公开(公告)号：US20080182031A1

公开(公告)日：2008-07-31

申请号：US12013909

申请日：2008-01-14

申请人： Tokihiko MATSUMURA ,  Ippei NAKAMURA

发明人： Tokihiko MATSUMURA ,  Ippei NAKAMURA

IPC分类号： C08F2/50 ,  C08F2/46

CPC分类号： B41M7/0081 ,  C09D11/101

摘要： An ink composition of the present invention is disclosed, which contains (i) a sensitizing dye represented by the following Formula (I); (ii) at least one polymerization initiator selected from the group consisting of α-aminoketones and acyl phosphine oxides; and (iii) an ethylenically unsaturated bond-containing polymerizable compound. In Formula (I), X represents O, S or NR; n represents an integer of 0 or 1; R represents a hydrogen atom, an alkyl group or an acyl group; R1 to R8 each independently represent a hydrogen atom or a monovalent substituent; R1 and R2, R2 and R3, and R3 and R4 may be connected to each other to form a ring; and R5 or R6 may be connected to R7 or R8 to form an aliphatic ring but not to form an aromatic ring.

摘要翻译： 公开了本发明的油墨组合物，其含有（i）由下式（I）表示的增感染料; （ii）至少一种选自α-氨基酮和酰基氧化膦的聚合引发剂; 和（iii）含烯属不饱和键的可聚合化合物。 在式（I）中，X表示O，S或NR; n表示0或1的整数; R表示氢原子，烷基或酰基; R 1至R 8各自独立地表示氢原子或一价取代基; R 1和R 2，R 2和R 3以及R 3， 和R 4可以彼此连接以形成环; R 5或R 6可以连接到R 7或R 8以形成脂族环但不是 形成芳环。

公开(公告)号：US20090186163A1

公开(公告)日：2009-07-23

申请号：US12353500

申请日：2009-01-14

申请人： Tsutomu UMEBAYASHI ,  Ippei NAKAMURA ,  Tokihiko MATSUMURA

发明人： Tsutomu UMEBAYASHI ,  Ippei NAKAMURA ,  Tokihiko MATSUMURA

IPC分类号： B05D5/06 ,  C08F2/46

CPC分类号： C09D11/38 ,  B33Y70/00 ,  C09D11/101

摘要： A photocurable composition is provided that includes a polymerizable compound, a photopolymerization initiator, a compound represented by Formula (I) below, and an amine compound, the photopolymerization initiator comprising an acylphosphine oxide compound and/or an α-aminoacetophenone compound in Formula (I) above, X denotes O, S, or NR, n denotes 0 or 1, R denotes a hydrogen atom, an alkyl group, or an acyl group, R1, R2, R3, R4, R5, R6, R7, and R8 independently denote a hydrogen atom or a monovalent substituent, and two of R1, R2, R3, and R4 that are adjacent may be bonded to each other to form a ring. There are also provided a photocurable ink composition that includes the photocurable composition and a colorant, an ink composition for photocuring inkjet recording that includes the photocurable ink composition, a process for producing a photocured material that includes preparing the photocurable composition and irradiating the photocurable composition with light having a light emission peak in the range of at least 340 nm but no greater than 400 nm, and an inkjet recording method that includes discharging the ink composition onto a recording medium and irradiating the ink composition with actinic radiation.

摘要翻译： 提供了包含可聚合化合物，光聚合引发剂，由下式（I）表示的化合物和胺化合物的光固化性组合物，所述光聚合引发剂包括式（I）中的酰基氧化膦化合物和/或α-氨基苯乙酮化合物 ），X表示O，S或NR，n表示0或1，R表示氢原子，烷基或酰基，R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8独立地 表示氢原子或一价取代基，相邻的R1，R2，R3和R4中的两个可以彼此键合形成环。 还提供了包含光固化性组合物和着色剂的光固化性油墨组合物，包含光固化性油墨组合物的光固化喷墨记录用油墨组合物，光固化性物质的制造方法，其包括制备光固化性组合物，并将光固化性组合物照射 具有至少340nm但不大于400nm范围内的发光峰的光，以及喷墨记录方法，其包括将油墨组合物排出到记录介质上并用光化辐射照射该油墨组合物。

公开(公告)号：US20100129565A1

公开(公告)日：2010-05-27

申请号：US12625557

申请日：2009-11-25

申请人： Tokihiko MATSUMURA

发明人： Tokihiko MATSUMURA

IPC分类号： B05D3/06 ,  C08F2/50

CPC分类号： C09D11/101 ,  C09D11/38

摘要： The invention provides an ink composition including a sensitizer represented by the following Formula (I), a photopolymerization initiator, and a polymerizable compound having an ethylenic unsaturated bond. In the Formula (I), R1, R6 and R8 each independently represent a hydrogen atom, a hydroxyl group, a halogen atom, a linear or branched alkyl group which may be substituted, or an alkoxy group which may be substituted. R2, R4, R5 and R7 each independently represent a hydrogen atom, a halogen atom, or a cyano group. R3 represents a hydrogen atom, a linear or branched alkyl group which may be substituted, or a cycloalkyl group which may be substituted.

