摘要:
The present invention relates to a process for the production of halogenated butyl rubber and an apparatus for the production of rubber cement for use in the production of halogenated butyl rubber. The process and apparatus permit direct mixing of aqueous rubber slurry with a non-halogenated organic solvent to make a rubber cement solution. The water layer is then separated from the partially dissolved rubber cement and the cement phase is sent for halogenation. The apparatus is an enclosed vessel comprised of at least one dissolving zone and at least one separator zone. The process and apparatus advantageously employ recycle of rubber cement in order to disrupt an interface layer that forms between the water and rubber cement, to thereby improve continuously operation of the process.
摘要:
The present invention relates to a process for the production of halogenated butyl rubber and an apparatus for the production of rubber cement for use in the production of halogenated butyl rubber. The process and apparatus permit direct mixing of aqueous rubber slurry with a non-halogenated organic solvent to make a rubber cement solution. The water layer is then separated from the partially dissolved rubber cement and the cement phase is sent for halogenation. The apparatus is an enclosed vessel comprised of at least one dissolving zone and at least one separator zone. The process and apparatus advantageously employ recycle of rubber cement in order to disrupt an interface layer that forms between the water and rubber cement, to thereby improve continuously operation of the process.
摘要:
Polyisoolefins are produced according to the invention by polymerizing isoolefins having 4 to 16 carbon atoms, optionally with conjugated diolefins having 4 to 6 carbon atoms and/or cationically polymerizable, mono- or polyunsaturated, organic compounds having 4 to 16 carbon atoms in the presence of mixtures of carbon dioxide and linear, branched and/or cyclic C.sub.4 -C.sub.8 alkanes and in the presence of catalysts at temperatures of -70.degree. C. to +20.degree. C. and pressures of 1 to 70 bar, wherein the weight ratio of carbon dioxide to alkanes is 10:90 to 90:10.The process according to the invention largely prevents the formation of fouling on the reactor walls, so ensuring better removal of heat. Moreover, in accordance with the process according to the invention, the polyisoolefins obtained may be directly chemically modified once the carbon dioxide has been removed.