摘要:
A heat-curable coating composition for cathodic electrocoating which becomes water-thinnable on protonation with an acid contains(A) 50-95% by weight of a polycondensation or polyaddition product having an average molecular weight of from 500 to 20,000 and containing primary and/or secondary hydroxyl groups and primary, secondary and/or tertiary amino groups, and(B) 5-50% by weight of a crosslinking agent obtainable by reactinga) an aliphatic polyhydroxy compound andb) an aromatic polyhydroxy compound withc) an aliphatic and/or cycloaliphatic polyisocyanate andd) a blocking agent.
摘要:
A heat-curable, cathodically depositable aqueous electrocoating composition contains(A) from 50 to 95% by weight of a polymerization or polycondensation or polyaddition product which has an average molecular weight of from 200 to 20,000 and primary and/or secondary hydroxyl groups and primary, secondary and/or tertiary amino groups and is water-thinnable on protonation with an acid, and(B) from 5 to 50% by weight of a water-thinnable crosslinking agent having cationic groups or groups which are convertible into cationic groups by protonation with an acid.
摘要:
A two-phase cathodic electrocoat is obtainable by coating an electrically conducting substrate with a mixture containingA) an aqueous cationic dispersion of a polycondensation or polyaddition product,B) an aqueous cationic dispersion of a polycondensation or polyaddition product having a glass transition temperature of from -80.degree. to 20.degree. C., the polymers of dispersions (A) and (B) being mutually incompatible, and C) optionally a crosslinking agent, a pigment paste, auxiliaries and/or additives, and then baking.
摘要:
Binder systems suitable for electrodeposition coating and based on basic, thermally crosslinkable epoxy or polyurethane resins as binders (B), containing from 0.001 to 1% by weight of a polymer (I) whose predominant components are ethyl acrylate and/or n-propyl acrylate, based on the overall solids content of the binder system.
摘要:
Heat-reactive crosslinking agents for surface coating binders, based on phenolic Mannich bases, are obtainable by reacting(A) one equivalent of a polyphenol with(B) from 0.5 to 2 equivalents of formaldehyde or of a formaldehyde-donating compound and(C) from 0.5 to 1 equivalent of one or more secondary aliphatic amines,removing the water of reaction and reacting the resulting reaction produce with(D) from 0.01 to 1 equivalent of a mono- and/or polyfunctional isocyanate compound.
摘要:
Cathodic electrocoating binders which are water-dilutable on protonation with an acid are obtainable by reactingA) an epoxy compound or a mixture of epoxy compounds having an epoxide equivalent weight of less than 2,000 withB) a compound which is monofunctional with respect to epoxides and contains aliphatic or phenolic OH groups andC) a secondary amine of 2 to 36 carbon atoms, with the proviso that the reaction product of A), B) and C) still contains free epoxy groups, andD) an amount of an amidoamine containing primary amino groups which is equivalent to or greater than the amount of these free epoxy groups, the said amidoamine being obtainable from a primary diamine and a mono- and/or dicarboxylic acid.
摘要:
Heat-curable aqueous coating agents for cathodic electrocoating contain(A) an amino-containing polymerization, polycondensation or polyaddition product as a binder which becomes water-dilutable on protonation with an acid,(B) a crosslinking agent and(C) from 0.05 to 10% by weight, based on components (A) and (B), of a monomeric organic complexing agent.
摘要:
Cathodic electrocoating binders which are water-dilutable on protonation with an acid are obtainable by reactingA) an epoxy compound or a mixture of epoxy compounds having an epoxide equivalent weight of less than 2,000 withB) a compound which is monofunctional with respect to epoxides and contains aliphatic or phenolic OH groups andC) a secondary amine of 2 to 36 carbon atoms, with the proviso that the reaction product of A), B) and C) still contains free epoxy groups, andD) an amount of an amidoamine containing primary amino groups which is equivalent to or greater than the amount of these free epoxy groups, the said amidoamine being obtainable from a primary diamine and a mono- and/or dicarboxylic acid.
摘要:
A heat-curable coating material for cathodic electrocoating is water-dilutable on protonation with an acid and contains(A) from 50 to 95% by weight of a polymer, polycondensate or polyadduct containing primary and/or secondary amino groups, as a binder, and(B) from 5 to 50% by weight of a crosslinking agent obtainable by reacting(a) a polyurethane with(b) formaldehyde or a formaldehyde-donating compound and(c) one or more secondary aliphatic amines.
摘要:
Polymeric reaction products which become water-thinnable on protonation with an acid and are suitable for use in the form of aqueous dispersions as additives in electrocoating baths are formed fromA. a butadiene/acrylonitrile copolymer which contains primary and/or secondary amino groups andB. an epoxy compound having an average molecular weight of from 140 to 10,000 and containing on average from 1.5 to 3 epoxy groups per molecule,the amount of (A) being such that 1.05 moles or more of primary and/or secondary amino groups of component (A) are present per mole of epoxy groups of component (B).