摘要:
A catalyst for oxidizing ethylene and producing ethylene oxide, said catalyst being prepared by pretreating a porous carrier with a solution containing a lithium compound and a cesium compound, thereafter, impregnating a solution containing a silver compound and a cesium compound in the pretreated porous carrier and then heat-treating the impregnated porous carrier. The use of the catalyst of this invention provides high selectivity in the production of ethylene oxide by the vapor contact oxidation of ethylene.
摘要:
There is provided a catalyst for producing ethylene oxide from ethylene which is composed of at least silver (Ag), cesium (Cs), rhenium (Re) and a carrier, and can be improved, in particular, in selectivity.The present invention relates to a catalyst for producing ethylene oxide from ethylene, comprising at least silver (Ag), cesium (Cs), rhenium (Re) and a carrier, said catalyst being produced by optionally pretreating the carrier to support an alkali metal thereon and then supporting Ag, Cs and Re on the carrier, wherein the carrier has a specific surface area of 0.6 to 3.0 m2/g and a weight ratio of a silicon (Si) content to a sodium (Na) content of 2 to 50 in terms of SiO2/Na2O; a content of Re in the catalyst is 170 to 600 ppm per 1 m2/g of the specific surface area of the carrier on the basis of a weight of the carrier; and a molar ratio of Cs to Re in the catalyst is 0.3 to 19.
摘要:
Disclosed is a catalyst for ethylene oxide production which is used for producing ethylene oxide from ethylene. This catalyst is composed of at least silver (Ag), caesium (Cs), rhenium (Re) and a carrier, and improved especially in selectivity. Specifically disclosed is a catalyst for ethylene oxide production, which is used for producing ethylene oxide from ethylene and composed of at least silver (Ag), caesium (Cs), rhenium (Re) and a carrier. If necessary, an alkali metal is loaded onto the carrier as a pretreatment, and then Ag, Cs and Re are loaded onto the carrier, thereby obtaining the catalyst. The carrier has a specific surface area of 0.6-3.0 m2/g, and a weight ratio between the silicon (Si) content and the sodium (Na) content in terms of SiO2/Na2O of 2-50, The Re content (based the carrier) is 170-600 ppm per 1 m2/g or the specific surface area of the carrier, and the molar ratio Cs/Re is 0.3-19.
摘要:
An olefin oxidation catalyst comprising a carrier, and silver and an alkali metal supported thereon, wherein the content of organic substances is less than 0.1 wt %.