apparatus for removing BHP contaminants (alkali hydroxide and H2O2) from a recycled aqueous alkali chloride solution stream before the stream is fed to a chloralkali cell so that the contaminants do not impair the operation of a chloralkali cell. Unwanted alkali hydroxide within the recycled alkali chloride brine solution is reacted with chlorine gas and converted into an alkali chloride, which is useful in the operation of the chloralkali cell, and oxygen gas, which is outgassed from the system. Any H2O2 remaining in the recycled stream after elimination of the alkali hydroxide is reacted with chlorine to form HCl and oxygen gas. The HCl raises the pH of the brine solution, after which the pH may be adjusted by the addition of supplemental alkali hydroxide.
摘要翻译： 在将流输送到氯碱池之前，从循环的氯化碱水溶液流中除去BHP污染物（碱金属氢氧化物和H 2 O 2）的方法和装置，使得污染物不会损害氯碱池的运行。 在循环的氯化碱盐水溶液中的不需要的碱性氢氧化物与氯气反应并转化成碱氯化物，其可用于氯碱电池的操作和从体系中脱气的氧气。 在碱性氢氧化物消除后残留在再循环物流中的任何H 2 O 2与氯反应形成HCl和氧气。 HCl提高盐水溶液的pH值，之后可以通过加入碱性氢氧化碱调节pH值。
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4.发明授权公开(公告)号：US08377384B2
公开(公告)日：2013-02-19
申请号：US11102385
申请日：2005-04-08
申请人： Thomas L. Bunn , Alan Z. Ullman , David Stelman
发明人： Thomas L. Bunn , Alan Z. Ullman , David Stelman
IPC分类号： B01J19/08
CPC分类号： C01B15/027 , C25B1/30
摘要： Methods and apparatus are provided for the generation of hydrogen peroxide from an electrochemical (EC) cell arrangement. One embodiment of the apparatus comprises an EC cell having anode and cathode electrodes with a cation exchange membrane disposed between them to form anode and cathode compartments. An aqueous salt solution is supplied to the anode compartment and water and oxygen are supplied to the cathode compartment. An electric potential applied across the anode and cathode electrodes initiates an electrochemical process that results in the formation of an acid anolyte solution in the anode compartment and an alkaline catholyte solution in the cathode compartment. The anolyte solution and the catholyte solution are combined in a neutralizing chamber to form a neutral aqueous solution comprising hydrogen peroxide, salt, and water. The hydrogen peroxide is separated from the neutral aqueous solution by conventional means.
摘要翻译： 提供了从电化学（EC）电池布置产生过氧化氢的方法和装置。 该装置的一个实施例包括具有阳极和阴极电极的EC电池，其间设置有阳离子交换膜以形成阳极和阴极隔室。 将盐水溶液供应到阳极室，并将水和氧气供应到阴极室。 施加在阳极和阴极电极两端的电位引发电化学过程，其导致在阳极室中形成酸性阳极电解液和阴极室中的碱性阴极电解液。 将阳极电解液和阴极电解液在中和室中合并形成包含过氧化氢，盐和水的中性水溶液。 过氧化氢通过常规方法与中性水溶液分离。
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5.发明授权公开(公告)号：US06884337B2
公开(公告)日：2005-04-26
申请号：US10151610
申请日：2002-05-20
申请人： Peter D. Amdisen , Thomas L. Bunn , Alan Z. Ullman
发明人： Peter D. Amdisen , Thomas L. Bunn , Alan Z. Ullman
摘要： A method of generating basic hydrogen peroxide (BHP) fuel for a chemical oxygen-iodine laser (COIL) using stored alkali chloride, typically potassium chloride, and water. The alkali chloride and water are mixed to form a saturated or nearly saturated aqueous salt solution for use as an anolyte feed to a chlor-alkali cell. The chlor-alkali cell generates alkali hydroxide, hydrogen, and chlorine. Water and oxygen are reacted to form peroxide which is combined with the alkali hydroxide from the chlor-alkali cell to form a dilute solution of BHP, a mixture of hydrogen peroxide and alkali hydroxide, which dissociates into O2H− and −OH. The BHP is concentrated and the molar ratio of hydrogen peroxide to alkali hydroxide is adjusted to 1:1 before the BHP is supplied to a COIL apparatus as fuel for the lasing process.
摘要翻译： 使用储存的碱性氯化物（通常是氯化钾）和水来产生用于化学氧碘激光（COIL）的碱性过氧化氢（BHP）燃料的方法。 将碱金属氯化物和水混合形成饱和或接近饱和的盐水溶液，以用作氯碱池的阳极电解液。 氯碱电池产生氢氧化碱，氢气和氯气。 水和氧反应形成过氧化物，其与来自氯碱池的碱金属氢氧化合物形成BHP（过氧化氢和碱金属氢氧化物的混合物）的稀溶液，其分解成O 2 H + - 和/或 - OH。 将BHP浓缩，将BHP供给COIL装置作为激光加工的燃料之前，将过氧化氢与碱金属氢氧化物的摩尔比调节至1:1。
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公开(公告)号：US08485741B1
公开(公告)日：2013-07-16
申请号：US12817608
申请日：2010-06-17
申请人： Thomas L. Bunn , Lynne C. Eigler
发明人： Thomas L. Bunn , Lynne C. Eigler
IPC分类号： G03B17/00
CPC分类号： G01C11/02 , G03B15/006 , G03B19/16 , G03B37/04
摘要： A method and apparatus for generating an image. Light is passed though an opening of a housing. The light has an intensity. At least a portion of the light received through the opening is increased using an intensifier unit to form intensified light. The intensified light is converted into a number of signals for the image using an image detection system located inside of the housing.
