Liquid crystalline compound containing fluorine atom substituted alkyl
group(s) and a liquid crystal composition
    7.
    发明授权
    Liquid crystalline compound containing fluorine atom substituted alkyl group(s) and a liquid crystal composition 失效
    含氟原子取代的烷基的液晶化合物和液晶组合物

    公开(公告)号:US5702641A

    公开(公告)日:1997-12-30

    申请号:US576461

    申请日:1995-12-21

    摘要: A liquid crystalline compound exhibiting a large .DELTA..epsilon. value, an electrical and chemical stability and a superior compatibility with existing liquid crystalline compounds, a liquid crystal composition containing the same, and a liquid crystal display element constructed by using the composition are provided, which liquid crystalline compound is expressed by the formula (I), F--(CH.sub.2)n-E--(CH.sub.2 CH.sub.2).sub.k --G--(CH.sub.2 CH.sub.2).sub.l --L--(CH.sub.2 CH.sub.2).sub.m --Z--Q--Y (I) wherein n is an integer of 1 to 10; k, l and m each independently are an integer of 0 to 2; ring E is 1,4-cyclohexylene group or 1,4-phenylene group, wherein one or more H atoms on each six-membered ring may be replaced by F atom(s); G and L each independently is a covalent bond or 1,4-cyclohexylene group or 1,4-phenylene group, wherein one or more H atoms on each six-membered ring may be replaced by F atom(s); Q is covalent bond or --O--; Y is a fluoroalkyl group of 1 to 3C or F atom; but in the case where ring E is 1,4-cyclohexylene group and at least one of G and L is covalent bond, k+l+m.noteq.0, and in the case where Q is --O--, Y is not F atom.

    摘要翻译: 提供了具有大的DELTAε值,电化学稳定性和与现有液晶化合物的优异相容性的液晶化合物,含有该液晶化合物的液晶组合物和使用该组合物构成的液晶显示元件,该液体 结晶化合物由式(I)表示,F-(CH2)nE-(CH2CH2)kG-(CH2CH2)lL-(CH2CH2)mZQY(I)其中n是1至10的整数; k,l和m各自独立地为0〜2的整数; 环E是1,4-亚环己基或1,4-亚苯基,其中每个六元环上的一个或多个H原子可被F原子取代; G和L各自独立地为共价键或1,4-亚环己基或1,4-亚苯基,其中每个六元环上的一个或多个H原子可被F原子取代; Q是共价键或-O-; Y为1〜3或氟原子的氟代烷基; 但是在环E为1,4-亚环己基并且G和L中的至少一个为共价键的情况下,k + 1 + m为“0”,在Q为-O-的情况下,Y为F原子 。

    Pyrimidine derivative, liquid crystal composition comprising the derivative, and liquid crystal display device fabricated by using the composition
    9.
    发明授权
    Pyrimidine derivative, liquid crystal composition comprising the derivative, and liquid crystal display device fabricated by using the composition 有权
    嘧啶衍生物,包含该衍生物的液晶组合物和使用该组合物制造的液晶显示装置

    公开(公告)号:US06326065B1

    公开(公告)日:2001-12-04

    申请号:US09203671

    申请日:1998-12-01

    IPC分类号: C09K1930

    摘要: Liquid crystalline compounds having a comparatively high voltage holding ratio, high &Dgr;n and high &Dgr;&egr;, and excellent miscibility with known liquid crystalline compounds at low temperatures. The novel compounds have the formula (1) wherein R represents hydrogen atom or an alkyl group having 1 to 20 carbon atoms; n1 and n2 are independently 0, 1, or 2 provided that the sum of n1 and n2 is 1 or 2; ring A and ring B independently represent 1,4-phenylene, fluorine substituted 1,4-phenylene expressed by the formula (a) in the specification or 1,4-cyclohexylene provided that at least one of ring A and ring B is fluorine substituted 1,4-phenylene expressed by the formula (a); Za, Zb, and Zc independently represent single bond, —CH2CH2—, —COO—, —CF2O—, or —CH2CH2CH2CH2—; Q1, Q2, Q3, Q4, Q5, Q6, and Q7 independently represent hydrogen atom, a halogen atom, or methyl group provided that when at least one of Za, Zb, and Zc is —CH2CH2—, then Q2 is fluorine atom, and that when Za, Zb, and Zc are all single bonds, then Q1, Q2, Q3, Q4, Q5, Q6, and Q7 independently represent hydrogen atom or fluorine atom; Y represents hydrogen atom, a halogen atom, or a halogenated alkyl group having 1 to 5 carbon atoms; and each atom constituting this compound may be replaced by its isotope.

    摘要翻译: 具有比较高的电压保持率,高DELTAn和高DELTAepsi的液晶化合物,以及在低温下与已知液晶化合物的优异的混溶性。 新化合物具有式(1)其中R表示氢原子或具有1至20个碳原子的烷基; n1和n2独立地为0,1或2,条件是n1和n2的和为1或2; 环A和环B独立地表示说明书中所示的1,4-亚苯基,由式(a)表示的氟取代的1,4-亚苯基或1,4-亚环己基,条件是环A和环B中的至少一个为氟取代的 由式(a)表示的1,4-亚苯基; Za,Zb和Zc独立地表示单键,-CH2CH2-,-COO-,-CF2O-或-CH2CH2CH2CH2-; Q1,Q2,Q3,Q4,Q5,Q6和Q7独立地表示氢原子,卤素原子或甲基,条件是当Za,Zb和Zc中的至少一个是-CH 2 CH 2 - 时,则Q2是氟原子, 当Za,Zb和Zc都是单键时,Q1,Q2,Q3,Q4,Q5,Q6和Q7独立地表示氢原子或氟原子; Y表示氢原子,卤素原子或碳原子数1〜5的卤代烷基; 并且构成该化合物的每个原子可以被其同位素代替。