公开(公告)号：US20110245553A1

公开(公告)日：2011-10-06

申请号：US13157002

申请日：2011-06-09

申请人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady

发明人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady

IPC分类号： C10G3/00

CPC分类号： C10G3/45 ,  B01D2257/504 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/201 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2400/04 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as fats and oils from plants and animals where the process provides for sulfur-component management. The process involves catalytically treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. A selective separation such as a hot high pressure hydrogen stripper may be used to remove at least the carbon oxides from the first zone effluent and provide a liquid recycle stream at pressure and temperature. A vapor stream is separated from the net process effluent and at least carbon dioxide is removed using at least one selective or flexible amine absorber. The resulting hydrogen-rich stream is recycled to the reaction zone.

摘要翻译： 已经开发了一种从可再生原料生产柴油沸点燃料的方法，例如来自植物和动物的脂肪和油，其中该方法提供硫成分管理。 该方法涉及通过氢化和脱氧催化处理可再生原料以提供可用作柴油沸程燃料的烃馏分。 选择性分离如热的高压氢气汽提器可用于从第一区流出物中至少除去碳氧化物，并在压力和温度下提供液体循环流。 蒸汽流与净处理流出物分离，并且使用至少一种选择性或柔性胺吸收剂除去至少二氧化碳。 将所得富氢流循环至反应区。

公开(公告)号：US08865954B2

公开(公告)日：2014-10-21

申请号：US13157002

申请日：2011-06-09

申请人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady

发明人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady

IPC分类号： C07C1/00 ,  C10G45/58 ,  C10G3/00 ,  C10L1/08

CPC分类号： C10G3/45 ,  B01D2257/504 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/201 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2400/04 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as fats and oils from plants and animals where the process provides for sulfur-component management. The process involves catalytically treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. A selective separation such as a hot high pressure hydrogen stripper may be used to remove at least the carbon oxides from the first zone effluent and provide a liquid recycle stream at pressure and temperature. A vapor stream is separated from the net process effluent and at least carbon dioxide is removed using at least one selective or flexible amine absorber. The resulting hydrogen-rich stream is recycled to the reaction zone.

摘要翻译： 已经开发了一种从可再生原料生产柴油沸点燃料的方法，例如来自植物和动物的脂肪和油，其中该方法提供硫成分管理。 该方法涉及通过氢化和脱氧催化处理可再生原料以提供可用作柴油沸程燃料的烃馏分。 选择性分离如热的高压氢气汽提器可用于从第一区流出物中至少除去碳氧化物，并在压力和温度下提供液体循环流。 蒸汽流与净处理流出物分离，并且使用至少一种选择性或柔性胺吸收剂除去至少二氧化碳。 将所得富氢流循环至反应区。

公开(公告)号：US08865953B2

公开(公告)日：2014-10-21

申请号：US13156976

申请日：2011-06-09

申请人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

发明人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

IPC分类号： C07C1/00 ,  C10L1/08

CPC分类号： C10L1/08 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils, the process providing for sulfur management. The process involves catalytically treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. The hydrocarbon fraction is isomerized to improve cold flow properties. A selective separation such as a hot high pressure hydrogen stripper is used to remove at least the carbon oxides from the first zone effluent before entering the isomerization zone, and to provide liquid recycle to the treating zone at pressure and temperature. A vapor stream is separated from the isomerization effluent and at least carbon dioxide is removed using at least one selective or flexible amine solution absorber. The resulting hydrogen-rich stream is recycled to the deoxygenation reaction zone.

摘要翻译： 已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法，该方法提供硫管理。 该方法涉及通过氢化和脱氧催化处理可再生原料以提供可用作柴油沸程燃料的烃馏分。 烃馏分异构化以改善冷流动性能。 在进入异构化区之前，使用诸如热高压氢气汽提器的选择性分离来从第一区流出物中至少除去碳氧化物，并在压力和温度下向处理区提供液体循环。 将蒸汽流与异构化流出物分离，并使用至少一种选择性或柔性的胺溶液吸收剂除去至少二氧化碳。 将所得富氢流循环至脱氧反应区。

公开(公告)号：US20090082603A1

公开(公告)日：2009-03-26

申请号：US12193176

申请日：2008-08-18

申请人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady

发明人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady

IPC分类号： C10G3/00

CPC分类号： C10G3/45 ,  B01D2257/504 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/201 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2400/04 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as fats and oils from plants and animals where the process provides for sulfur-component management. The process involves catalytically treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. A selective separation such as a hot high pressure hydrogen stripper may be used to remove at least the carbon oxides from the first zone effluent and provide a liquid recycle stream at pressure and temperature. A vapor stream is separated from the net process effluent and at least carbon dioxide is removed using at least one selective or flexible amine absorber. The resulting hydrogen-rich stream is recycled to the reaction zone.

