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    Dye releasing couplers for color diffusion transfer elements with dye barrier layers
    1.
    发明授权
    Dye releasing couplers for color diffusion transfer elements with dye barrier layers 失效

    公开(公告)号：US5342730A

    公开(公告)日：1994-08-30

    申请号：US952444

    申请日：1992-09-28

    申请人： Thomas R. Welter ,  John Texter

    发明人： Thomas R. Welter ,  John Texter

    IPC分类号： G03C8/08 ,  G03C8/52 ,  G03C5/54

    CPC分类号： G03C8/52 ,  G03C8/08

    摘要： In accordance with this invention a photographic color diffusion transfer element and process for its development are provided. The element comprises a single dimensionally stable support, wherein said support comprises an opaque and light reflecting layer, and coated thereon in reactive association and in sequence (1) a mordant layer for binding diffusible dyes, (2) a stripping layer, (3) one or more layers comprising radiation sensitive silver halide and a diffusible-dye forming coupler, and (4) a barrier layer comprising a polymer that (a) allows the passage of solutions for processing said element when said element is contacted with an external processing bath and (b) impedes the diffusion out of said element of the diffusible dye formed from said diffusible-dye forming coupler, and wherein said diffusible-dye forming coupler is of the structureCp-L-DyewhereinCp is a coupler radical selected from the group comprising cyan dye forming radicals, magenta dye forming radicals, yellow dye forming radicals, black dye forming radicals, and colorless product forming radicals, said Cp being substituted in the coupling position with a divalent linking group, L;Dye is a dye radical exhibiting selective absorption in the visible spectrum and contains a solubilizing group;and where said -L-Dye group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent. In another preferred embodiment, said element comprises a single dimensionally stable transparent support, and coated thereon in reactive association and in sequence (1) a mordant layer for binding diffusible dyes, (2) an opacifying light reflecting layer, (3) one or more layers comprising radiation sensitive silver halide and a diffusible-dye forming coupler, and (4) a barrier layer comprising a polymer that (a) allows the passage of solutions for processing said element when said element is contacted with an external processing bath and (b) impedes the diffusion out of said element of the diffusible dye formed from said diffusible-dye forming coupler. In another preferred embodiment, said element comprises a single dimensionally stable transparent support, and coated thereon in reactive association and in sequence (1) one or more layers comprising radiation sensitive silver halide and a diffusible-dye forming coupler, (2) an opacifying light reflecting layer, (3) a mordant layer for binding diffusible dyes, and (4) a barrier layer comprising a polymer that (a) allows the passage of solutions for processing said element when said element is contacted with an external processing bath and (b) impedes the diffusion out of said element of the diffusible dye formed from said diffusible-dye forming coupler.

    Methine-dye releasing couplers for heat image separation systems
    2.
    发明授权
    Methine-dye releasing couplers for heat image separation systems 失效
    用于热图像分离系统的甲基染料释放成色剂

    公开(公告)号：US5455140A

    公开(公告)日：1995-10-03

    申请号：US250145

    申请日：1994-05-27

    申请人： John Texter ,  Thomas R. Welter ,  David T. Southby ,  Jared B. Mooberry

    发明人： John Texter ,  Thomas R. Welter ,  David T. Southby ,  Jared B. Mooberry

    IPC分类号： G03C8/10 ,  G03C8/40 ,  G03C8/12

    CPC分类号： G03C8/10 ,  G03C8/4013

    摘要： An aqueous-developable photographic color diffusion transfer element is disclosed where this element comprises one and only one dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a methine-dye releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, and wherein said methine-dye releasing coupler is of the structure (I)Cp--L--M (I)whereCp is a coupler radical substituted in the coupling position with a divalent linking group, L;M is a methine-dye radical exhibiting selective absorption in the visible spectrum; and where the --L--M group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent, and where said methine-dye radical M is released from said --L--M group subsequent to the coupling off of said --L--M group.Also disclosed in this invention is a diffusion transfer process for forming a color photographic image comprising the steps of:exposing said element to actinic radiation; processing said element by immersing said element in an external aqueous bath containing color developer of the primary amine type;washing said element;drying said element to remove the imbibed water; andheating said element to effect dye diffusion transfer to an image receiving layer.