摘要翻译： 本发明提供一种油墨组合物，其包含由下式（I）表示的增感剂，光聚合引发剂和具有烯键式不饱和键的聚合性化合物。 在式（I）中，R 1，R 6和R 8各自独立地表示氢原子，羟基，卤素原子，可被取代的直链或支链烷基或可被取代的烷氧基。 R2，R4，R5和R7各自独立地表示氢原子，卤素原子或氰基。 R3表示氢原子，可被取代的直链或支链烷基或可被取代的环烷基。

公开(公告)号：US20100015352A1

公开(公告)日：2010-01-21

申请号：US12497558

申请日：2009-07-03

申请人： Tokihiko MATSUMURA

发明人： Tokihiko MATSUMURA

IPC分类号： C08F2/50 ,  C08J7/06

CPC分类号： C09D11/101 ,  C09D11/38

摘要： An ink-jet ink composition containing the following components of (a), (b), and (c), and having a viscosity at 25° C. in the range of from 5 mPa·s to 100 mPa·s, (a) a polymerizable compound, (b) a photopolymerization initiator, and (c) a sensitizer represented by the following formula (i): in the Formula (i), X represents O, S or NR; n represents an integer of 0 or 1; R represents a hydrogen atom, an alkyl group or an acyl group; each of R1, R2, R3, R4, R5, R6, R7 and R8 independently represents a hydrogen atom or a monovalent substituent, provided that any neighboring two of R1, R2, R3 and R4 may be bonded to each other to form a ring, and R5 and R7 or R8, or R6 and R7 or R8, may be bonded to each other to form an aliphatic ring but do not form an aromatic ring.

摘要翻译： 一种含有（a），（b）和（c）的组分的喷墨油墨组合物，在25℃下的粘度为5mPa.s至100mPa.s，（a ）可聚合化合物，（b）光聚合引发剂，和（c）由下式（i）表示的增感剂：在式（ⅰ）中，X表示O，S或NR; n表示0或1的整数; R表示氢原子，烷基或酰基; R 1，R 2，R 3，R 4，R 5，R 6，R 7和R 8各自独立地表示氢原子或一价取代基，条件是R 1，R 2，R 3和R 4中的任何相邻的两个可以彼此键合以形成环 ，R 5和R 7或R 8或R 6和R 7或R 8可以彼此键合以形成脂族环，但不形成芳香环。

公开(公告)号：US20100013899A1

公开(公告)日：2010-01-21

申请号：US12496661

申请日：2009-07-02

申请人： Tokihiko MATSUMURA

发明人： Tokihiko MATSUMURA

IPC分类号： C08F2/46 ,  B41J2/01

CPC分类号： C07D335/06 ,  B33Y70/00 ,  C07D277/74 ,  C07D335/10 ,  C08G59/1438 ,  C08G59/24 ,  C08L63/00 ,  C09B9/02 ,  C09B11/28 ,  C09B23/0091 ,  C09B23/148 ,  C09B57/00 ,  C09B57/001 ,  C09B57/02 ,  C09D11/101

摘要： A photo-curable composition including (A) a cationic polymerizable compound, (B) a sensitizing colorant represented by the following formula (I), and (C) an onium salt; an ink composition containing the photo-curable composition; an inkjet recording method using the ink composition are provided, and in formula (I), X represents O, S or NR, R represents a hydrogen atom, an alkyl group, or an acyl group, n represents 0 or 1, each of R1 to R8 independently represents a hydrogen atom, or a monovalent substituent.