摘要翻译： 已经开发了一种从可再生原料生产柴油沸点燃料的方法，例如来自植物和动物的脂肪和油，其中该方法提供硫成分管理。 该方法涉及通过氢化和脱氧催化处理可再生原料以提供可用作柴油沸程燃料的烃馏分。 选择性分离如热的高压氢气汽提器可用于从第一区流出物中至少除去碳氧化物，并在压力和温度下提供液体循环流。 蒸汽流与净处理流出物分离，并且使用至少一种选择性或柔性胺吸收剂除去至少二氧化碳。 将所得富氢流循环至反应区。

公开(公告)号：US20090077866A1

公开(公告)日：2009-03-26

申请号：US12193156

申请日：2008-08-18

申请人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady ,  Peter Kokayeff

发明人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady ,  Peter Kokayeff

IPC分类号： C10L1/18

CPC分类号： C10L1/08 ,  C10G3/46 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils and animal oils, fats, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating, decarbonylating, and/or hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel or diesel boiling range fuel blending component. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties. A portion of the hydrogenated and deoxygenated feedstock is selectively separated and then recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.

摘要翻译： 已经开发了用于从可再生原料如植物油和动物油，脂肪和油脂生产柴油沸点燃料的方法。 该方法包括通过氢化和脱氧处理可再生原料，即脱羧，脱羰和/或加氢脱氧，以提供可用作柴油沸程燃料或柴油沸程燃料调配组分的烃馏分。 如果需要，烃馏分可以被异构化以改善冷流动性能。 氢化和脱氧原料的一部分被选择性分离，然后再循环到处理区以提高反应混合物的氢溶解度。

公开(公告)号：US20090229172A1

公开(公告)日：2009-09-17

申请号：US12403024

申请日：2009-03-12

申请人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

发明人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

IPC分类号： C10L1/00 ,  C10G63/04

CPC分类号： C10G3/50 ,  C10G3/46 ,  C10G65/043 ,  C10G65/12 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2300/80 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/28 ,  C10L1/026 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

摘要： A process has been developed for producing a diesel boiling point range product and an aviation boiling point range product from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction which is then isomerized and selectively cracked to form the diesel boiling point range product and the aviation boiling point range product. A portion of the diesel boiling point range product, aviation boiling point range product, naphtha product, LPG, or any combination thereof can be optionally used as a rectification agent in the selective hot high pressure hydrogen stripper to decrease the amount of product carried in the stripper overhead.

摘要翻译： 已经开发了用于生产柴油沸点范围产物和来自可再生原料如植物油和动物油的航空沸点范围产物的方法。 该方法包括通过氢化和脱氧来处理可再生原料以提供烃馏分，然后异构化并选择性裂化形成柴油沸点范围产物和航空沸点范围产物。 柴油沸点范围产品，航空沸点范围产品，石脑油产品，LPG或其任何组合的一部分可以任选用作选择性热高压氢气汽提器中的精馏剂，以减少在 汽提塔头顶。

公开(公告)号：US20090077868A1

公开(公告)日：2009-03-26

申请号：US12193196

申请日：2008-08-18

申请人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

发明人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

IPC分类号： C10L1/18

CPC分类号： C10L1/08 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils, the process providing for sulfur management. The process involves catalytically treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. The hydrocarbon fraction is isomerized to improve cold flow properties. A selective separation such as a hot high pressure hydrogen stripper is used to remove at least the carbon oxides from the first zone effluent before entering the isomerization zone, and to provide liquid recycle to the treating zone at pressure and temperature. A vapor stream is separated from the isomerization effluent and at least carbon dioxide is removed using at least one selective or flexible amine solution absorber. The resulting hydrogen-rich stream is recycled to the deoxygenation reaction zone