    摘要翻译： 公开了一种含水显影照相色彩扩散转移元件，其中该元件包括一个且仅一维稳定的载体，以及包含辐射敏感卤化银的一层或多层，用于促进染料通过亲水性粘合剂的热扩散的热溶剂， 染料释放成色剂和亲水性粘合剂，其中所述染料在所述粘合剂和热溶剂中是热扩散的，并且其中所述次甲基染料释放成色剂具有结构式（I）Cp-LM（I），其中Cp是取代基 与二价连接基团的偶联位置L; M是在可见光谱中表现出选择性吸收的次甲基染料基团; 并且其中-LM基团在所述成色剂基团与伯胺显影剂的氧化产物反应时脱离，并且其中所述次甲基染料基团M在所述-LM基团的偶联之后从所述-LM基团释放出来 。 本发明还公开了用于形成彩色照相图像的扩散转移方法，包括以下步骤：将所述元件暴露于光化辐射; 通过将所述元件浸入含有伯胺型彩色显影剂的外部水浴中来处理所述元件; 洗涤元素; 干燥所述元件以除去吸收的水; 并加热所述元件以进行染料扩散转移到图像接收层。

    Dye releasing couplers for heat image separation systems
    3.
    发明授权
    Dye releasing couplers for heat image separation systems 失效
    用于热图像分离系统的脱色成色剂

    公开(公告)号：US5356750A

    公开(公告)日：1994-10-18

    申请号：US993580

    申请日：1992-12-21

    申请人： John Texter ,  Thomas R. Welter ,  David T. Southby ,  Jared B. Mooberry

    发明人： John Texter ,  Thomas R. Welter ,  David T. Southby ,  Jared B. Mooberry

    IPC分类号： G03C8/10 ,  G03C8/40 ,  G03C5/54

    CPC分类号： G03C8/4033 ,  G03C8/10 ,  G03C8/4066

    摘要： An aqueous-developable photographic color diffusion transfer element comprising a single dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a dye-releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, and wherein said dye-releasing coupler is of the structureCp--L-DyewhereCp is a cyan dye forming radical, magenta dye forming radical, yellow dye forming radical, black dye forming radical, or colorless product forming radical, said Cp being substituted in the coupling position with a divalent linking group, L;Dye is a dye radical exhibiting selective absorption in the visible spectrum; and where said --L-Dye group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent is disclosed.

    摘要翻译： 含水显影照相色彩扩散转移元件包括单尺寸稳定的载体和一层或多层包含辐射敏感的卤化银，用于促进染料通过亲水性粘合剂的热扩散的热溶剂，染料释放成色剂和亲水性粘合剂， 其中所述染料在所述粘合剂和热溶剂中是热扩散的，并且其中所述染料释放成色剂具有结构Cp-L-Dye，其中Cp是形成自由基的青色染料，形成自由基的品红色染料，形成自由基的黄色染料，黑色染料 形成自由基或无色产物形成基团，所述Cp在偶联位置被二价连接基团L取代; 染料是在可见光谱中显示出选择性吸收的染料基团; 并且其中所述-L-染料基团在所述成色剂基团与伯胺显影剂的氧化产物反应时偶联。

    Heat development of elements containing methine-dye releasing couplers
    4.
    发明授权
    Heat development of elements containing methine-dye releasing couplers 失效
    含有次甲基染料释放成色剂的元素的热显影

    公开(公告)号：US5470688A

    公开(公告)日：1995-11-28

    申请号：US250146

    申请日：1994-05-27

    申请人： John Texter ,  Thomas R. Welter ,  David T. Southby ,  Jared B. Mooberry

    发明人： John Texter ,  Thomas R. Welter ,  David T. Southby ,  Jared B. Mooberry

    IPC分类号： G03C8/10 ,  G03C8/40 ,  G03C8/12

    CPC分类号： G03C8/10 ,  G03C8/4013 ,  Y10S430/159

    摘要： In accordance with this invention a heat-developable photographic color diffusion transfer element is provided, where this element comprises a dimensionally stable support and one or more layers comprising radiation sensitive silver halide, an organic silver salt oxidizing agent, a reducing agent, a methine-dye releasing compound, and a binder, wherein said methine-dye is heat diffusible in said element, and wherein said methine-dye releasing compound is of the structureCp--L--M (I)whereCp is a coupler radical substituted in the coupling position with a divalent linking group, L;M is a methine-dye radical exhibiting selective absorption in the visible spectrum; and where the --L--M group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent, and where said methine-dye radical M is released from said --L--M group subsequent to the coupling off of said --L--M group.