摘要翻译： 一种用于生成图像的方法和装置。 光通过一个房屋的开口。 光线有强度。 通过开口接收的光的至少一部分使用增强器单元增加以形成增强的光。 使用位于壳体内部的图像检测系统将增强的光转换成用于图像的多个信号。
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7.发明授权Method and system for producing singlet delta oxygen (SDO) and laser system incorporating an SDO generator 有权用于生成单重态三氧化碳（SDO）和掺入SDO发生器的激光系统的方法和系统公开(公告)号：US07512169B2
公开(公告)日：2009-03-31
申请号：US11673336
申请日：2007-02-09
申请人： Thomas L. Bunn
发明人： Thomas L. Bunn
IPC分类号： H01S3/095
CPC分类号： C01B13/02 , H01S3/036 , H01S3/0979 , H01S3/2215 , H01S3/223
摘要： A method for producing singlet delta oxygen may include forming a molecular beam of oxygen clusters from oxygen from an oxygen source. The method may also include optically pumping the molecular beam of oxygen clusters to produce singlet delta oxygen.
摘要翻译： 用于制备单重态三氧化碳的方法可以包括从氧源形成氧簇的分子束。 该方法还可以包括光泵浦氧簇的分子束以产生单重态三氧化碳。
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8.发明申请METHOD AND SYSTEM FOR PRODUCING SINGLET DELTA OXYGEN (SDO) AND LASER SYSTEM INCORPORATING AN SDO GENERATOR 有权用于生产符合SDO发生器的单层三氧化二矽（SDO）和激光系统的方法和系统公开(公告)号：US20080192793A1
公开(公告)日：2008-08-14
申请号：US11673336
申请日：2007-02-09
申请人： Thomas L. Bunn
发明人： Thomas L. Bunn
IPC分类号： H01S3/095 , C01B13/02 , H01S3/0953
CPC分类号： C01B13/02 , H01S3/036 , H01S3/0979 , H01S3/2215 , H01S3/223
摘要： A method for producing singlet delta oxygen may include forming a molecular beam of oxygen clusters from oxygen from an oxygen source. The method may also include optically pumping the molecular beam of oxygen clusters to produce singlet delta oxygen.
摘要翻译： 用于制备单重态三氧化碳的方法可以包括从氧源形成氧簇的分子束。 该方法还可以包括光泵浦氧簇的分子束以产生单重态三氧化碳。
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公开(公告)号：US08405322B1
公开(公告)日：2013-03-26
申请号：US12817581
申请日：2010-06-17
申请人： Thomas L. Bunn
发明人： Thomas L. Bunn
CPC分类号： G03B19/16 , G02B23/12 , G03B15/006 , G03B17/17 , G03B33/08 , G03B33/12 , H01J31/506 , H04N5/2252
摘要： A method and apparatus are present for increasing an intensity of light. Light is sent into an input of a housing in which a vacuum is substantially provided in the housing. The light sent into the input of the housing is converted into initial electrons. Movement of the initial electrons is caused to diverge from an axis through the housing to form diverged electrons. Additional electrons are generated to form an increased number of electrons in response to receiving at least a portion of the diverged electrons. The increased number of electrons is converted into output light that exits an output of the housing.
摘要翻译： 存在用于增加光强度的方法和装置。 光被送入壳体的输入端，其中壳体中基本上设有真空。 发送到壳体的输入端的光被转换为初始电子。 引起初始电子的运动从轴通过壳体发散以形成发散的电子。 响应于接收至少一部分发散电子而产生附加电子以形成增加数量的电子。 增加的电子数转换成离开壳体的输出的输出光。
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10.发明授权Methods and apparatus for simultaneous chlorine and alkaline-peroxide production 有权同时进行氯和碱过氧化物生产的方法和装置公开(公告)号：US07025868B2
公开(公告)日：2006-04-11
申请号：US10338648
申请日：2003-01-07
CPC分类号： F41H13/005 , C25B1/26 , C25B1/30 , H01S3/095
摘要： An electrolytic cell for producing chlorine and basic hydrogen peroxide suitably includes an anode partition and a cathode partition separated by a membrane. The cathode partition is divided into a catholyte compartment and a gas plenum by a gas diffusion cathode. The anode partition electrolyzes alkali chloride received from the laser to produce free chlorine and alkali ions. The catholyte partition reduces oxygen received from the gas plenum through the cathode, and produces alkaline peroxide from the oxidized components combined with alkali ions received through the membrane from the anode partition. The cell is particularly useful in a fuel regeneration system (FRS) for a chemical oxygen iodine laser (COIL).
摘要翻译： 用于生产氯和碱性过氧化氢的电解池适宜地包括阳极隔板和隔膜隔开的阴极隔板。 阴极隔板通过气体扩散阴极分为阴极电解室和气室。 阳极隔板电解从激光器接收的碱金属氯化物，产生游离氯和碱离子。 阴极电解液分隔板通过阴极减少从气体压力室接收的氧气，并从氧化的组分产生碱性过氧化物，并与从阳极隔板通过膜接受的碱离子组合。 该电池在用于化学氧碘激光器（COIL）的燃料再生系统（FRS）中特别有用。
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