摘要翻译： 一种光固化性组合物，其包含（A）阳离子可聚合化合物，（B）由下式（I）表示的增感着色剂和（C）鎓盐; 含有光固化性组合物的油墨组合物; 提供了使用该油墨组合物的喷墨记录方法，在式（I）中，X表示O，S或NR，R表示氢原子，烷基或酰基，n表示0或1，R1 至R8独立地表示氢原子或一价取代基。

公开(公告)号：US20090087575A1

公开(公告)日：2009-04-02

申请号：US12207162

申请日：2008-09-09

申请人： Tokihiko MATSUMURA ,  Tsutomu Umebayashi

发明人： Tokihiko MATSUMURA ,  Tsutomu Umebayashi

IPC分类号： B05D3/06 ,  C08L41/00 ,  C08L39/04 ,  C07D335/04 ,  C08F4/32 ,  C08F4/30

CPC分类号： C09B69/109 ,  B41M7/0072 ,  C09B67/0033 ,  C09D11/101 ,  C09D11/328

摘要： The invention provides an ink composition including (i) a sensitizing dye having a polymerizable group as a substituent, (ii) a polymerization initiator and (iii) a polymerizable compound having an ethylenically unsaturated bond. The invention also provides an inkjet recording method and a polymerizable compound useful as a sensitizing dye. The sensitizing dye (i) is represented by Formula (I) or (II) below. In the formulae, X represents O, S, NRa, or NRb, n1 and n2 each represent 0 or 1, Ra, Rb, and R1 to R18 each represent a hydrogen atom or a monovalent substituent, and one polymerizable group is present in the molecule.

摘要翻译： 本发明提供一种油墨组合物，其包含（i）具有可聚合基团作为取代基的增感染料，（ii）聚合引发剂和（iii）具有烯属不饱和键的聚合性化合物。 本发明还提供喷墨记录方法和可用作敏化染料的可聚合化合物。 敏化染料（i）由下式（I）或（II）表示。 在该式中，X表示O，S，NR a或NR b，n 1和n 2各自表示0或1，R a，R b，R 1至R 18各自表示氢原子或一价取代基，并且一个可聚合基团存在于 分子。

公开(公告)号：US20100247880A1

公开(公告)日：2010-09-30

申请号：US12749531

申请日：2010-03-30

申请人： Takeyoshi KANO ,  Tomomi TATEISHI ,  Tokihiko MATSUMURA

发明人： Takeyoshi KANO ,  Tomomi TATEISHI ,  Tokihiko MATSUMURA

IPC分类号： B32B3/10 ,  C08F222/30 ,  C08L39/00 ,  B32B27/00 ,  B32B15/08 ,  C25D5/56

CPC分类号： C08F222/30 ,  B32B27/28 ,  C08F220/60 ,  C23C18/1641 ,  C23C18/1653 ,  C23C18/30 ,  Y10T428/24917 ,  Y10T428/31504 ,  Y10T428/31678

摘要： There is provided a polymer containing a unit represented by the following Formula (1), and a unit represented by following Formula (2). In Formula (1) and Formula (2), R1 to R5 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group; R6 represents an unsubstituted alkyl group, alkenyl group, alkynyl group or an aryl group; V and Z each independently represent a single bond, a substituted or unsubstituted divalent organic group, an ester group, an amide group or an ether group, and L1 and L2 each independently represent a substituted or unsubstituted divalent organic group.

摘要翻译： 提供含有由下式（1）表示的单元的聚合物和由下式（2）表示的单元。 在式（1）和式（2）中，R 1至R 5各自独立地表示氢原子，取代或未取代的烷基; R6表示未取代的烷基，烯基，炔基或芳基; V和Z各自独立地表示单键，取代或未取代的二价有机基团，酯基，酰胺基或醚基，L1和L2各自独立地表示取代或未取代的二价有机基团。

公开(公告)号：US20100227076A1

公开(公告)日：2010-09-09

申请号：US12715415

申请日：2010-03-02

申请人： Kazuhiro YOKOI ,  Tokihiko MATSUMURA

发明人： Kazuhiro YOKOI ,  Tokihiko MATSUMURA

IPC分类号： B05D3/06

CPC分类号： C08F2/50 ,  C09D11/101 ,  Y10T428/24802

摘要： The present invention provides an ink composition containing (A) a polymer compound having (a-1) a photoradical generation site and (a-2) at least one segregation site selected from a fluoroalkyl group, a siloxane structure, and a long-chain alkyl group, (B) a radical-polymerizable compound, and (C) a photoradical generator having a structure different from that of (A).

摘要翻译： 本发明提供一种油墨组合物，其含有（A）具有（a-1）光自由基产生位点和（a-2）至少一个选自氟代烷基，硅氧烷结构和长链的分离位点的高分子化合物 烷基，（B）自由基聚合性化合物，（C）具有与（A）不同的结构的光发电机。