    摘要翻译： 根据本发明，提供了一种可热显影的照相彩色扩散转移元件，其中该元件包括尺寸稳定的支撑体和一个或多个包含辐射敏感卤化银，有机银盐氧化剂，还原剂，次甲基 - 染料释放化合物和粘合剂，其中所述次甲基染料在所述元件中是可热扩散的，并且其中所述次甲基染料释放化合物具有结构Cp-LM（I），其中Cp是在与 二价连接基团L; M是在可见光谱中表现出选择性吸收的次甲基染料基团; 并且其中-LM基团在所述成色剂基团与伯胺显影剂的氧化产物反应时脱离，并且其中所述次甲基染料基团M在所述-LM基团的偶联之后从所述-LM基团释放出来 。

    Heat image separation with phenolic thermal solvents and dye releasing couplers
    5.
    发明授权
    Heat image separation with phenolic thermal solvents and dye releasing couplers 失效
    用酚类热溶剂和染料释放成色剂进行热图像分离

    公开(公告)号：US5512410A

    公开(公告)日：1996-04-30

    申请号：US323967

    申请日：1994-10-17

    申请人： John Texter ,  Thomas R. Welter ,  David T. Southby ,  Jared B. Mooberry ,  David S. Bailey

    发明人： John Texter ,  Thomas R. Welter ,  David T. Southby ,  Jared B. Mooberry ,  David S. Bailey

    IPC分类号： G03C8/10 ,  G03C8/40 ,  G03C8/50

    CPC分类号： G03C8/4033 ,  G03C8/10 ,  G03C8/4066

    摘要： An aqueous-developable photographic color diffusion transfer element comprising one and only one dimensionally stable support and one or more layers comprising radiation sensitive silver halide, thermal solvent for facilitating the thermal diffusion of dyes through a hydrophilic binder, a dye-releasing coupler, a dye-receiving layer intermediate said support and dye-releasing coupler containing layers, a stripping layer intermediate said dye-receiving layer and any layers containing silver halide or dye-releasing coupler, and hydrophilic binder, wherein said dye is heat diffusible in said binder and thermal solvent, wherein said dye-releasing coupler is of the structureCp--L--DyewhereCp is a coupler radical substituted in the coupling position with a divalent linking group, L;Dye is a dye radical exhibiting selective absorption in the visible spectrum; and where said --L--Dye group couples off upon reaction of said coupler radical with the oxidation product of a primary amine developing agent, and such that said Dye radical is subsequently released from the --L--Dye group;where said stripping layer contains a stripping agent; andwherein said thermal solvent has the structure I: ##STR1## wherein (a) Z.sub.1, Z.sub.2, Z.sub.3, Z.sub.4, and Z.sub.5 are substituents, the Hammet sigma parameters of Z.sub.2, Z.sub.3, and Z.sub.4 sum to give a total, .SIGMA., of at least -0.28 and less than 1.53;(b) the calculated logP for I is greater than 3 and less than 10, is disclosed.

    摘要翻译： 一种含水显影照相色彩扩散转移元件，包括一个且仅一维稳定的载体和一个或多个包含辐射敏感卤化银的层，用于促进染料通过亲水性粘合剂的热扩散的热溶剂，染料释放成色剂，染料 接收层介于所述支持和释放染料的成色剂层之间，所述染料接收层和包含卤化银或染料释放成色剂的任何层的剥离层和亲水性粘合剂，其中所述染料在所述粘合剂中热扩散，并且热 溶剂，其中所述染料释放成色剂具有结构Cp-L-Dye，其中Cp是在与二价连接基团L的偶联位置取代的成色剂基团; 染料是在可见光谱中显示出选择性吸收的染料基团; 并且其中所述-L-染料基团在所述成色剂基团与伯胺显影剂的氧化产物反应时脱离，并且使得所述染料自由基随后从-L-染料基团中释放; 其中所述剥离层包含剥离剂; 并且其中所述热溶剂具有以下结构I：其中（a）Z 1，Z 2，Z 3，Z 4和Z 5为取代基，Z 2，Z 3和Z 4的Hammetσ参数相加， SIGMA至少为-0.28且小于1.53; （b）公开了I的计算logP大于3并小于10。