摘要翻译： 已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法，该方法提供了硫的管理。 该方法涉及通过氢化和脱氧催化处理可再生原料以提供可用作柴油沸程燃料的烃馏分。 烃馏分异构化以改善冷流动性能。 在进入异构化区之前，使用诸如热高压氢气汽提器的选择性分离来从第一区流出物中至少除去碳氧化物，并在压力和温度下向处理区提供液体循环。 将蒸汽流与异构化流出物分离，并使用至少一种选择性或柔性的胺溶液吸收剂除去至少二氧化碳。 将所得富氢流循环至脱氧反应区

公开(公告)号：US08198492B2

公开(公告)日：2012-06-12

申请号：US12403024

申请日：2009-03-12

申请人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

发明人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

IPC分类号： C10L1/16 ,  C10L5/00 ,  C07C4/00

CPC分类号： C10G3/50 ,  C10G3/46 ,  C10G65/043 ,  C10G65/12 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2300/80 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/28 ,  C10L1/026 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

摘要： A process has been developed for producing a diesel boiling point range product and an aviation boiling point range product from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction which is then isomerized and selectively cracked to form the diesel boiling point range product and the aviation boiling point range product. A portion of the diesel boiling point range product, aviation boiling point range product, naphtha product, LPG, or any combination thereof can be optionally used as a rectification agent in the selective hot high pressure hydrogen stripper to decrease the amount of product carried in the stripper overhead.

摘要翻译： 已经开发了用于生产柴油沸点范围产物和来自可再生原料如植物油和动物油的航空沸点范围产物的方法。 该方法包括通过氢化和脱氧来处理可再生原料以提供烃馏分，然后异构化并选择性裂化形成柴油沸点范围产物和航空沸点范围产物。 柴油沸点范围产品，航空沸点范围产品，石脑油产品，LPG或其任何组合的一部分可以任选用作选择性热高压氢气汽提器中的精馏剂，以减少在 汽提塔头顶。

公开(公告)号：US07999142B2

公开(公告)日：2011-08-16

申请号：US12193156

申请日：2008-08-18

申请人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady ,  Peter Kokayeff

发明人： Tom N. Kalnes ,  Terry L. Marker ,  John P. Brady ,  Peter Kokayeff

IPC分类号： C07C4/00

CPC分类号： C10L1/08 ,  C10G3/46 ,  C10G3/50 ,  C10G45/58 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils and animal oils, fats, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating, decarbonylating, and/or hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel or diesel boiling range fuel blending component. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties. A portion of the hydrogenated and deoxygenated feedstock is selectively separated and then recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.

摘要翻译： 已经开发了用于从可再生原料如植物油和动物油，脂肪和油脂生产柴油沸点燃料的方法。 该方法包括通过氢化和脱氧处理可再生原料，即脱羧，脱羰和/或加氢脱氧，以提供可用作柴油沸程燃料或柴油沸程燃料调配组分的烃馏分。 如果需要，烃馏分可以被异构化以改善冷流动性能。 氢化和脱氧原料的一部分被选择性分离，然后再循环到处理区以提高反应混合物的氢溶解度。

公开(公告)号：US07982078B2

公开(公告)日：2011-07-19

申请号：US12193196

申请日：2008-08-18

申请人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

发明人： John P. Brady ,  Tom N. Kalnes ,  Terry L. Marker

IPC分类号： C07C1/00 ,  C07C4/00

CPC分类号： C10L1/08 ,  C10G2300/1003 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/28 ,  Y02E50/13 ,  Y02P30/20

摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils, the process providing for sulfur management. The process involves catalytically treating a renewable feedstock by hydrogenating and deoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. The hydrocarbon fraction is isomerized to improve cold flow properties. A selective separation such as a hot high pressure hydrogen stripper is used to remove at least the carbon oxides from the first zone effluent before entering the isomerization zone, and to provide liquid recycle to the treating zone at pressure and temperature. A vapor stream is separated from the isomerization effluent and at least carbon dioxide is removed using at least one selective or flexible amine solution absorber. The resulting hydrogen-rich stream is recycled to the deoxygenation reaction zone.

摘要翻译： 已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法，该方法提供硫管理。 该方法涉及通过氢化和脱氧催化处理可再生原料以提供可用作柴油沸程燃料的烃馏分。 烃馏分异构化以改善冷流动性能。 在进入异构化区之前，使用诸如热高压氢气汽提器的选择性分离来从第一区流出物中至少除去碳氧化物，并在压力和温度下向处理区提供液体循环。 将蒸汽流与异构化流出物分离，并使用至少一种选择性或柔性的胺溶液吸收剂除去至少二氧化碳。 将所得富氢流循环至脱氧反应区。