    Heterocycloalkyl-substituted naphthalene-based tetracarboxylic diimide compounds as N-type semiconductor materials for thin film transistors
    6.
    发明授权
    Heterocycloalkyl-substituted naphthalene-based tetracarboxylic diimide compounds as N-type semiconductor materials for thin film transistors 有权
    杂环烷基取代的萘基四羧酸二酰亚胺化合物作为薄膜晶体管的N型半导体材料

    公开(公告)号：US07858970B2

    公开(公告)日：2010-12-28

    申请号：US11771196

    申请日：2007-06-29

    申请人： Deepak Shukla ,  Thomas R. Welter ,  Wendy G. Ahearn

    发明人： Deepak Shukla ,  Thomas R. Welter ,  Wendy G. Ahearn

    IPC分类号： H01L35/24 ,  H01L51/00

    CPC分类号： H01L51/0053 ,  C09B57/08 ,  H01L51/0545 ,  Y02E10/549

    摘要： A thin film transistor comprises a layer of organic semiconductor material comprising a tetracarboxylic diimide naphthalene-based compound having, attached to one or both of the imide nitrogen atoms, a substituted or unsubstituted heterocycloalkyl ring system. Such transistors can further comprise spaced apart first and second contacts or electrodes in contact with said material. Further disclosed is a process for fabricating an organic thin-film transistor device, preferably by sublimation deposition onto a substrate, wherein the substrate temperature is no more than 200° C.

    摘要翻译： 一种薄膜晶体管包括一层有机半导体材料，它包括一个四羧酸二酰亚胺萘系化合物，它具有连接到一个或两个酰亚胺氮原子上的取代或未取代的杂环烷基环系。 这种晶体管还可以包括与所述材料接触的间隔开的第一和第二触点或电极。 进一步公开了一种用于制造有机薄膜晶体管器件的方法，优选通过升华沉积到衬底上，其中衬底温度不超过200℃。

    Photographic element containing a novel cyan dye forming coupler and process for its use
    8.
    发明授权
    Photographic element containing a novel cyan dye forming coupler and process for its use 失效
    含有新型青色染料成色剂的摄影元件及其使用方法

    公开(公告)号：US5508148A

    公开(公告)日：1996-04-16

    申请号：US359137

    申请日：1994-12-19

    申请人： Philip T. S. Lau ,  Thomas H. Jozefiak ,  Thomas R. Welter

    发明人： Philip T. S. Lau ,  Thomas H. Jozefiak ,  Thomas R. Welter

    IPC分类号： G03C7/00 ,  G03C7/305 ,  G03C7/34

    CPC分类号： G03C7/30523 ,  G03C7/344

    摘要： A photographic element comprises a light sensitive silver halide emulsion layer having associated therewith a cyan dye-forming coupler dispersed in an organic solvent, the coupler having the formula: ##STR1## wherein A, B, and C are hydrogen or fluoride;X is selected from the group consisting of halogen, alkoxy and methyl groups;R is an aromatic or aliphatic group and n is 1 or 2;R' is a substituent group and m is from 0 to 4;COG is hydrogen or a coupling-off group capable of being split-off by an oxidized color developer; andwherein the substituent groups X, R, and R' are selected so as to ballast the coupler and keep it from wandering within the photographic elements.

    摘要翻译： 照相元件包括光敏卤化银乳剂层，其具有分散在有机溶剂中的青色染料形成成色剂，所述成色剂具有下式：uoride; X选自卤素，烷氧基和甲基; R是芳族或脂族基团，n是1或2; R'为取代基，m为0〜4; COG是氢或能够被氧化的显色剂分离的偶合离去基团; 并且其中选择取代基组X，R和R'，以便使耦合剂镇定并使其不被在照相元件内漂移。